• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.666-671
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• 2012

Gas hydrates are inclusion compounds formed when small-sized guest molecules are incorporated into the well defined cages made up of hydrogen bonded water molecules. Since large masses of natural gas hydrates exist in permafrost regions or beneath deep oceans, these naturally occurring gas hydrates in the earth containing mostly $CH_4$ are regarded as future energy resources. The heat of dissociation is one of the most important thermal properties in exploiting natural gas hydrates. The accurate and direct method to measure the dissociation enthalpies of gas hydrates is to use a calorimeter. In this study, the high pressure micro DSC (Differential Scanning Calorimeter) was used to measure the dissociation enthalpies of methane, ethane, and propane hydrates. The accuracy and repeatability of the data obtained from the DSC was confirmed by measuring the dissociation enthalpy of ice. The dissociation enthalpies of methane, ethane, and propane hydrates were found to be 54.2, 73.8, and 127.7 kJ/mol-gas, respectively. For each gas hydrate, at given pressures the dissociation temperatures which were obtained in the process of enthalpy measurement were compared with three-phase (hydrate (H) - liquid water (Lw) - vapor (V)) equilibrium data in the literature and found to be in good agreement with literature values.

• Economic and Environmental Geology
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• v.41 no.3
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• pp.359-372
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• 2008

A number of researches on disaster risk reduction using the most advanced equipments and scientific technologies have been performed to minimize the damage of property and to protect human life. Although the Korean government is trying to enlarge the research area for disaster risk reduction, the investment size and the applicable results in this area have stayed in the lower level comparing to other scientific fields in Korea and the same field in advanced countries. However, the National Emergency Management Agency (NEMA), a government Agency which is responsible for disaster management coordination, was established in June 2004 establishing an efficient and well-organized system to cope with various disasters. In this study, investment size by the government was evaluated and associated areas were also identified. We also analyzed the roles on research and development for disaster risk reduction among different government Ministries were analyzed and role assignment to each Ministry was proposed. The role assignment has been concreted by conducting the process of approval in the government.

• Journal of the Korean Society of Marine Environment & Safety
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• v.13 no.1 s.28
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• pp.21-28
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• 2007

The purpose of this study was to observe the effect on the water quality and sediment environment by the use of Nano-S for anti-Red tide material. The experiment was performed at subtidal and intertidal zone during six months(from Aug 2005 to Feb. 2006). The experiment sites were divided with concentration of materials. One is lower concentration(0.1%) and the other is higher concentration(1%). The results of experiments didn't show the remarkable influence of the materials effect before and after applying the Nano-S and the red mud. pH, salinity and DO were slowly increased during experiment period but nutrients were conversely decreased in the seawater. In the subtidal zone, qualities of sediments, IL, AVS and COD, were gradually lowered and the similar results were appeared in the intertidal zone. These results showed similar trends over all the experiment sites including control site. The results of heavy metals also did not show the interest different effect before and after applying the Nano-S and red mud compared with control site.

• Journal of the Korean Geotechnical Society
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• v.29 no.1
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• pp.23-27
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• 2013

The risks of debris flows caused by climate change have increased significantly around the world. Recently, landslide disaster prevention technology is more focused on the failure and post-failure dynamics to mitigate the hazards in flow-prone area. In particular, we should define the soil strength and flow characteristics to estimate the debris flow mobility in the mountainous regions in Korea. To do so, we selected known ancient landslides area: Inje, Pohang and Sangju debris flows. Firstly we measured physical and mechanical properties: liquidity index and undrained shear strength by fall cone penetrometer. From the test results, we found that there is a possible relationship between liquidity index and undrained shear strength, $C_{ur}=(1.2/I_L)^{3.3}$, in the selected areas, even though they were different in geological compositions. Assuming that the yield stress is equal to the undrained shear strength at the initiation of sliding, we examined the flow characteristics of weathered soils in Korea. When liquidity index is given as 1, 1.5 and 3.0, the debris flow motion of weathered soils is compared with that of mud-rich sediments, which are known as low-activity clays. At $I_L=1$, it seems that debris flow could reach approximately 250m after 5 minutes. As liquidity index increased from 1 to 3, the debris flow propagation of weathered soils is twice than that of low-activity clays. It may be due to the fact that soil masses mixed with the ambient water and then highly fragmented during flow, thereby leading to the high mobility. The results may help to predict the debris flow propagation and to develop disaster prevention technology at similar geological settings, especially for the weathered soils, in Korea.

• Journal of the Korean Geotechnical Society
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• v.40 no.1
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• pp.29-37
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• 2024

In this study, recycled concrete aggregates (RCA) were treated in a 5-kg-scale prototype reactor with carbon dioxide (CO₂) to enhance their material quality and geotechnical performance. The aggregate crushing value (ACV) and California bearing ratio (CBR) were measured on untreated RCAs and CO₂-treated RCAs. After CO₂ treatment, the ACV decreased from 35.6% to 33.2%, and the CBR increased from 97.5% to 102.4%. The CO₂ treatment caused a reduction of fine particle generation and an increase in bearing capacity through carbonation. When CO₂ treatment was performed with mechanical agitation, which provided additional enhancement in mechanical quality, the ACV was reduced further to 30.3%, and the CBR increased to 137.7%. If upscaled effectively, the proposed CO₂ treatment technique would be an effective method to reduce carbon emissions in construction industries.

• The Journal of Engineering Geology
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• v.19 no.2
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• pp.153-163
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• 2009

In this study, a series of triaxial tests on Jeju basalt were carried out and then rock strength parameters were estimated by the Mohr-Coulomb failure criterion and the Hoek-Brown failure criterion using the test results. The characteristics of both failure criterions were investigated through comparing the estimated rock strength parameters. As the result of the Mohr-Coulomb criterion, the cohesions and the internal friction angles are determined as 5.35 MPa and $50.25^{\circ}$ of Pyoseonri basalt, 16.99 MPa and $60.66^{\circ}$ of Trachy-basalt, and 2.33 MPa and $37.05^{\circ}$ of Scoria, respectively. The cohesions and internal friction angles were estimated by the Hoek-Brown failure criterion in the basis of the results of regression analysis. The cohesions and the internal friction angles are determined as 4.77 MPa and $52.47^{\circ}$ of Pyoseonri basalt, 14.69 MPa and $60.70^{\circ}$ of Trachy-basalt, and 2.22 MPa and $47.60^{\circ}$ of Scoria, respectively. As the result of comparison between the Mohr-Coulomb failure criterion and the failure envelope predicted by the Hoek-Brown criterion, the cohesion estimated by the Hoek-Brown criterion is usually lower than that obtained from the Mohr-Coulomb criterion, whereas the friction angle estimated by the Hoek-Brown criterion is higher than that obtained from the Mohr-Coulomb criterion.

• Economic and Environmental Geology
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• v.51 no.2
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• pp.149-166
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• 2018

Many large earthquakes have continuously been reported and resulted in significant human casualties and extensive damages to properties globally. The accident of Fukushima nuclear power plant in Japan was caused by a mega-tsunami, which is a secondary effect associated with the Tohoku large earthquake (M=9.0, 2011. 3. 11.). Most earthquakes occur by reactivation of pre-existing active faults. Therefore, the importance of paleoseismological study have greatly been increased. The Korean peninsula has generally been considered to be a tectonically stable region compared with neighboring countries such as Japan and Taiwan, because it is located on the margin of the Eurasian intra-continental region. However, the recent earthquakes in Gyeongju and Pohang have brought considerable insecurity on earthquake hazard. In particular, this region should be secure against earthquake, because many nuclear facilties and large industrial facilities are located in this area. However, some large earthquakes have been reported in historic documents and also several active faults have been reported in southeast Korea. This study explains the evaluation methods of geological structures on active fault, fault damage zone, the relationship between earthquake and active fault, and respect distance. This study can contribute to selection of safe locations for nuclear facilities and to earthquake hazards and disaster prevention.

• Korean Journal of Remote Sensing
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• v.21 no.4
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• pp.341-369
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• 2005

Hyperspectral images have emerged as a new and promising remote sensing data that can overcome the limitations of existing optical image data. This study was designed to provide a comprehensive review on definition, data processing methods, and applications of hyperspectral data. Various types of airborne, spaceborne, and field hyperspectral image sensors were surveyed from the available literatures and internet search. To understand the current status of hyperspectral remote sensing technology and research development, we collected several hundreds research papers from international journals (IEEE Transactions on Geoscience and Remote Sensing, International Journal of Remote Sensing, Remote Sensing of Environment and AVIRIS Workshop Proceedings), and categorized them by sensor types, data processing techniques, and applications. Although several hyperspectral sensors have been developing, AVIRIS has been a primary data source that the most hyperspectral remote sensing researches were relied on. Since hyperspectral data have very large data volume with many spectral bands, several data processing techniques that are particularly oriented to hyperspectral data have been developed. Although atmospheric correction, spectral mixture analysis, and spectral feature extraction are among those processing techniques, they are still in experimental stage and need further refinement until the fully operational adaptation. Geology and mineral exploration were major application in early stage of hyperspectral sensing because of the distinct spectral features of rock and minerals that could be easily observed with hyperspectral data. The applications of hyperspectral sensing have been expanding to vegetation, water resources, and military areas where the multispectral sensing was not very effective to extract necessary information.

• Analytical Science and Technology
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• v.34 no.1
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• pp.23-35
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• 2021

In order to measure the volatile organic compounds (VOCs) of a sample which is too large to use commercially available chamber, a stainless steel vacuum chamber (VC) (with an internal diameter of 205 mm and a height of 50 mm) was manufactured and the temperature of the chamber was controlled using an oven. After concentrating the volatiles of the sample in the chamber by helium gas, it was made possible to remove residual volatile substances present in the chamber under reduced pressure ((2 ± 1) × 10-2 mmHg). The chamber was connected to a purge & trap (P&T) using a 6 port valve to concentrate the VOCs, which were analyzed by gas chromatography-mass spectrometry (GC-MS) after thermal desorption (VC-P&T-GC-MS). Using toluene, the toluene recovery rate of this device was 85 ± 2 %, reproducibility was 5 ± 2 %, and the detection limit was 0.01 ng L-1. The method of removing VOCs remaining in the chamber with helium and the method of removing those with reduced pressure was compared using Korean drinking water regulation (KDWR) VOC Mix A (5 μL of 100 ㎍ mL-1) and butylated hydroxytoluene (BHT, 2 μL of 500 ㎍ mL-1). In case of using helium, which requires a large amount of gas and time, reduced pressure ((2 ± 1) × 10-2 mmHg) only during the GC-MS running time, could remove VOCs and BHT to less than 0.1 % of the original injection concentration. As a result of analyzing volatile substances using VC-P&T-GC-MS of six types of cell phone case, BHT was detected in four types and quantitatively analyzed. Maintaining the chamber at reduced pressure during the GC-MS analysis time eliminated memory effect and did not affect the next sample analysis. The volatile substances in a cell phone case were also analyzed by dynamic headspace (HT3) and GC-MS, and the results of the analysis were compared with those of VC-P&T-GC-MS. Considering the chamber volume and sample weight, the VC-P&T configuration was able to collect volatile substances more efficiently than the HT3. The VC-P&T-GC-MS system is believed to be useful for VOCs measurement of inhomogeneous large sample or devices used inside clean rooms.

• The Journal of Engineering Geology
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• v.17 no.1 s.50
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• pp.125-133
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• 2007

The environmental and geotechnical properties are investigated to the 8th landfill area made of only sewage sludge in Nanji-Do. To do this, the soils are sampled in this area, and leaching tests, heavy metal content tests, and so on are performed to research the environmental properties. As the result of heavy metal content tests, Pb, Zn, Cu, Ni, Cd and Cr were leached from the sewage sludge. Because the leaching concentration of Cu is more than the standard value of California state, Cu content have to bring down during the recycling of the sewage sludge. Meanwhile, a series of tests concerning specific gravity, liquid and plastic limits, compaction, permeability and shear strength is performed to research the geotechnical properties. The sewage sludge is consisted of sand, silt and clay, and is classified into non-organic silt or organic clay with 42.3% of plastic index. As the result of compaction test, it is expected that the compaction effect according to variation of water contents is low relatively because the dry unit weight is low and the curve of compaction forms flatness. Also, as the result of direct shear tests, the cohesion is $0.058kg/cm^2$, and the internal friction angle is $14^{\circ}$. Taking everything into consideration, the various problems are happening in case of recycling the sludge like the cover layer of landfill and so on because the compaction is bad, and the shear strength is low. Also, it is expected that the ground water pollution caused by leaching the heavy metal into the sludge. To do recycling the sewage sludge in this site, supplementary and treatment programs should be prepared.