• Geosystem Engineering
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• v.21 no.5
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• pp.262-272
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• 2018

The U-statistic method is one of the most important structural methods to separate the anomaly from background. It considers the location of samples and carries out the statistical analysis of the data without judging from a geochemical point of view and tries to separate subpopulations and determine anomalous areas. In the present study, 3D U-statistic method has been applied for the first time through the three-dimensional (3D) modeling of an ore deposit. In order to achieve this purpose, 3D U-statistic is applied on the data (Fe grade) resulted from the drilling network in Baghak mine, central part of the Sangan iron mines (in Khorassan Razavi Province, Iran). Afterward, results from applying 3D U-statistic method are used for 3D modeling of the iron mineralization. Results show that the anomalous values are well separated from background so that the determined samples as anomalous are not dispersed and according to their positioning, denser areas of anomalous samples could be considered as anomaly areas. And also, final results (3D model of iron mineralization) show that output model using this method is compatible with designed model for mining operation. Moreover, seen that U-statistic method in addition for separating anomaly from background, could be very efficient for the 3D modeling of different ore type.

• The Journal of Engineering Geology
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• v.26 no.1
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• pp.1-13
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• 2016

Groundwater flow paths and groundwater ages at a radioactive waste repository located in a coastal area of South Korea were evaluated using the hydrochemical and hydrogeological characteristics of groundwater, surface water, rain water, and seawater, as well as by numerical modeling. The average groundwater travel time in the top layer of the model, evaluated by numerical modeling and groundwater age (34 years), approximately corresponds to the groundwater age obtained by chlorofluorocarbon (CFC)-12 analysis (26-34 years). The data suggest that the groundwater in wells in the study area originated up-gradient at distances of 140-230 m. Results of CFC analyses, along with seasonal variations in the δ¹⁸O and δD values of groundwater and the relationships between ²²²Rn concentrations and δ¹⁸O values and between ²²²Rn concentrations and δD values, indicate that groundwater recharge occurs in the summer rainy season and discharge occurs in the winter dry season. Additionally, a linear relationship between dissolved SiO₂ concentrations and groundwater ages indicates that natural mineralization is affected by the dilution of groundwater recharge in the rainy summer season.

• Economic and Environmental Geology
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• v.12 no.4
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• pp.207-221
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• 1979

The studied area occupies the southern part of Haenam peninsula located in the southwestern corner of Korea. The stratigraphic sequences of the area are grouped into following three units in ascending order. (1) Late Cretaceous sedimentary rocks of Uhangri Formation which consist of the alternative beds of black shales and tuffaceous sediments, Hwangsan acidic fine grained tuffs and Jindo rhyolite flows. (2) Late Cretaceous biotite granite and acidic porphyries which intruded the Late Cretaceous sedimentary rocks. (3) Tertiary(?) pitchstone. The study purposes to delineate any of geochemical aspects on the deposition of the sequences, the average amounts of organic materials and the effect to the maturation of hydrocarbonization which has been occured by the intrusives. Sixty nine black shale samples were collected from Uhangri Formation in the northern and southern coasts of the peninsula. Organic carbons, total extracted organic matters and hydrocarbons were mainly determined by the Soxhlet extraction method, together with C-H-N elemental analyses. Based on the field and laboratory studies, the following interpretations have been obtained. (1) The paleohydrostatic condition of the sedimentation which took place was relatively calm and stable to delineate a lacustrine environment. (2) The amounts of organic material were more or less constant throughout the period of the deposition of the sediments. (3) The degree of hydrocarbonization of the Uhangri Formation in the northern coast was taken place higher than that in the southern coast due to the differences of thermal effect by the biotite granite which is assumed to be as a heat source in the area. Among the northern coast, some black shales in Uhangri and Mogsam areas which had been under the most moderate temperature environment snow symptomatic oily material, whereas, those in Sinseongri area do not, which were presumably to be intensive thermal alteration by the later acidic porphyries.

• Economic and Environmental Geology
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• v.12 no.2
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• pp.79-93
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• 1979

Twenty five samples of the scheelite-powellite series from twelve Korean tungsten deposits of various geologic settings were studied mineralogically and geochemically. Variations in the trace-element contents of the scheelite minerals are considered in relation to geologic settings and mineralogic properties. Scheelites from ore deposits developed in similar geologic settings and under similar physicochemical conditions are characterized by specific combinations of trace elements.

• Journal of The Geomorphological Association of Korea
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• v.23 no.3
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• pp.79-92
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• 2016

Samples from two boreholes of coastal dune field at Jangho-ri coast, Gochang was studied. These were analyzed by grain size analysis geochemical analysis, and the application of OSL dating method to understand the development during the Holocene. The boreholes SB8 and SB9 were classified into three different sedimentary layers by their mean grain size and geochemical characteristics. The results revealed that the upper sand layer is equivalent to the present coastal dune layer, which developed since 1,200 years ago; the silt layer in the middle to the dune slack or lagoon sedimentation layer, which developed between 1,200 and 6,000 years ago; and the sand layer at the bottom to the paleo coastal dune that developed between 6,000 and 7,000 years ago. It was proposed that the forming material of current coastal dune was supplied from the sandy flat in coastal area, while the middle silt layer was supplied from the weathered soil of a bed rock by the comparison with material of surrounding area. In the case of coastal dune, concentrated layer of sands were identified which were buried about 300 and 1,200 years ago, which is identified as the little ice age. This study confirmed the development of Jangho-ri coastal dunes after Holocene Climate Optimum period, and it is likely to assist in the understanding of coastal dunes development.

• Nuclear Engineering and Technology
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• v.25 no.1
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• pp.154-165
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• 1993

A stochastic method using continuous time Markov process is presented to model the one-dimensional convective nuclide transport in geologic media, which have usually heterogeneous feature in physical/geochemical parameters such as velocity, dispersion coefficient, and retardation factor resulting poor description by conventional deterministic advection-dispersion model. The primary desired quantities from a stochastic model are the mean values and variance of the state variables as a function of time. The time-dependent probability distributions of nuclides are presented for each discretized compartment given the volumetric groundwater flux and the intensity of transition. Since this model is discrete in medium space, physical/geochemical parameters which affect nuclide transport can be easily incorporated for the heterogeneous media as well as remarkably layered media having spatially varied parameters. Even though the Markov process model developed in this study was shown to be sensitive to the number of discretized compartments showing numerical dispersion as the number of compartments are increased, this could be easily calibrated by comparing with the analytical deterministic model.

• Journal of Soil and Groundwater Environment
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• v.24 no.1
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• pp.10-16
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• 2019

Alkalinity is an essential parameter for understanding geochemical processes and calculating partial pressure of $CO_2$, dissolved inorganic carbon, and mineral saturation indices. The Gran Titration Method (GTM) is one of the most accurate methods for measuring the alkalinity in water samples. However, this method has not been widely employed in measuring groundwater alkalinity in Korea, probably due to inadequate and insufficient understanding of the method. In this regard, this article was prepared to introduce GTM and related know-hows learned from the authors' experiences in measuring alkalinity. This paper also introduces a MS Excel-based alkalinity calculator as a handy tool for GTM.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.4
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• pp.307-327
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• 2008

Geochemical study on the rocks and minerals of the Gyeongju low and intermediate level waste repository was carried out in order to provide geochemical data for the safety assessment and geochemical modeling. Polarized microscopy, X-ray diffraction method, chemical analysis for the major and trace elements, scanning electron microscopy(SEM), and stable isotope analysis were applied. Fracture zones are locally developed with various degrees of alteration in the study area. The study area is mainly composed of granodiorite and diorite and their relation is gradational in the field. However, they could be easily distinguished by their chemical property. The granodiorite showed higher $SiO_2$ content and lower MgO and $Fe_2O_3$ contents than the diorite. Variation trends of the major elements of the granodiorite and diorite were plotted on the same line according to the increase of $SiO_2$ content suggesting that they were differentiated from the same magma. Spatial distribution of the various elements showed that the diorite region had lower $SiO_2,\;Al_2O_3,\;Na_2O\;and\;K_2O$ contents, and higher CaO, $Fe_2O_3$ contents than the granodiorite region. Especially, because the differences in the CaO and $Na_2O$ distribution were most distinct and their trends were reciprocal, the chemical variation of the plagioclase of the granitic rocks was the main parameter of the chemical variation of the host rocks in the study area. Identified fracture-filling minerals from the drill core were montmorillonite, zeolite minerals, chlorite, illite, calcite and pyrite. Especially pyrite and laumontite, which are known as indicating minerals of hydrothermal alteration, were widely distributed in the study area indicating that the study area was affected by mineralization and/or hydrothermal alteration. Sulfur isotope analysis for the pyrite and oxygen-hydrogen stable isotope analysis for the clay minerals indicated that they were originated from the magma. Therefore, it is considered that the fracture-filling minerals from the study area were affected by the hydrothermal solution as well as the simply water-rock interaction.

• The Korean Journal of Malacology
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• v.29 no.1
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• pp.51-63
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• 2013

To assess the effect of environmental factors on the sustainability of cultured production shellfish, we investigated the habitat characteristics of tidal flat (Namhae-po in Taean). We measured the physiochemical parameters (temperature, salanity, pH, dissolved oxygen and nutrients) and the geochemical characteristics (chemical oxygen demand, ignition loss, C/N ratio and C/S ratio). Surface sediments were collected from several site of tidal flat to examine the geochemical characteristics of both the benthic environment and heavy metal pollution. The grain size for research area of tidal flat were similar at the ratio of silt and clay in comparison with the other site of it. The C/N ratio was more than 5.0, reflecting the range arising from the mix of marine organism and organic matter. The C/S ratio (about 2.8) showed that survey area had anoxic or sub-anoxic bottom conditions. The enrichment factor (Ef) and index of accumulation rate (Igeo) of the metals showed that those research areas can be classified as heavily polluted, heavily to moderately polluted, or more or less unpolluted, respectively. Adult surf clam (Mactra veneriformis) density was highest at St. 2 (middle part of the Namhae-po), on the other hand, surf clam spat density was highest at St. 3 (lower part of the Namhae-po). Heavy rain, terrigenous suspended clay with fresh water from neighboring agricultural land, and severe high air temperature during summer could be thought as detrimental causes of spat and adult mortality in Namhae-po tidal flat. We suggested that the growth of shellfish in the tidal flat was effected by the various environmental conditions, so an improvement in the cultured method was needed.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.2
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• pp.121-131
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• 2021

Magnesium (Mg) present in carbonate minerals as impurities has been used as a geochemical proxy to infer the environmental conditions where the minerals precipitated. The reliability of Mg geochemical proxies requires fundamental understanding of Mg incorporation into minerals based on accurate speciation of Mg ²⁺ in the crystal structure, which is determined mainly by application of X-ray absorption spectroscopy (XAS). However, high uncertainties are involved in interpreting the XAS spectra of minerals containing trace amount of Mg ²⁺. Because density function theory (DFT) can predict an XAS spectrum for a crystal structure, DFT calculations can reduce the uncertainties in the interpretation of the XAS spectrum. In this study, we calculated ab initio Mg K-edge absorption spectra of Mg silicates and (hydr)oxides based on DFT and analyzed the correlation between the calculated spectra and Mg structural parameters. Our ab initio Mg K-edge absorption spectra well reproduced the key features of the experimental spectra. The absorption-edge positions of the calculated spectra showed the weak positive correlation with the average Mg-O bond distance or Mg effective coordination number. The current study shows that DFT-based core-level spectroscopy method is a powerful tool in providing standard Mg K-edge spectra of diverse Mg minerals and determining the Mg chemical species within carbonate minerals.