• Elastomers and Composites
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• v.54 no.3
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• pp.182-187
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• 2019

To improve the mechanical properties of glass-fiber-reinforced polypropylene (PP) composites through interfacial adhesion control between the PP matrix and glass fiber, the surface of the glass fiber was modified with PP-graft-maleic anhydride (MAPP). Surface modification of the glass fiber was carried out through the well-known hydrolysis-condensation reaction using 3-aminopropyltriethoxy silane, and then subsequently treated with MAPP to produce the desired MAPP-anchored glass fiber (MAPP-a-GF). The glass-fiber-reinforced PP composites were prepared by typical melt-mixing technique. The effect of chemical modification of the glass fiber surface on the mechanical properties of composites was investigated. The resulting mechanical and morphological properties showed improved interfacial adhesion between the MAPP-a-GF and PP matrix in the composites.

• Composites Research
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• v.19 no.3
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• pp.15-22
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• 2006

In this study, we prepared glass fiber reinforced polypropylene composites using Brabender twin-screw extruder. Compatibilizer, polypropylene-based maleic anhydride (PP-g-MAH), was used to increase the molecular interaction between polypropylene matrix and glass fiber and to enhance melt processability. We also measured the shear and uniaxial elongational behaviors of glass-fiber reinforced composites in the absence or presence of compatibilizer. The effects of compatibilizer and fiber loading on the viscoelastic behaviors were examined. It was fuund that the PP-g-MAH compatibilizer improved the fluidity and increased the molecular bonding of composite melts in shear flow. Transient elongational viscosity was increased with fiber loadings in uniaxial elongational flow However, it was decreased with increasing elongational rates because of microscale shear flow between fibers.

• Polymer(Korea)
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• v.27 no.4
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• pp.299-306
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• 2003

It is well known that the interaction and adhesion between the glass fiber (GF) and polymer matrix has a significant effect in determining the properties of fiber-reinforced materials. Therefore, it is one of important considerations to modify the surface of glass fiber with an appropriate sizing. We investigated the treatment method of glass fiber with coupling agent to improve the interaction of the interfacial region. The correlation between interfacial property and interphase microstructure was also examined in an attempt to realize a proper morphology at the glass fiber surfaces.

• The Korean Journal of Rheology
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• v.10 no.2
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• pp.57-64
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• 1998

A pultrusion resin impregnation (PRI) die, which has been developed recently in our laboratory, was used to pre-pare various composite system. The continuous fiber reinforced composites of glass fiber/polypropylene(GFPP) and glass fiber/polyamide 6 (GFPA) were first manufactured by means of the PRI die and then cut into chopped pellets of predet-ermined length. These pellets and either virgin or modified thermoplastic resin were melt-mixed by a twin screw extruder to prepare GF/PA/PP and GF/PA/PPMA system. The mechanical properties of these blends were investigated and discussed in terms of their morphological observations. These preliminary results revealed that this new impregnation die could be suc-cessfully applied to produce prepregs suitavle for the final shaping process.

• Polymer(Korea)
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• v.36 no.6
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• pp.677-684
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• 2012

Injection molding process is a popular polymer processing involving plasticizing and enforcing the material flow into the mold. A polymer material shrinks according to temperature variations during the shaping process, and subsequently molding shrinkage developed. Developed deflections or warpages after molding process in part are caused by residual stress relaxation contained in the part. Adding inorganic materials or fibers such as glass and carbon to control shrinkage and enhance warpage resistance are common. In this study, warpages according to part design have been investigated through experiment. Warpages for molding conditions and mold designs such as gate locations were measured. Warpages along flow direction and perpendicular to the flow direction were also measured. Warpages near gate and far from gate were compared. Glass fiber reinforced crystalline polymers, PP and PA66 have been used in this experiment. Glass fiber reinforced crystalline polymers showed large warpage compared with glass reinforced amorphous polymers. Warpages in crystalline polymers were less influenced by molding conditions compared with amorphous polymers, however warpages of crystalline polymers significantly depend on part design.

• International Journal of Concrete Structures and Materials
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• v.9 no.4
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• pp.475-486
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• 2015

Mode II fracture toughness ($K_{IIc}$) of fiber reinforced concrete (FRC) has been widely investigated under various patterns of test specimen geometries. Most of these studies were focused on single type fiber reinforced concrete. There is a lack in such studies for hybrid fiber reinforced concrete. In the current study, an experimental investigation of evaluating mode II fracture toughness ($K_{IIc}$) of hybrid fiber embedded in high strength concrete matrix has been reported. Three different types of fibers; namely steel (S), glass (G), and polypropylene (PP) fibers were mixed together in four hybridization patterns (S/G), (S/PP), (G/PP), (S/G/PP) with constant cumulative volume fraction ($V_f$) of 1.5 %. The concrete matrix properties were kept the same for all hybrid FRC patterns. In an attempt to estimate a fairly accepted value of fracture toughness $K_{IIc}$, four testing geometries and loading types are employed in this investigation. Three different ratios of notch depth to specimen width (a/w) 0.3, 0.4, and 0.5 were implemented in this study. Mode II fracture toughness of concrete $K_{IIc}$ was found to decrease with the increment of a/w ratio for all concretes and test geometries. Mode II fracture toughness $K_{IIc}$ was sensitive to the hybridization patterns of fiber. The (S/PP) hybridization pattern showed higher values than all other patterns, while the (S/G/PP) showed insignificant enhancement on mode II fracture toughness ($K_{IIc}$). The four point shear test set up reflected the lowest values of mode II fracture toughness $K_{IIc}$ of concrete. The non damage defect concept proved that, double edge notch prism test setup is the most reliable test to measure pure mode II of concrete.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.186-191
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• 2004

we can say that the increasing range of the value of GMT Sheet's tensile strength in the direction of fiber orientation is getting wider as the fiber content increases. It shows that the value of GMT Sheet's tensile strength in the direction of fiber orientation 90 is similar with the value of pp's intensity when fiber orientation function is J= 0.7, regardless of the fiber content. Tensile strength of GMT Sheet is affected by the fiber orientation distribution more than by the fiber content.

• Design & Manufacturing
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• v.2 no.4
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• pp.54-61
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• 2008

Warpage, which is one of the molding trouble, acts as possible factor which results in defect in assembly. In this study, a mold was designed to produce specimens with rib parallel to flow direction, specimens with rib perpendicular to flow direction and specimens without rib. This work researched change of warpage according to injection molding condition such as injection pressure, packing pressure, packing time, resin temperature, mold temperature in non-crystalline resins(PC, ABS), crystalline resins(PP, PA66), and 30% glass fiber reinforced-resins(PC, ABS, PP, PA66).Specimens with rib and Crystalline resins show more warpage than specimens without rib and non-crystalline resins, respectively. Glass fiber reinforced-resins and specimens with rib parallel to flow direction show smaller warpage than conventional resins and specimens with rib perpendicular to flow, respectively. Specimens with rib and specimens without rib show reduced warpage as packing time increases. In addition, warpage increase as resin temperature increases. It is found that CAE shows similar tendency with experiment as packing time, resin temperature. when the rib is caused, warpage will reduce and prevent the transformation. product of a irregular form occurs warpage. In the study It'll be basic data that product occurs warpage, preferablity.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.05a
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• pp.314-319
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• 2004

Many of researches regarding mechanical properties of composite materials are associated with humid environment and temperature. Especially the temperature is a very important factor influencing the design of thermoplastic composites. However, the effect of temperature on impact behavior of reinforced composites have not yet been fully explored. An approach which predicts critical fracture toughness GIC was performed by the impact test in this work The main goal of this work is to study effects of temperature in the impact test with glass fiber/polypropylene(GF/pp) composites. The critical fracture energy and failure mechanisms of GF/PP composites are investigated in the temperature range of $60^{\circ}C\;to\;-50^{\circ}C$ by impact test. The critical fracture energy shows a maximum at ambient temperature and it tends to decrease as temperature goes up or goes down. Major failure mechanisms can be classified such as fiber matrix debonding, fiber pull-out and/or delamination and matrix deformation.

• Polymer(Korea)
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• v.24 no.5
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• pp.701-712
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• 2000

The continuous fiber reinforced composites of GF/PA were fabricated using a pultrusion resin impregnation apparatus and cut into pellets of 6 mm length. GF/PA pellets were then melt-mixed with PP resin to prepare new types of ternary composites, GF/PA/PP. Mechanical and rheological properties of such composites revealed to be better than conventional ternary composites due to the longer average glass fibers. Measurements also showed that the mechanical properties of the composites prepared by direct injection molding were higher than those of the composites prepared by injection molding followed by extrusion. To improve adhesions of fiber surfaces and polymer matrix, PP-MAH (maleic anhydride) has been introduced in the GF/PA/PP composites as a compatibilizer. It was found that PP-MAH did indeed improve surface adhesion between fibers and polymer matrix and that, as a result, various mechanical properties were markedly enhanced. Visualization of the phase structure in the samples was done by means of SEM. The surfaces of glass fibers in GF/PA/PP composites revealed that the fibers remained to be encapsulated by PA resin. However, pre-encapsulation did not persist in GF/PA/PP/PP-MAH composites due to the improvement of surface adhesion between fibers and polymer matrix, although resin sticking to the fiber was observed.