• Title/Summary/Keyword: geoscience and mineral resources technology

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Determination of fluoride in fluorite mine wastewater by ion chromatography with post-wash technique (후세척-이온크로마토그래피를 이용한 형석 광산 폐수 중 플루오라이드 정량)

  • Song, Kyung-Sun;Eum, Chul-Hun;Kim, Sang-Yeon
    • Analytical Science and Technology
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    • v.19 no.5
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    • pp.383-388
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    • 2006
  • Simple post-wash method by ion chromatography (IC) was established for the rapid and precise determination of fluoride ion in wastewater from mine in fluorite mineralized area. High sulfate in sample was retained in a pre-column and less strongly held fluoride ion was transferred to the principal separation system using modified conventional IC with switching technique. An analytical column with high capacity (AS 9 HC) was used as a pre-column to retain the amount of high sulfate. A guard column (AG 14) as a separation column was used to increase the response of fluoride and reduce the system pressure. According to the recovery of fluoride ion with one detector and the observation of sulfate peak with another conductivity detector, the optimum switching time of 10-port chromatographic injector was 4.3 min. The limit of detection (S/N = 3) of fluoride in synthetic solution containing $500mg\;L^{-1}$ sulfate was $2.4{\mu}g/L$, with $25{\mu}L$ sample volume.

Evaluating Shear Wave Velocity of Rock Specimen Through Compressional Wave Velocities Obtained from FFRC and Ultrasonic Velocity Methods (양단자유공진주 및 초음파속도법으로 획득한 압축파 속도를 이용한 암석시편의 전단파 속도 도출)

  • Bang, Eun Seok;Park, Sam Gyu;Kim, Dong Soo
    • Geophysics and Geophysical Exploration
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    • v.16 no.4
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    • pp.250-256
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    • 2013
  • Using shear wave velocity is more reasonable to estimate strength and integrity of rock compared with using compressional wave. It is often ambiguous to pick the dominant frequency caused by torsional wave when evaluating $V_S$ of rock specimen from FFRC method. It is also sometimes ambiguous to pick the first arrival point of S wave compared with P wave in the signals acquired from ultrasonic velocity method. Otherwise, the procedure of evaluating $V_P$ using ultrasonic velocity method and $V_L$ using FFRC method is relatively stable. Through the relationship between elastic modulus, poisson's ratio and $V_S$ can be obtained from $V_P$, $V_L$. Applicability was checked using model specimens having different material property and length and rock specimens sampled in mine area, and usefulness of proposed procedure was verified.

Properties and Recovery Technologies for Rare-Platinum Group using Patent Information (특허정보(特許情報)를 이용한 희소백금족(稀少白金族) 특성(特性)과 회수기술(回收技術))

  • Ahn, Jong-Gwan;Lee, Kang-Myoung;Lee, Jae-Ryeong
    • Resources Recycling
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    • v.18 no.4
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    • pp.3-13
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    • 2009
  • Rare platinum group (RPG)including rhodium, ruthenium, iridium, osmium, exists at the rate of 0.4 ppb or less in the earth's crust. For the purpose of suggestion to developing necessity for recycling technology with the RPG, survey on the characteristics and the recovery technologies was carried out by using patent information.

Origin of Organic Matter and Geochemical Variation of Upper Quaternary Sediments from the Ulleung Basin (울릉분지 상부 제4기 퇴적물의 유기물 기원 및 지화학적 분포)

  • Kim, Ji-Hoon;Park, Myong-Ho;Ryu, Byong-Jae;Lee, Young-Joo;Oh, Jae-Ho;Cheong, Tae-Jin;Chang, Ho-Wan
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.605-622
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    • 2007
  • Elemental, Rock-Eval pyrolysis and isotopic analysis of the core sediments from the northwestern and eastern Ulleung Basin of the East were carried out to identify their geochemical characteristics, spatial and vertical variation and origin of organic matter in Upper Quaternary sediments from the northwestern and eastern Ulleung Basin of the East Sea. TOC, m and TS did not show spatial variation between the sampling locations whereas they showed systematic vertical variation associated with MIS stages related to the sea-level change of the East Sea. It is suggested that these past changes of sea-level influenced the sedimentary depositional environments and/or diagenesis which resulted the patterns observed in this study. Based on the results of TOC/N, TS/TOC, ${\delta}^{13}C_{org}\;and\;{\delta}^{15}N_{org}$ analysis, organic matters in the study area appears to be predominantly originated from the marine algae rather than land plant and deposited under normal marine oxic condition during MIS I and MIS III period, and under euxinic/anoxic condition during MIS II period. TOC/N, ${\delta}^{13}C_{org}\;and\;{\delta}^{15}N_{org}$ have a relatively constant value irrespective of MIS stages, implying that the organic matter source does not change by the sea-level fluctuations. However, the results of Rock-Eval pyrolysis indicates that the organic matter is in immature stage and originated from land-plant (Type III), locating in the immature stage land plant (Type III). Similar differences were reported from other areas such as the Atlantic Ocean, Iberia Abyssal Plain, Mediterranean Sea, suggesting that Rock-Eval method does not exactly reflect the characteristic of immature organic matters. Accordingly, the application of Rock-Eval pyrolysis for delineating the source of immature organic matters should be approached with caution and all other geochemical proxies should be considered altogether at the same time.

Urban archaeological investigations using surface 3D Ground Penetrating Radar and Electrical Resistivity Tomography methods (3차원 지표레이다와 전기비저항 탐사를 이용한 도심지 유적 조사)

  • Papadopoulos, Nikos;Sarris, Apostolos;Yi, Myeong-Jong;Kim, Jung-Ho
    • Geophysics and Geophysical Exploration
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    • v.12 no.1
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    • pp.56-68
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    • 2009
  • Ongoing and extensive urbanisation, which is frequently accompanied with careless construction works, may threaten important archaeological structures that are still buried in the urban areas. Ground Penetrating Radar (GPR) and Electrical Resistivity Tomography (ERT) methods are most promising alternatives for resolving buried archaeological structures in urban territories. In this work, three case studies are presented, each of which involves an integrated geophysical survey employing the surface three-dimensional (3D) ERT and GPR techniques, in order to archaeologically characterise the investigated areas. The test field sites are located at the historical centres of two of the most populated cities of the island of Crete, in Greece. The ERT and GPR data were collected along a dense network of parallel profiles. The subsurface resistivity structure was reconstructed by processing the apparent resistivity data with a 3D inversion algorithm. The GPR sections were processed with a systematic way, applying specific filters to the data in order to enhance their information content. Finally, horizontal depth slices representing the 3D variation of the physical properties were created. The GPR and ERT images significantly contributed in reconstructing the complex subsurface properties in these urban areas. Strong GPR reflections and highresistivity anomalies were correlated with possible archaeological structures. Subsequent excavations in specific places at both sites verified the geophysical results. The specific case studies demonstrated the applicability of ERT and GPR techniques during the design and construction stages of urban infrastructure works, indicating areas of archaeological significance and guiding archaeological excavations before construction work.

Formative Age of Coastal Terraces and Uplift Rate in the East Coast of South Korea (우리나라 동해안의 해안단구 형성시기와 융기율)

  • Park, Chung-Sun;Kihm, You Hong;Nahm, Wook-Hyun;Lee, Gwang-Ryul
    • Journal of The Geomorphological Association of Korea
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    • v.24 no.4
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    • pp.43-55
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    • 2017
  • This study tries to examine papers on coastal terrace in the East Coast of South Korea and to summarize formative age and elevation of the terrace. Spatial and temporal variations of uplift rate in the Coast based on absolute age published are also reviewed. The terrace in the middle part in the Coast from Goseong to Samcheok distributes in an elevation of 10-20 m and its formative age is MIS 5a. The terraces during MIS 5e and 7 develop on an elevation of 20-35 m and 60-80 m, respectively. The mid-southern part in the Coast from Uljin to Yeongil Bay has the terraces with elevations of 10-25 m and 25-45 m and their ages are MIS 5a or 5c and 5e, respectively. The terraces with elevations of 10-25 m and 30-45 m correspond to MIS 5a and 5e, respectively, in the southern part in the Coast from Homigot to Busan. Assuming that elevation of sea level during the formation of each terrace is the same as in the present time, uplift rates in the Coast range from 0.05 to 1.36 m/ky with an average of approximately 0.33 m/ky. The highest and lowest rates since MIS 5 are found in the Gyeongju (approximately 0.39 m/ky) and Pohang (approximately 0.19 m/ky) areas. With a consideration of elevation of sea level at that time, however, the middle, midsouthern and southern parts in the Coast show uplift rates of 0.16-0.28 m/ky, 0.20-0.36 m/ky and 0.24- 0.36 m/ky since MIS 5, respectively, suggesting that the southern part in the Coast has experienced relatively higher uplift rate.

A Study on Advanced Geoscientific Research Activities Related to the Korean Peninsula by Foreign Geologists Prior to 1945 (해방이전 외국인에 의한 서구식 한반도 지질광상조사 성과고찰연구)

  • Kim, Seong-Yong;Lee, Jae-Wook
    • Economic and Environmental Geology
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    • v.48 no.1
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    • pp.77-88
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    • 2015
  • Advanced geological surveys and exploration activities were first carried out in Korea in 1884 in accordance with a treaty of friendship and commerce between Great Britain and Korea and a treaty of friendship and commerce between Germany and Korea. The first paper by Gottsche, C. was also published in a German Journal in 1886. Efforts toward independent acquisition of Western geological survey and exploration technology were actively promoted by the Korean Empire in the early 1900s, but were frustrated by the Japanese Empire. Systematic geological surveys and exploration were conducted in Korea by Japanese geologists during the Japanese occupation. A basic geological maps(61sheets), a bulletin on the geological survey of Korea, a bulletin and technical report on deposits in Korea, and a coalfield geological survey report were published during this period. Overall, the intentions under lying the geological surveys and exploration activities by foreigners in Korea prior to the Japanese occupation were questionable. However, the results of these surveys and explorations themselves can be evaluated as positive in terms of academic performance.

Numerical Simulation of Triaxial Compression Test Using the GREAT Cell: Hydro-Mechanical Experiment (GREAT 셀을 이용한 삼축압축시험의 수치모사: 수리역학 실험)

  • Dohyun Park;Chan-Hee Park
    • Tunnel and Underground Space
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    • v.33 no.2
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    • pp.83-94
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    • 2023
  • Unlike the conventional triaxial test cells for cylindrical specimens, which impose uniform lateral confining pressures, the GREAT (Geo-Reservoir Experimental Analogue Technology) cell can exert differential radial stresses using eight independently-controlled pairs of lateral loading elements and thereby generate horizontal stress fields with various magnitudes and orientations. In the preceding companion paper, GREAT cell tests were numerically simulated under different mechanical loading conditions and the validity of the numerical model was investigated by comparing experimental and numerical results for circumferential strain. In the present study, we simulated GREAT cell tests for an artificial sample containing a fracture under both mechanical loading and fluid flow conditions. The numerical simulation was carried out by varying the mechanical properties of the fracture surface, which were unknown. The numerical responses (circumferential strains) of the sample were compared with experimental data and a good match was found between the numerical and experimental results under certain mechanical conditions of the fracture surface. Additionally, the effect of fluid flow conditions on the mechanical behavior of the sample was investigated and discussed.

The Estimation of Weight of Attributes of Geological & Thematic Maps Using the AHP Method (AHP분석을 통한 지질도 및 주제도의 가치구성요소별 중요도 분석)

  • Kim, Dae-Hyung;Kim, Ji-Whan;Kim, Jin-Soo;Heo, Eunn-Yeong
    • Economic and Environmental Geology
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    • v.41 no.5
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    • pp.517-526
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    • 2008
  • Geological and related thematic maps make various economical and social benefits at many sectors. Recently, development of information managing technology such as GIS, Geographic Information System, enlarges the usage of geological map and information. In this research, using the Analytic Hierarchy Process, we analyzed the weight of attributes which compose value of geological map and information. Results of research are as follows. By the analysis of the weight of attributes, we found that the weight of confidence, upper hierarchy attribute, was above 50%. The weight of convenience and additional effect was about $16%{\sim}30%$ in the geological map, geophysical map, geochemical map and hydrogeologic map. And the consumption of each maps will increase, especially in large scale map.

Numerical Simulation of Triaxial Compression Test Using the GREAT Cell: Preliminary Study (GREAT 셀을 이용한 삼축압축시험의 수치모사: 예비연구)

  • Park, Dohyun;Park, Chan-Hee
    • Tunnel and Underground Space
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    • v.32 no.3
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    • pp.219-230
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    • 2022
  • The Geo-Reservoir Experimental Analogue Technology (GREAT) cell was designed to recreate the thermal-hydro-mechanical conditions of deep subsurface in the laboratory. This apparatus can generate a polyaxial stress field using lateral loading elements, which rotate around the longitudinal axis of a sample and is capable of performing a fluid flow test for samples containing fractures. In the present study, numerical simulations were carried out for triaxial compression tests using the GREAT cell and the mechanical behavior of samples under different conditions of lateral loading was investigated. We simulated an actual case, in which triaxial compression tests were conducted for a polymer sample without fractures, and compared the results between the numerical analysis and experiment. The surface strain (circumferential strain) of the sample was analyzed for equal and non-equal horizontal confining pressures. The results of the comparison showed a good consistency. Additionally, for synthetic cases with a fracture, we investigated the effect of the friction and type of fracture surface on the deformation behavior.