• 폴리머
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• 제26권1호
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• pp.139-144
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• 2002

본 연구에서는 PPS와 ABS의 물성을 상호보완하며, 두 성분간의 상용성을 향상시키기 위해 반응압출법을 이용하여 maleic anhydride(MAH)를 ABS에 치환시켜 MABS를 제조하였으며, ABS의 화학적 개질이 블렌드의 기계적 및 동력학적 물성에 미치는 영향을 관찰하였다. 동력학적 특성 분석을 통하여서는 PPS/MABS 블렌드가 거의 전조성 영역에서 단일 유리전이온도를 가짐을 확인하였다. 블렌드의 기계적 성질은, 상용화제를 포함하고 있는 블렌드가 더욱 강한 인장강도, 굴곡강도, 충격강도 등을 나타냄을 확인하였다. 이는 상용화제의 도입으로 인해 분산상과 매트릭스 사이의 계면장력이 낮아져 분산상의 크기가 작아지며 계면간의 상호작용이 증진되어 물성이 향상되었기 때문이다.

• Bulletin of the Korean Chemical Society
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• 제33권1호
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• pp.183-188
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• 2012

A blue phosphorescent $Ir(dfpypy)_3$ (dfpypy:fluorinated pyridine-pyridine ligand) complex with meridional configuration has been synthesized by newly developed effective method and its solid state structure and photoluminescence are characterized. For this complex, mer-$Ir(dfpypy)_3$, the glass-transition and decomposition temperatures appear at $160^{\circ}C$ and $384^{\circ}C$ respectively in TGA and DSC experiments, which indicates that this complex has high thermal stability. In a crystalline structure, an average Ir-C bond length of mer-$Ir(dfpypy)_3$ is slightly longer than that of fac-$Ir(dfpypy)_3$, which assumed to be due to the weak trans-influence. The absorption and emission spectra are observed more red-shifted in mer-$Ir(dfpypy)_3$ than fac-$Ir(dfpypy)_3$. In addition, the former is readily oxidized than the latter in electrochemical behavior.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 1999년도 가을 학술발표회 논문집
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• pp.11-18
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• 1999

Recently advanced countries are now beginning to use ACM (Advanced Composites Material), which is mostly used in the industry of airplane, ship building and sports equipments, in the construction industry. Compared with existing construction materials, ACM possesses many advantages such as light-weight, high-strength, corrosion resistant property. Among other manufacturing process of ACM, pultrusion is one of the promising one of civil engineering application. In this paper, the structural characteristics of pultruded GFRP strip were studied. Major parameters to influence structural behavior of pultruded GFRP are considered to be fiber volume fraction, die temperature, pulling speed and fiber orientations. The effect of these parameters are studied by experimently and analytically. From this study, it is concluded that fiber volume fraction and fiber orientations influence more on the mechanical property of pultruded GFRP. In addition to above parametric study, off-axis tests were carried out and the results are compared with failure theories. It showed that they agree well each other. Since this study is carried out in limited scope, further research on the reinforcement in the transverse direction, experiment on the compressive strength and research on the durability should be conducted for wide application of pultruded GFRP sections.

• 한국재료학회지
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• 제15권8호
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• pp.548-553
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• 2005

Trivalent cerium$(Ce^{3+})$ activated YAG (yttrium aluminum garnet, $Y_3Al_5O_{12})$) thin films phosphor were deposited on quartz glass substrates by rf magnetron sputtering. The effects of sputtering parameters, annealing atmosphere, and substrates on growing behaviors and luminescent properties were investigated. The sputtering parameters were $O_2/(Ar+O_2)$ gas ratio, rf power, and deposition time. XRD (X-ray diffractometery) spectra exhibited that as-deposited films were amorphous, while they were transformed to the crystalline phases by post-annealing. The crystallinity and the atomic ratio strongly depended on the sputtering gas ratio $O_2/(Ar+O_2)$. High quality YAG:Ce thin films could be obtained at the gas ratio of $50\%$ oxygen. After annealing process, PL (Photoluminescence) spectra excited at 450nm showed a yellow single band at 550nm. The films deposited at the sputtering gas ratio of 50% oxygen exhibited the highest PL intensity.

• Macromolecular Research
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• 제12권5호
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• pp.478-483
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• 2004

Two different diene monomers [dicyclopentadiene (DCPD) and 5-ethylidene-2-norbornene (ENB)] as self-healing agents for polymeric composites were microencapsuled by in situ polymerization of urea and formaldehyde. We obtained plots of the storage modulus (G') and tan $\delta$ as a function of cure time by using dynamic mechanical analysis to investigate the cure behavior of the unreacted self-healing agent mixture in the presence of a catalyst. Glass transition temperatures (T$\_$g/) and exothermic reactions of samples cured for 5 and 120 min in the presence of different amounts of the catalyst were analyzed by differential scanning calorimetry. Of the two dienes, ENB may have advantages as a self-healing agent because, when cured under same conditions as DCPD, it reacts much faster in the presence of a much lower amount of catalyst, has no melting point, and produces a resin that has a higher value of T$\_$g/. Microcapsules containing the healing agent were successfully formed from both of the diene monomers and were characterized by thermogravimetric analysis. Optical microscopy and a particle size analyzer were employed to observe the morphology and size distribution, respectively, of the microcapsules. The microcapsules exhibited similar thermal properties as well as particle shapes and sizes.

• 복합신소재구조학회 논문집
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• 제2권3호
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• pp.12-17
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• 2011

본 논문은 노후교량바닥판 대체용으로서 하이브리드 GFRP-강재 바닥판의 휨거동을 구조적 거동특성을 기술하고 있다. 하이브리드 GFRP-강재 바닥판의 구조적 특성을 조사하기 위해 정적하중의 실험적 연구를 수행하였다. 하이브리드 바닥판의 파괴모드는 초기항복을 지나서 연성거동을 나타내었다. 결과는 유한요소프로그램 ANSYS의 값과 비교하였다. 제안된 하이브리드 바닥판이 교량적용에 유용함을 확인하였다. 하이브리드 바닥판의 두께는 유사한 휨 강성을 갖는 완전복합신소재 바닥판께와 비교하였을 때 감소될 수 있었다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.134-134
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• 2016

The effect of different thermal treatments on the sub-50 nm copper nanoparticles is examined in the aspects of chemical, electrical and surface morphology. The copper nanoparticles are chemically synthesized and fabricated for paste-type solution. Simple bar coating method is practiced as a deposition process to form copper thin film on a typical slide glass. Deposited copper thin films are annealed by two different routes: general tube furnace with 99.99 % Ar atmosphere and selective laser sintering process. The thermal behavior of the different thermal-treated copper thin films is compared by SEM, XRD, FT-IR and XPS analysis. In this study, the laser sintering process ensures low annealing temperature, fast working speed and ambient-accessible route. Moreover, the laser-sintered copper thin film shows good electrical property and enhanced chemical stability than conventional thermal annealing process. Consequently, the proposed laser sintering process can be compatible with plastic substrate for flexible applications.

• 한국표면공학회지
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• 제43권1호
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• pp.7-11
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• 2010

Solid phase crystallization (SPC) is a simple method in producing a polycrystalline phase by annealing amorphous silicon (a-Si) in a furnace environment. Main motivation of the crystallization technique is to fabricate low temperature polycrystalline silicon thin film transistors (LTPS-TFTs) on a thermally susceptible glass substrate. Studies on SPC have been naturally focused to the low temperature regime. Recently, fabrication of polycrystalline silicon (poly-Si) TFT circuits from a high temperature polycrystalline silicon process on steel foil substrates was reported. Solid phase crystallization of a-Si films proceeds by nucleation and growth. After nucleation polycrystalline phase is propagated via twin mediated growth mechanism. Elliptically shaped grains, therefore, contain intra-granular defects such as micro-twins. Both the intra-granular and the inter-granular defects reflect the crystallinity of SPC poly-Si. Crystallinity and SPC kinetics of high temperatures were compared to those of low temperatures using Raman analysis newly proposed in this study.

• 한국세라믹학회지
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• 제36권1호
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• pp.15-20
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• 1999

상압소결 질화규소에 대한 고온정피로 거동을 K-t(stress intensity/life test)법에 의해 조사하였다. 정피로 크랙성장속도는 온도의 증가와 함께 증가한다. 온도의 증가에 따라 크랙성장속도가 증가하는 이유는 온도 증가에 따라 파괴인성치가 감소하기 때문으로 판명되었다. 즉 정피로 크랙성장속도 da/dt를 da/dt=AK1m로 나타내면, 이 식의 정수 A는 파괴인성치의 파괴인성치의 함수이도, 지수 m은 온도나 파괴인성치에 관계없이 일정한 상수이다. 그러나 글래스상의 연화가 일어나는 고온의 경우 크랙성장속도는 이상의 관계로부터 벗어남을 발견하고, 그 이유에 대하여 고찰하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.165-168
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• 2008

본 연구에서는 철근콘크리트 구조물의 보강에 이용되는 유리섬유강화 복합재료(Glass Fiber Reinforced Polymer, GFRP) 형상에 관한 연구로서 콘크리트의 피복두께 및 FRP 보강재의 형상(Plate, Box)을 실험 변수로 하여 FRP 보강 철근콘크리트 보의 거동 평가 관한 연구를 수행하였다. 이를 위하여 본 연구에서는 T. J. Teng 등이 제안한 설계식을 이용하여 보강량을 결정하였고 기존의 FRP Plate 보강재의 성능개선을 위하여 FRP Sandwich box 보강재를 설계, 적용하여 보았다. 연구의 결과 예상과 달리 FRP Plate 보강재가 Sandwich box 보강재보다 보강효과가 우수한 것으로 조사되었으며, 이는 보강재 제작상의 한계점 및 core 재료가 너무 약하여 Sandwich box 보강재의 Top Plate와 Bottom Plate가 일체화 거동을 하지 못하여 나타난 결과로 사료된다.