• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.6 no.2
• /
• pp.71-80
• /
• 2001

To understand paleoceanographic environmental changes in the Esat Sea during the transitional period between Holocene and last glacial maximum, geochemical high resolution study was conducted by using a piston core(95PC-1) samples collected from the southernmost part of the Ulleung Basin. Geochemical results reveal that major distinctive paleoceanographic variations in transitional period are prominent. Major elemental concentrations show distinctive variations between glacial and Holocene suggesting changes in sediment supply. $TiO_2/Al_2O_3$ ratio of the sediment indicates different sediment composition between Holocene and glacial period. The content of total organic carbon ranging from 0.5% to 4% during transitional period. These vslues showed 2-4 times and two times higher than those of last glacial and Holocene, respectively. The C/N ratios deduced from organic matters exceed10 during transitional period suggesting terrigenous organic matter are supplied from continent, especially during last glacial maximum. Carbonate contents are relatively stable during Holocene and last glacial maximum with gradual decrease during glacial period with high fluctuation during transitional period. The variations of chemical index of weathering (CIW) also show a distinctive variation between glacial and Holocene, which is coincident with those of carbonate and organic carbon. The grain size distribution indicates that the difference content of silt fraction during Holocene and glacial period is closely related with climatic effect during glacial period. Therefore geochemical differences in sediment composition between Holocene and last glacial maximum is thought to be related to paleoceanographic, sea-level change and local paleoclimatic changes.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.10 no.3
• /
• pp.189-197
• /
• 2012

Geochemical composition of fracture filling minerals and groundwater was investigated to characterize geochemical characteristics of groundwater system at the KURT site. Minerals such as calcite, illite, laumontite, chlorite, epidote, montmorillonite, and kaolinite, as well as I/S mixed layer minerals were detected in the minerals extracted from the fracture surfaces of the core samples. The groundwater from the DB-1, YS-1 and YS-4 boreholes showed alkaline conditions with pH of higher than 8. The electrical conductivity (EC) values of the groundwater samples were around $200{\mu}S/cm$, except for the YS-1 borehole. Dissolved oxygen was almost zero in the DB-1 borehole indicating highly reduced conditions. The Cl- concentration was estimated around 5 mg/L and showed homogeneous distribution along depths at the KURT site. It might indicate the mixing between shallow groundwater and deep groundwater. The shallow groundwater from boreholes showed $Ca-HCO_3$ type, whereas deep groundwater below 300 m from the surface indicated $Na-HCO_3$ type. The isotopic values observed in the groundwater ranged from -10.4 to -8.2‰ for ${\delta}^{18}O$ and from -71.3 to -55.0‰for ${\delta}D$. In addition, the isotope-depleted water contained higher fluoride concentration. The oxygen and hydrogen isotopic values of deep groundwater were more depleted compared to the shallow groundwater. The results from age dating analysis using $^{14}C$ indicated relatively younger (2000~6000yr old) groundwater compared to other european granitic groundwaters such as Stripa (Sweden).

• Korean Journal of Mineralogy and Petrology
• /
• v.35 no.4
• /
• pp.409-421
• /
• 2022

Achieving a highly resolved spatial distribution of Mn-bearing minerals and elements in the natural ferromanganese nodules can provide detailed knowledge of the temporal variations of geochemical conditions affecting the formation processes of nodules. While a recent study utilizing Raman spectroscopy has reported the changes in the manganate mineral phases with growth for spherical nodules from the Arctic Sea, the distributions of minerals and elements in the nodules from the shallow Arctic Sea with non-spherical forms have not yet fully elucidated. Here, we reported the micro-laser Raman spectra with varying data acquisition points along three different profiles from the center to the outermost rim of the non-spherical ferromanganese nodules collected from the East Siberian Sea (~73 m). The elemental distributions in the nodule (such as Mn, Fe, etc.) were also investigated by energy dispersive X-ray spectroscopy (EDS) analysis to observe the internal structure and mineralogical details. Based on the microscopic observation, the internal structures of a non-spherical nodule can be divided into three different regions, which are sediment-rich core, iron-rich substrate, and Mn-Fe layers. The Raman results show that the Mn-bearing mineral phases vary with the data acquisition points in the Mn-Fe layer, suggesting the changes in the geochemical conditions during nodule formation. In addition, we also observe that the mineral composition and structural characteristics depend on the profile direction from the core to the rim. Particularly, the Raman spectra obtained along one profile show the lack of Fe-(oxy)hydroxides and the noticeably high crystallinity of Mn-bearing minerals such as birnessite and todorokite. On the other hand, the spectra obtained along the other two profiles present the presence of significant amount of amorphous or poorly-ordered Fe-bearing minerals and the low crystallinity of Mn-bearing minerals. These results suggest that the diagenetic conditions varied with the different growth directions. We also observed the presence of halite in several layers in the nodule, which can be evidence of the alteration of seawater after nodule formation. The current results can provide the opportunity to obtain detailed knowledge of the formation process and geochemical environments recorded in the natural non-spherical ferromanganese nodule.

• 한국지구물리탐사학회:학술대회논문집
• /
• 2003.11a
• /
• pp.344-351
• /
• 2003

Hydrogeological survey and geochemical analysis were carried out in Phra Yun area, Northeast Thailand, which is a typical salt-affected area for an understanding of hydrogeological groundwater behaviours. Geological survey reveals the presence of G1 and F1 faults. Electromagnetic ground conductivity prospecting shows that the high conductivity zones of 15 mS/cm or more are distributed at underground of the G1 and F1 faults where saline groundwater is discharged. The distribution patterns of tritium concentration show that high tritium concentration zones of groundwater were recharged from pond and river. On the assumption that the annual average tritium concentration of precipitation in Northeast Thailand is same as tritium concentration of precipitation in Tokyo and groundwater flows as piston flow, the age of recharging precipitation of groundwater with 15 TU in 1997 could be estimated at 1967-1970 years. The velocity of groundwater flow was calculated to be $5.3{\times}10^{-7}\;m/s\;and\;2.1{\times}x10^{-6}\;m/s$ respectively from a duration time of 30 years and distance of groundwater flow 500m -2000m from the pond and river to the investigation wells. Because the estimated values of velocity of groundwater flow are compatible with the hydraulic conductivities, it is considered that 30 years is a reasonable period for recharging groundwater.

• Geophysics and Geophysical Exploration
• /
• v.7 no.1
• /
• pp.99-104
• /
• 2004

A combination of drilling, geophysical well logging, and electrical soundings was performed to evaluate seawater intrusion in Baeksu-eup, Youngkwang-gun, Korea. The survey area extends for over 24 $km^2$. To delineate the extent of seawater intrusion, 60 vertical electrical soundings (VES) have been carried out. Twelve wells were also drilled for the collection of hydrogeological, geochemical, and geophysical well logging data, to delineate the degree and vertical extent of seawater intrusion. To map the spatial distribution of seawater in this coastal aquifer, geophysical data and hydrogeochemical results were used, and the relation between the resistivity of groundwater and equivalent NaCl concentration was found. Layer parameters derived from VES data, various in-situ physical properties from geophysical well logging, and the estimated equivalent NaCl concentration were very useful for quantitative evaluation of seawater intrusion. Our approach for evaluating seawater intrusion can be considered a valuable attempt at enhancing the use of geophysical data.

• Nuclear Engineering and Technology
• /
• v.55 no.8
• /
• pp.2889-2896
• /
• 2023

The waste acceptance criteria for heavy metals in mixed waste should be developed by reflecting the leaching behaviors that could highly depend on the repository design and environment surrounding the waste. The current standards widely used to evaluate the leaching characteristics of heavy metals would not be appropriate for the silo-type repository since they are developed for landfills, which are more common than a silo-type repository. This research aimed to explore the leaching behaviors of cementitious waste with Pb, Cd, and Sb metallic and oxide powders in an environment simulating a silo-type radioactive waste repository. The Toxicity Characteristic Leaching Procedure (TCLP) and the ANS 16.1 standard were employed with standard and two modified solutions: concrete-saturated deionized and underground water. The compositions and elemental distribution of leachates and specimens were analyzed using an inductively coupled plasma optical emission spectrometer (ICP-OES) and energy-dispersive X-ray spectroscopy combined with scanning electron microscopy (SEM-EDS). Lead and antimony demonstrated high leaching levels in the modified leaching solutions, while cadmium exhibited minimal leaching behavior and remained mainly within the cement matrix. The results emphasize the significance of understanding heavy metals' leaching behavior in the repository's geochemical environment, which could accelerate or mitigate the reaction.

• The Journal of the Petrological Society of Korea
• /
• v.21 no.2
• /
• pp.203-216
• /
• 2012

Based on the petrologic and age data of the Cretaceous to early Tertiary granites in south Korea, we propose a new tectonic model reflecting their temporal and spatial variations. A number of petrographic and geochemical studies on the granites suggest that they originated from the magma formed by subduction of oceanic crust in continental margin and were emplaced in epizone. The MMEs with various shapes and sizes, which were produced due to the magma mixing caused by the injection of mafic magma from mantle during the crystallization of the granitic magma, are observed in the granites. The distributions of the MMEs and ages of the granites show a distinctive spatio-temporal distribution pattern. The distribution pattern can be explained by a multiple slab window model related to the ridge subduction of Izanagi-Pacific plates during the Late Cretaceous.

• Ocean and Polar Research
• /
• v.25 no.4
• /
• pp.447-457
• /
• 2003

In order to understand the distribution of changes of geochemical characteristics in surface sediments according to various environmental changes around the artificial Lake Shihwa, surface sediments were sampled at $13{\sim}15$ sites form 1997 to 1999 and analyzed by C/S analyzer, ICP/MS and AAS. The average $S/C_{org}$ ratio was 0.35 in the surface sediments, which is similar to 0.36, the characteristic ratio of marine sediments. Heavy metal contents and enrichment factors in the surface sediments tended to be decreasing from the head to the mouth of the Lake Shihwa. With the deposition of fine-grained sediments in the central part of lake, anoxic water column induced the sulfides compounds with Cu, Cd and Zn. Metals such as Al, Fe, Cr, Co, Ni, Cu, Zn and Cd except for Mn and Pb showed relatively high correlation coefficients among them. The contents of Cr, Co, Ni, Cu, Zn and Cd in the surface sediments of the lake were two to five times higher than those in the lake before dike construction and also in outer part of the dike. These are mainly due to the Input of untreated industrial and municipal waste-waters into the lake, and the accumulation of heavy metals by limitation of physical mixing. Although metal contents of the surface sediments at the sites near the water-gate due to outer seawater inflow tended to be lower than those during the desalination, heavy metals were deposited in areas around the new industrial complex in the evidence of spatial distribution of heavy metals in the sediments. This is mainly due to the input of untreated waste-waters from tributaries.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.45 no.6
• /
• pp.694-703
• /
• 2012

To understand the characteristics of sedimentary and benthic environments in habitats of naturally-occurring intertidal benthic macroalgae, various geochemical parameters of sediment (grain size, ignition loss [IL], chemical oxygen demand [COD], and acid volatile sulfur [AVS]) and pore water (temperature, salinity, pH, and nutrients) were measured in the southern intertidal zone of Hampyeong Bay at two month intervals from April to October 2009. Ecological characteristics including the distribution and biomass of benthic macroalgae were also investigated. Benthic macroalgae were distributed below 4 to 5 m depth from mean sea level near the lower portion of the intertidal zone where air exposure time is relatively short. The distribution area and biomass of benthic macroalgae gradually decreased during the study period. The surface sediments in the benthic algal region were mainly composed of finer sediments, such as slightly gravelly mud and mud. The temperature, salinity, pH, and nutrient concentrations (except dissolved inorganic nitrogen) in pore water did not differ in regions with and without benthic macroalgae, whereas the mean grain size and the concentrations of IL, COD, and AVS in sediments were much higher in regions harboring benthic macroalgae. The correlation between mean grain size and IL in sediments displayed two distinct gradients and the slope was much steeper in regions harboring benthic macroalgae, indicating that the content of organic matter in benthic algal region is not solely dependent on mean grain size. Our results indicate that the benthic macroalgae in the southern intertidal zone of Hampyeong Bay play an important role in the accumulation of organic matter in sediment.

• Proceedings of KOSOMES biannual meeting
• /
• 2008.05a
• /
• pp.159-164
• /
• 2008

In order to understand the spatio-temporal distribution of geochemical parametrs in surface sediments of the artificial Lake Shihwa in the vicinity of Kyunggi Hay in Korea, surface sediments were sampled at 14 sites in July 2007 and analyzed by CHN analyzer and ICP/MS. Metal concentrations in the sediments tended to be decreasing from the head to the mouth of the Lake Shihwa because of extreme pollutant discharge from various kinds of anthropogenic sources such as the Banweol and Shihwa Industrial Complex and cities. With the deposition of fine-grained sediments, high metal concentrations were also observed in the central part of lake. Although various programs(improvement of wastewater collection and treatment system, sea-lake water exchange etc) to improve the environmental conditions around the Lake Shihwa after dike construction were carried out, it was not dear to reach a good environmental quality. Therefore, further environmental programs should be conducted continuously for environmental improvement.