• Title/Summary/Keyword: glass bead

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Chemical Characteristic of Glass Beads Excavated from Bakjimeure Site in Asan, Korea (아산 명암리 밖지므레 유적 출토 유리구슬의 화학적 특성)

  • Kim, Na Young;Kim, Gyu Ho
    • Journal of Conservation Science
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    • v.28 no.3
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    • pp.205-216
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    • 2012
  • 65 samples of glass bead excavated from Mahan tombs of Asan Bakjimeure site consists of 13 of potash glass group and 52 of soda glass group and soda glass is superior in numbers. When classified according to color, purple blue glass bead is accompanied potash and soda glass group whereas purple glass bead is potash glass group and red, greenish blue, green and gold foil glass bead is soda glass group. Purple blue glass bead is classified as LCA type in which the content of the stabilizer is low. Of this, the soda glass categorized as LMK type with low content of MgO and $K_2O$ is determined that natron is used as the raw material. As to red glass, the homogeneous glass is LCA-B/HMK type and the heterogeneous glass is HCLA/LMK type. Thus, each of these two types are likely to be used plant ash and natron respectively. Greenish blue and green glass depends of the type that round glass is LCA-A/LMHK type and the segmented glass is LCA-B/HMK type. The gold foil glass bead is manufactured by the purity of 19.9~22.6K gold foil and the soda glass of HCLA/LMK type. In other words, the most of the glass bead of Asan Bakjimeure site is similar to the composition of the glass confirmed in other sites of the Baekche period. On the other hand, the greenish blue and green segmented bead and some red round bead is a different chemical composition is considered that the difference in raw materials. These characteristics is expected to be an important evidence for the understanding of the trade system of the ancient glass.

A Study on Immoblization of Pepsin (��프신의 고정화(固定化)에 관한 연구(硏究))

  • Park, Jong Lae
    • Current Research on Agriculture and Life Sciences
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    • v.3
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    • pp.166-173
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    • 1985
  • Several enzyme immobilization methods has been compared for immobilization of pepsin. Carboxymethyl cellulose and diethylaminoethyl cellulose were activated with Hcl and with NaOH, and were used for immobilization of pepsin. Sepharose-4B was activated cyanogen bromide, and was used for immobilization of pepsin. Porous glass beads were derivatized with 3-aminopropyitrlethoxysilane and with succinicanhydride, and were used for immobilization of pepsin. The results abtained were summarized as follow, 1. 10 mg/gr. dry bead and 15mg/gr. dry bead of pepsin were absorbed to CM-cellulose and DEAE-cellulose, 20 mg/gr. dry bead and 27 mg/gr. dry bead were coupled to CM-cellulose and DEAE-cellulose with glutaraldehyde respectively. Enzyme yields were 22% and 24% of soluble pepsin. 2. 16 mg/gr. dry bead of pepsin was attached to cyanogen bromide activated sepharose-4B, 19mg/gr. dry bead was cross linked to the activated bead with glutaraldehyde. Immobilized enzyme activity was 23% of soluble pepsin. 3. 40 mg/gr. dry bead of pepsin was conjugated to the derivatized glass beads. Immobilized enzyme activity was 45% of soluble pepsin.

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Physical Properties and Preparation of HDPE Filled with Microencapsulated Glass Beads (마이크로 캡슐화된 Glass bead 충전 HDPE 복합재의 제조와 물리적 성질)

  • Kim, Dong-Kook;Kim, Kwang-Ho;Im, Seung-Soon;Noh, Si-Tae
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.430-439
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    • 1992
  • To improve the adhesion of interface and dispersion of glass beads in the composite, HDPE filled with glass brads, we encapsulated the g1ass beads with polymer by phase separation method using complex coacervation in organic solvent. EMAA and EAA were used as the polymeric wall materials. The microencapsulation efficiency and morphology were observed by thermogravimetric analysis and SEM, respectively. And also we investigated the physical and dynamic mechanical properties of the composite as the function of the beads contents and microencapsulation efficiency. Compared with the composite containing non-treated glass beads, the decrease in tensile strengthe of the composites containing the encapsulated glass beads become markedly small, and about 30~40% Increase in tensile modulus was observed. From the results of the dynamic mechanical analysis, it was found that the adhesion of interface and dispersion could be improved upon encapsulation.

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Effect of Frequency and Fixed Solid Catalyst for Radical Production in Sonocatalysis (초음파 촉매 공정에서 주파수와 고정된 고체 촉매가 라디칼 생성에 미치는 영향)

  • Cho, Eunju;Na, Seungmin;Lee, Seban;Khim, Jeehyeong
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.219-223
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    • 2012
  • The fixed solid catalysts such as glass bead, steel mesh, and $TiO_2$ coated ceramic bead were used to investigate effect of radical production at different frequencies. The radical production rate at 300 kHz was faster than that at 35 kHz without solid, but the tendency was changed with the presence of glass bead. The presence of glass beads create non-continuous points between the solid and liquid phases leading to increased formation of cavitation bubbles. However, the radical production decreased when steel mesh was used at 35 kHz although the surface area of contact with liquid was same when glass bead was used. Hence the solid catalyst did not always enhance the radical production. The radical production using $TiO_2$ coated ceramic bead was dramatically increased at 35 kHz due to the breakage of $TiO_2$ coated ceramic bead. Therefore the radical productions at 300 kHz using fixed solid catalysts generally increased while at 35 kHz the results fluctuated according to the experimental conditions.

Temperature Reduction of Concrete Pavement Using Glass Bead Materials

  • Pancar, Erhan Burak;Akpinar, Muhammet Vefa
    • International Journal of Concrete Structures and Materials
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    • v.10 no.1
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    • pp.39-46
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    • 2016
  • In this study, different proportions of glass beads used for road marking were added into the concrete samples to reduce the temperature gradient through the concrete pavement thickness. It is well known that decreasing the temperature gradient reduces the risk of thermal cracking and increases the service life of concrete pavement. The extent of alkali-silica reaction (ASR) produced with partial replacement of fine aggregate by glass bead was investigated and compressive strength of concrete samples with different proportion of glass bead in their mix designs were measured in this study. Ideal results were obtained with less than 0.850 mm diameter size glass beads were used (19 % by total weight of aggregate) for C30/37 class concrete. Top and bottom surface temperatures of two different C30/37 strength class concrete slabs with and without glass beads were measured. It was identified that, using glass bead in concrete mix design, reduces the temperature differences between top and bottom surfaces of concrete pavement. The study presented herein provides important results on the necessity of regulating concrete road mix design specifications according to regions and climates to reduce the temperature gradient values which are very important in concrete road design.

Photocatalytic Degradation of Benzene in the Gas Phase using TiO2 Coated on Ceramic and Glass Beads (세라믹과 유리에 코팅한 TiO2 광촉매를 이용한 가스상 벤젠의 제거)

  • 손현석;양원호;김현용;이소진;박종래;조경덕
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.1
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    • pp.57-66
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    • 2003
  • TiO$_2$ sol was prepared by sol-gel method, and this sol was coated in ceramic and glass bead by dip-coating method. The coated catalyst was applied to degrade benzene in the gas phase by exposing to UV -lamp (365 nm) in a batch reactor. The removal efficiency of the benzene was compared by changing various conditions such as the kind of chemical additives, the coating beads (ceramic and glass), solution pH, the initial concentration of TiO$_2$ sol, UV intensity, and benzene concentration. The physical structure of TiO$_2$ sol used in this study was found to be pu-rely anatase type from XRD analysis. The results showed that ceramic bead was effective as the coating agent rath-er than glass bead. The significant change in the benzene removal efficiency of benzene did not occur with chang-ing coating frequency and the initial concentration of TiO$_2$ sol. The removal efficiency of benzene increased with increasing UV intensity, and with acidic treatment of TiO$_2$-coated ceramic bead.

Verification Study on the Treasure #634 of Silla Face-Inlaid Glass Bead: Focusing on the Design and Cultural Symbolic Elements (보물 제634호 신라 인면 상감 유리구슬의 검증 연구: 디자인과 문화 상징요소를 중심으로)

  • Misuk Choi;Hyo Jeong Lee;Youngjoo Na
    • Science of Emotion and Sensibility
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    • v.26 no.4
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    • pp.71-92
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    • 2023
  • This study investigates the symbolism and meaning of the bead design, its relationship with the Silla culture, and the conditions of glass bead manufacturing to verify the theory of Silla's production of Silla face-inlaid glass beads with excellent artistry and technology. The research method includes investigating the design analysis, ancient documents, myths, relics, glass, and metal production techniques. Moreover, Hongshan cultural relics and other cases of inlaid glass beads were collected. There are records in the literature that the people of Makhan, Buyeo and Silla of ancient Korea people considered beads as treasures and used them for accessories. It was confirmed that all the design elements of the bead-patterned hair topknot, golden crown, birds, and flower trees were closely related to the myth of Kim Al-ji of Silla, the oviparous tales and the sacred birds and divine beasts of the north. Moreover, the pattern and arrangements were found to be similar in other Silla relics. The origin of beads and face pendants was Hongsan culture, and a stone cast for beads was discovered in Bukpyo of Gojoseon, the lower-level culture of Hajiajeom. In addition, excavating inlaid glass beads from Sik-ri tombs of Korea and a face-inlaid glass bead from Toganmori tombs in Japan confirms the theory of Silla's production. The fact that the Baekje people of ancient Korea had a glass bead manufacturing office in Japan in the fifth centuries suggests that the Silla people also had a manufacturing plant in Java, Indonesia, because this place was a crossroads of Silla's Sea Silk Road and a source of raw materials and labors with a close relationship to Silla. Therefore, the face-inlaid glass bead was indeed self-made by Silla, who possessed the tradition of bead myths and hair topknot, and the high-level skills such as gold crowns and metal inlays.

Analysis on Glass-Bead Type Retroreflector's Optical Characteristics (유리구슬형 재귀반사기의 광학적 특성 해석)

  • Lee, E.H.
    • Journal of the Korean Society for Precision Engineering
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    • v.11 no.4
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    • pp.165-173
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    • 1994
  • Retroreflector is different from other reflecting surfaces as it mades reflection in which radiation is returned in directions close to its incoming direction. Because of this characteristics, retroreflectors find many applications in traffic safety related areas. Retroreflectors are usually made using comer cubes, or partially coated glass beads. These glass beads can be made very small, so that they can be coated on sheets or mixed with paints. The design of glass type retroreflector depends on glass bead's shape and material, and its optical characteristics are related to the refractive index of glass. In this paper, a method of anlyzing glass bead type retroreflector's sptical characteristics with respect to shape and optica property of the glass, is presented. First, the coefficient of retroreflection, which is a measure of retroreflector's optical characteristics, is derived analytically using geometrical optics method. And the result is plotted using numerical methods. The results show good match with those obtained experimentally, which were supplied from a commercial retroreflector manufacturer.

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Killing Effects of $UV-TiO_2$ Photocatalytic System on Microorganisms ($UV-TiO_2$ 광촉매 반응기에 의한 미생물의 살균효과)

  • 김중곤;신용국;이영상;김용호;김시욱
    • Korean Journal of Microbiology
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    • v.37 no.2
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    • pp.130-136
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    • 2001
  • The killing effects of two types(one-phase reactor and two-phase reactor) of UV-TiO$_2$photocatalytic system on the microorganisms have been studied. The UV-lamp which emits maximum 39 watts at 254 nm was prepared in these system. Three types of $TiO_2$ coating method were adopted. One type is thin film coated form on the quartz tube in the reactor and another one is surface rough coated form on the glass bead. The other one is $TiO_2$-mixed alginate bead form. UV irradiation was carried out for 1 min. In case of one phase reactor, the bactericidal efficiencies of E. coli by $TiO_2$-coated quartz tube and $TiO_2$-coated glass bead were 63.2% and 89.9%, respectively. In the air-bubbling system, the bactericidal efficiency was 95%, however, the efficiency decreased to 90.6% in the non-bubbling system. In the $TiO_2$-mixed alginate bead system, bactericidal efficiency was 86%. When $H_2O$$_2$ was treated (10, 15, 20, and 25 mg/ι) to the $TiO_2$-coated glass bead reactor, bactericidal efficiency significantly increased according to the concentration of $H_2$$O_2$. Two phase reactor showed more elevated efficiency. E. coli was more sensitive to the reaction than S. cerevisiae.

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Trend in glass bead and regulation of road marking, and suggestions for preparing an autonomous vehicle age (도로표시 규정 및 글라스비드 동향과 자율주행차량 시대를 대비한 제언)

  • Kang, Byeongguk;Kang, Seunggu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.5
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    • pp.229-237
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    • 2019
  • For maintaining high visibility of lane, the high refractive index glass beads with excellent retro-reflectivity are usually applied on the road marking paint. The retro-reflectivity standard of general road marking is different in each country; it is defined as $240mcd/m^2{\cdot}lux$ based on white light in Korea and $250{\sim}300mcd/m^2{\cdot}lux$ in developed countries. In this paper, the recent trends on the manufacturing technology of glass beads suitable for autonomous driving age as well as the road marking regulations has been reviewed. Also, in preparation for the commercialization of autonomous vehicles in the future, the necessity of raising the standard value and improving the glass bead properties were proposed.