• Title/Summary/Keyword: glass behavior

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The Characteristic Improvement of Photodiode by Schottky Contact (정류성 접합에 의한 광다이오드의 특성 개선)

  • Hur Chang-wu
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.8 no.7
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    • pp.1448-1452
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    • 2004
  • In this paper, a photodiode capable of obtaining a sufficient photo/ dark current ratio at both a forward bias state and a reverse bias state is proposed. The photodiode includes a glass substrate, an Cr thin film formed as a lower electrode over the glass substrate, Cr silicide thin film(∼l00$\AA$) ) formed as a schottky barrier over the Cr thin film, a hydrogenated amorphous silicon film formed as a photo conduction layer over a portion of the Cr silicide thin film. Transparent conduction film ITO (thickness 100nm) formed as an upper electrode over the hydro-generated amorphous silicon film is then deposited in pure argon at room temperature for the Schottky contact and light window. The high quality Cr silicide thin film using annealing of Cr and a-Si:H is formed and analyzed by experiment. We have obtained the film with a superior characteristics. The dark current of the ITO/a-Si:H Schottky at a reverse bias of -5V is ∼3$\times$IO-12 A/un2, and one of the lowest reported, hitherto. AES(Auger Electron Spectroscophy) measurements indicate that this notable improvement in device characteristics stems from reduced diffusion of oxygen, rather than indium, from the ITO into the a-Si:H layer, thus, preserving the integrity of the Schottky interface. The spectral response of the photodiode for wavelengths in the range from 400nm to 800nm shows the expected behavior whereby the photocurrent is governed by the absorption characteristics of a-Si:H.

Effect of Glass Fiber-Reinforced Polymer (GFRP) Shear Connector's Shape on Inplane Shear Strength of Insulated Concrete Sandwich Panels (유리섬유복합체를 사용한 전단연결재 형상에 따른 중단열 벽체의 면내전단내력)

  • Jang, Seok-Joon;You, Young-Chan;Kim, Ho-Ryong;Yun, Hyun-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.4
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    • pp.9-17
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    • 2013
  • This paper describes an experimental program to investigate the shear behavior of insulated concrete sandwich panels (CSPs) with different types of GFRP shear connector. The study included testing of 13 insulated CSP specimens with two types of surface conditions for extruded polystyrene (XPS) insulation and various shapes of shear connectors. All specimens were loaded in direct shear by means of push-out and were consist of three concrete panels, two insulation layer and four rows of GFRP shear connectors. Load-relative slip between concrete panel and insulation response of CSP specimens has been established through push-out shear test. Test results indicate that the surface condition of insulation has a significant effect on the bond strength between concrete panel and insulation. The specimen used XPS foam with 10mm deep slot shows higher bond strength than those used XPS foam with meshed surface. Corrugated GFRP shear connectors show equivalent strength to grid GFRP shear connectors. Cross-sectional area and embedded length of shear connector have a notable effect on overall response and inplane shear strength of the CSP specimens.

The Characterization and Sintering Behavior of Alumina Powder Prepared by Heat-treatment of Artificial Marble Waste Containing $Al(OH)_3$ Powder ($Al(OH)_3$ 함유(含有) 인조대리석폐기물(人造大理石廢棄物)로부터 제조(製造)된 알루미나 분말(粉末)의 특성(特性) 및 소결거동(燒結擧動) 연구(硏究))

  • Ryu, Sung-Soo;Seo, Sung-Gyu;Kim, Hyung-Tae;Kim, Hyeong-Jun;Park, Jun-Gyu;Yang, Jae-Gyu
    • Resources Recycling
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    • v.18 no.2
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    • pp.69-76
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    • 2009
  • Alumina powder was prepared from heat-treatment of artificial marble waste fine aggregate containing $Al(OH)_3$ for the purpose of the feasibility of its recycling. Artificial marble waste was heat-treated between $500^{\circ}C$ and $1000^{\circ}C$ and XRD, BET surface area, BJH pore size distribution and adsorption of As were analyzed for heat-treated powder. It was found that the adsorption efficiency of As was significantly affected by phase composition of alumina powder rather than its physical characteristic. Heat-treated powder compact was sintered to produce the pellet. Alumina pellet with porosity more than 60% could be obtained after sintering below $1200^{\circ}C$ and also the addition of glass powder as a sintering aid had a positive effect on lowering sintering temperature, led to the high porosity near 60% and adsorption of As over 60% even at $900^{\circ}C$.

Strain induced/enhanced ferromagnetism in $Mn_3Ge_2$thinfilms

  • Dung, Dang Duc;Feng, Wuwei;Thiet, Duong Van;Sin, Yu-Ri-Mi;Jo, Seong-Rae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.135-135
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    • 2010
  • In Mn-Ge equilibrium phase diagram, many Mn-Ge intermetallic phases can be formed with difference structures and magnetic properties. The MnGe has the cubic structure and antiferromagnetic(AFM) with Neel temperature of 197 K. The calculation predicted that the $MnGe_2$ with $Al_2Cu$-type is hard to separate between the paramagnetic(PM) states and the AFM states because this compound displays PM and AFM configuration swith similar energy. Mn-doped Ge showed the FM with Currie temperature of 285 K for bulk samples and 116 K for thin films. In addition, the $Mn_5Ge_3$ compound has hexagonal structure and FM with Curie temperature around 296K. The $Mn_{11}Ge_8$ compound has the orthorhombic structure and Tc is low at 274 K and spin flopping transition is near to 140 K. While the bulk $Mn_3Ge_2$ exhibited tetragonal structure ($a=5.745{\AA}$;$c=13.89{\AA}$) with the FM near to 300K and AFM below 150K. However, amorphous $Mn_3Ge_2$ ($a-Mn_3Ge_2$) was reported to show spin glass behavior with spin-glass transition temperature (Tg) of 53 K. In addition, the transition of crystalline $Mn_3Ge_2$ shifts under high pressure. At the atmospheric pressure, $Mn_3Ge_2$ undergoes the magnetic phase transition from AFM to FM at 158 K. The pressure dependence of the phase transition in $Mn_3Ge_2$ has been determined up to 1 GPa. The transition was found to occur at 1 GPa and 155 K with dT/dP=-0.3K/0.1 GPa. Here report that Ferromagnetic $Mn_3Ge_2$ thin films were successfully grown on GaAs(001) and GaSb(001) substrates using molecular beam epitaxy. Our result revealed that the substrate facilitates to modify magnetic and electrical properties due to tensile/compressive strain effect. The spin-flopping transition around 145 K remained for samples grown on GaSb(001) while it completely disappeared for samples grown on GaAs(001). The antiferromagnetism below 145K changed to ferromagnetism and remained upto 327K. The saturation magnetization was found to be 1.32 and $0.23\;{\mu}B/Mn$ at 5 K for samples grown on GaAs(001) and GaSb(001), respectively.

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Effect of Stitching on Mechanical and Impact Properties of Glass Fiber Reinforced Composite (스티칭에 의한 유리섬유강화 복합재료의 물성 및 충격거동 변화)

  • Park, Jae-Yong;Kang, Tae-Jin;Yuk, Jong-Il
    • Korean Journal of Materials Research
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    • v.2 no.5
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    • pp.366-374
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    • 1992
  • Mechanical and impact properties of stitched S2 glass fiber reinforced polyester woven laminates composites have been studied. Laminates were stitched using Kevlar 49 thread with 1/2, 1, and 2 inch stitch spacing. Tensile and 3-point bending tests haute been performed to evaluate the mechanical properties of stitched and unstitched laminates. Impact tests at applied energy of 234.7J were performed to examine the impact behavior and toughness changes of the specimen. The same specimens were also tested repeatedly at low impact energy level of 110.2J for 3 times to evaluate damage tolerance properties. The tensile and 3-point bending test results showed that one inch spacing specimen had the highest tensile and flexural strength. It also showed the highest energy absorption capability and the best damage tolerance property at the repeated impact test. The half inch spacing specimen showed the lowest tensile strength and energy absorption property at the impact energy level of 234.7J, even though it had the highest frequency of stitching thread.

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Performance and Charging-Discharging Behavior of AGM Lead Acid Battery according to the Improvement of Bonding between Active Material/Substrate using Sand-Blasting Method (Sand-Blasting법을 이용한 활물질/기판간 결합력 향상에 따른 AGM 연축전지의 성능 및 충방전 거동)

  • Kim, Sung Joon;Lim, Tae Seop;Kim, Bong-Gu;Son, Jeong Hun;Jung, Yeon Gil
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.75-83
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    • 2021
  • To cope with automobile exhaust gas regulations, ISG (Idling Stop & Go) and charging control systems are applied to HEVs (Hybrid Electric Vehicle) for the purpose of improving fuel economy. These systems require quick charge/discharge performance at high current. To satisfy this characteristic, improvement of the positive electrode plate is studied to improve the charge/discharge process and performance of AGM(Absorbent Glass Mat) lead-acid batteries applied to ISG automotive systems. The bonding between grid and A.M (Active Material) can be improved by applying the Sand-Blasting method to provide roughness to the surface of the positive grid. When the Sand-Blasting method is applied with conditions of ball speed 1,000 rpm and conveyor speed 5 M/min, ideal bonding is achieved between grid and A.M. The positive plate of each condition is applied to the AGM LAB (Absorbent Glass Mat Lead Acid Battery); then, the performance and ISG life characteristics are tested by the vehicle battery test method. In CCA, which evaluates the starting performance at -18 ℃ and 30 ℃ with high current, the advanced AGM LAB improves about 25 %. At 0 ℃ CA (Charge Acceptance), the initial charging current of the advanced AGM LAB increases about 25 %. Improving the bonding between the grid and A.M. by roughening the grid surface improves the flow of current and lowers the resistance, which is considered to have a significant effect on the high current charging/discharging area. In a Standard of Battery Association of Japan (SBA) S0101 test, after 300 A discharge, the voltage of the advanced AGM LAB with the Sand-Blasting method grid was 0.059 V higher than that of untreated grid. As the cycle progresses, the gap widens to 0.13 V at the point of 10,800 cycles. As the bonding between grid and A.M. increases through the Sand Blasting method, the slope of the discharge voltage declines gradually as the cycle progresses, showing excellent battery life characteristics. It is believed that system will exhibit excellent characteristics in the vehicle environment of the ISG system, in which charge/discharge occurs over a short time.

Experimental Analysis of Large Size Concrete-Filled Glass Fiber Reinforced Composite Piles Subjected to the Flexural Compression (대구경 콘크리트 충전 복합소재 파일의 휨-압축 거동에 대한 실험적 분석)

  • Lee, Sung Woo;Choi, Sokhwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.5A
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    • pp.519-529
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    • 2009
  • Fiber reinforced composite materials have various advantages in mechanical and chemical aspects. Not only high fatigue and chemical resistance, but also high specific strength and stiffness are attained, and therefore, damping characteristics are beneficial to marine piles. Since piles used for marine structures are subjected to compression and bending as well, detailed research is necessary. Current study examine the mechanical behavior under flexural and/or compressive loads using concrete filled fiber reinforced plastic composite piles, which include large size diameter. 25 pile specimens which have various size of diameters and lengths were fabricated using hand lay-up or filament winding method to see the effect of fabrication method. The inner diameters of test specimens ranged from 165 mm to 600 mm, and the lengths of test specimens ranged from 1,350 mm to 8,000 mm. The strengths of the fill-in concrete were 27 and 40 MPa. Fiber volumes used in circumferential and axial directions are varied in order to see the difference. For some tubes, spiral inner grooves were fabricated to reduce shear deformation between concrete and tube. It was observed that the piles made using filament winding method showed higher flexural stiffness than those made using hand lay-up. The flexural stiffness of piles decreases from the early loading stage, and this phenomenon does not disappear even when the inner spiral grooves were introduced. It means that the relative shear deformation between the concrete and tube wasn't able to be removed.

Observation of Molecular Relaxation Behavior of Glucose Powders with Different Structures and Particle Sizes Using Low Field Nuclear Magnetic Resonance (NMR) (NMR을 이용한 구조 및 입도 차이에 따른 분말 포도당의 molecular relaxation behavior의 관찰)

  • Chung, Myung-Soo
    • Korean Journal of Food Science and Technology
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    • v.34 no.6
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    • pp.1140-1144
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    • 2002
  • Molecular relaxation behaviors of crystalline glucose anhydrous, crystalline glucose monohydrate, and amorphous glucose with different particle sizes were observed by measuring spin-spin relaxation time constant $(T_2)$ at the temperature range of $-20\;to\;110^{\circ}C$ using temperature-controlled low field nuclear magnetic resonance spectroscopy. No change in $T_2$ values of crystalline glucose anhydrous was observed throughout the temperature range, whereas $T_2$ values of crystalline glucose monohydrate and amorphous glucose increased from around $45\;and\;65^{\circ}C$, respectively. These results indicate that molecular mobility of crystalline glucose anhydrous does not change even at temperature higher than $100^{\circ}C$ and that the stability of powdered glucose could be improved by increasing the particle size of materials.

Flexural Behavior of Concrete Beams Reinforced with Lap Spliced FRP Bar (겹이음된 FRP 보강근으로 보강된 콘크리트 보의 휨거동)

  • Oh, Hongseob
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.1 s.53
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    • pp.186-194
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    • 2009
  • This is a part of the extensive ongoing investigation being carried out by author to develop appropriate design procedure of the concrete member reinforced with FRP rebars instead of conventional steel rebars. This study presents the experimental results of a research programme to assess the structural characteristics of spliced rebar in reinforced concrete members with FRP reinforcement. The test variables are the diameter of FRP rebar and the embedment length. The development length (ld) was calculated according to the ACI 440 for FRP rebars in concrete. A total of 14 concrete beams reinforced with spliced FRP rebars and 4 reference beams reinforced with non-spliced FRP rebars were tested. The effects of bar size (10, 13, 16 and 19 mm) and splice length (from 0.72 to 1.58ld) on the bond strength were empirically evaluated. The test results indicate that a modification factor of 1.3 and 1.6 is relatively sufficient for the bond development length of glass FRP rebars in order to achieve an adequate tension lap splice length.

Preparation and Oxygen Permeability of True-IPN's based on Silicone Rubber and Polystyrene (실리콘 고무와 폴리스틸렌을 이용한 True-IPNs의 제조 및 산소투과 특성)

  • Kim, Jun-Hyun;Byun, Hong-Sik
    • Membrane Journal
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    • v.10 no.4
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    • pp.205-212
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    • 2000
  • The true-lPN's based on silicone rubber(SR)rrubbery polymer) and polystyrenc(PS)(glass polymer) were prepared by using the sequential IP!\' method_ The characteristic of permeability of oxygen/nitrogen was investigated with the control of the amount of PSOO-70 wt%) in the true-lPN, As a results of fTlR and N1Vm. the SRIPS membrane was synthesised successfully with the IPN synthetic method, Thermal analysis resulls indicated that the degree of mixing of IPN increased with increase of the amount of PS in the IPN. Regarding the characteristic of gas permeability, the membrane showed a trend of decrease in oxygen permeability as the PS content increased, The oxygen permeability of membrane having 50 wt% of PS. however, increased momentarily, Selectivity, meanwhile, increased slightly as the contents of I'S increased. However, the maximum value of oxygen selectivity, which is 20.6% enhanced Value, was obtained with the membrane containing 50 wt% of PS. This can be explained that the behavior of lPN, i.e. mutual assistance, is pronounced in the membrane having 50 wt% of PS.

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