• Korean Journal of Mineralogy and Petrology
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• v.35 no.4
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• pp.409-421
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• 2022

Achieving a highly resolved spatial distribution of Mn-bearing minerals and elements in the natural ferromanganese nodules can provide detailed knowledge of the temporal variations of geochemical conditions affecting the formation processes of nodules. While a recent study utilizing Raman spectroscopy has reported the changes in the manganate mineral phases with growth for spherical nodules from the Arctic Sea, the distributions of minerals and elements in the nodules from the shallow Arctic Sea with non-spherical forms have not yet fully elucidated. Here, we reported the micro-laser Raman spectra with varying data acquisition points along three different profiles from the center to the outermost rim of the non-spherical ferromanganese nodules collected from the East Siberian Sea (~73 m). The elemental distributions in the nodule (such as Mn, Fe, etc.) were also investigated by energy dispersive X-ray spectroscopy (EDS) analysis to observe the internal structure and mineralogical details. Based on the microscopic observation, the internal structures of a non-spherical nodule can be divided into three different regions, which are sediment-rich core, iron-rich substrate, and Mn-Fe layers. The Raman results show that the Mn-bearing mineral phases vary with the data acquisition points in the Mn-Fe layer, suggesting the changes in the geochemical conditions during nodule formation. In addition, we also observe that the mineral composition and structural characteristics depend on the profile direction from the core to the rim. Particularly, the Raman spectra obtained along one profile show the lack of Fe-(oxy)hydroxides and the noticeably high crystallinity of Mn-bearing minerals such as birnessite and todorokite. On the other hand, the spectra obtained along the other two profiles present the presence of significant amount of amorphous or poorly-ordered Fe-bearing minerals and the low crystallinity of Mn-bearing minerals. These results suggest that the diagenetic conditions varied with the different growth directions. We also observed the presence of halite in several layers in the nodule, which can be evidence of the alteration of seawater after nodule formation. The current results can provide the opportunity to obtain detailed knowledge of the formation process and geochemical environments recorded in the natural non-spherical ferromanganese nodule.

• Geophysics and Geophysical Exploration
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• v.17 no.2
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• pp.58-65
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• 2014

We studied the source mechanisms of very-long-period event recorded at seismic station WIZ near White Island Volcano, New Zealand on August 4, 2012. Since seismic data at only one station were available, we conducted moment tensor inversion using three simplified models (explosion, crack, and pipe models). To constrain the moment tensor solution of seismic event, we computed synthetic data for each model to compare with observed data. Type and orientation for the best model is a crack at a depth of 1600 m with a dip of $80^{\circ}NE$ and a strike of $N80^{\circ}W$. We interpret that a deep explosion may have opened a crack for gases to escape, and the upward gas flow triggered the surface explosions four hours later as confirmed by a webcam. The interpretation based on moment tensor inversion is consistent with previous studies of geochemical data of the volcanic island.

• Economic and Environmental Geology
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• v.8 no.4
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• pp.175-182
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• 1975

The chemical similarity of the magnetite-bearing amphiboltes of the Yangyang iron mine to mixtures of sedimentary pelites and limestone or dolomite and to the Gyeonggi para-amphibolites (So, 1974) is consistently indicated by all the chemical data of the rocks. Eight amphibolite samples were each analyzed for 18 elements, by wet chemical and emission spectroscopic methods, and these chemical data were compared with the para-amphibolites from the Gyeonggi metamorphic complex. Petrography and oxidation ratios were also considered.

• Korean Journal of Remote Sensing
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• v.25 no.4
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• pp.321-338
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• 2009

The objective of this paper is to compare spatial prediction capabilities of univariate kriging algorithms for generating GIS-based thematic maps from ground survey data with asymmetric distributions. Four univariate kriging algorithms including traditional ordinary kriging, three non-linear transform-based kriging algorithms such as log-normal kriging, multi-Gaussian kriging and indicator kriging are applied for spatial interpolation of geochemical As and Pb elements. Cross validation based on a leave-one-out approach is applied and then prediction errors are computed. The impact of the sampling density of the ground survey data on the prediction errors are also investigated. Through the case study, indicator kriging showed the smallest prediction errors and superior prediction capabilities of very low and very high values. Other non-linear transform based kriging algorithms yielded better prediction capabilities than traditional ordinary kriging. Log-normal kriging which has been widely applied, however, produced biased estimation results (overall, overestimation). It is expected that such quantitative comparison results would be effectively used for the selection of an optimal kriging algorithm for spatial interpolation of ground survey data with asymmetric distributions.

• Proceedings of the Korean Quaternary Association Conference
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• 2004.06a
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• pp.51-51
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• 2004

As an important contribution to the planed drilling (IODP) in the central part of the Arctic Ocean, we are currently working on a refined chronostratigraphy for Marine Isotope Stage (MIS) 16 to MIS 2 on the exciting material from ODP Site 910A (Leg 151) which has been recovered from the marginal Eastern Arctic Ocean (the Yermak Plateau - the Atlantic/Arctic Ocean Gateway). Several stratigraphic age fix-points support the interpretation of the stable oxygen. isotope record of planktonic foraminifer N, pachyderma sin. that is punctuated by several short-term meltwater events. We believe that our new record will serve as 'the important correlating tool for establishing a basic stratigraphy for the Quaternary Arctic Ocean as well as for generating high-resolution paleoenvironmental reconstructions in the central Arctic Ocean. Furthermore, our study will provide reference stratigraphic data sets for interpreting the micropaleontological, sedimentological and organic / inorganic - geochemical proxies of the new boreholes that will be drilled on the Lomonosov Ridge(Central Arctic Ocean) in the frame of the "Arctic Coring Expedition' (ACEX, IODP) in summer 2004.

• Journal of the Korean earth science society
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• v.33 no.5
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• pp.434-449
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• 2012

The Mesozoic leucocratic granite in the northeastern margin of the Taebaeksan Basin was transformed to protomylonite and mylonite. Mylonitic foliations generally strike to NWWNW and dip to NE with the development of a sinistral strike-slip (top-to-the-northwest) shear sense. Grain-size reduction of feldspar in the mylonitized leucocratic granite occurred due to fracturing, myrmekite formation and neocrystallization of albitic plagioclase along the shear fractures of K-feldspar porphyroclasts. As the deformation proceeded, compositional layering consisting of feldspar-, quartz- and/or muscovite-rich layers developed in the mylonite. In the feldspar-rich layer, fine-grained albitic plagioclase and interstitial K-feldspar were deformed dominantly by granular flow. On the other hand, quartz-rich layers containing core-mantle and quartz ribbons structures were deformed by dislocation creep. Based on calculations from conventional two-feldspar and ternary feldspar geothermometers, mylonitization temperatures of the leucocratic granite range from 360 to $450^{\circ}C$. It thus indicates that the mylonitization has occurred under greenschist-facies conditions. Based on the geochemical features and previous chronological data, the leucocratic granite was emplaced during the Middle Jurassic at volcanic arc setting associated with crustal thickening. And then the mylonitization of the granite occurred during the late Middle to Late Jurassic (150-165 Ma). Therefore, the mylonitization of the Jurassic granitoids in the Taebaeksan Basin was closely related to the development of the Honam shear zone.

• Ocean and Polar Research
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• v.26 no.3
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• pp.507-514
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• 2004

A sediment core drilled from Lake langer on King George Island was analyzed for a variety of textural md geochemical properties along with $^{14}C$ age dates. These data were combined with published records of other cores to provide a detailed history of Holocene variation of total organic carbon (TOC) contents with respect to terrestrial paleoclimate change. The lithologic contrast of the lower diamicton and upper fine-grained sediments shows the glacier activity and subsequent lake formation. Low TOC contents fluctuated during the diamicton deposition whereas the increase of TOC began with the lake formation during the postglacial period that started about 5,000 yr B.p More notable are the distinct TOC peaks that may imply enhanced primary productivity during the warm period. The uniform and low TOC contents may reflect the limited productivity during the evolution of the lake. However, the recent TOC readvance clearly indicates gradual warming on King George Island. However, the paleoclimatic signature in the terrestrial lake environment during the Holocene seems to be subtle and less distinct, compared to the marine environment.

• Computers and Concrete
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• v.21 no.1
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• pp.103-110
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• 2018

This study introduces the supervised committee fuzzy model as a hybrid fuzzy model to predict compressive strength (CS) of geopolymers prepared from alumina-silica products. For this purpose, more than 50 experimental data that evaluated the effect of $Al_2O_3/SiO_2$, $Na_2O/Al_2O_3$, $Na_2O/H_2O$ and Na/[Na+K] on (CS) of geopolymers were collected from the literature. Then, three different Fuzzy Logic (FL) models (Sugeno fuzzy logic (SFL), Mamdani fuzzy logic (MFL), and Larsen fuzzy logic (LFL)) were adopted to overcome the inherent uncertainty of geochemical parameters and to predict CS. After validating the model, it was found that the SFL model is superior to MFL and LFL models, but each of the FL models has advantages to predict CS. Therefore, to achieve the optimal performance, the supervised committee fuzzy logic (SCFL) model was developed as a hybrid method to combine the benefits of individual FL models. The SCFL employs an artificial neural network (ANN) model to re-predict the CS of three FL model predictions. The results also show significant fitting improvement in comparison with individual FL models.

• Economic and Environmental Geology
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• v.21 no.1
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• pp.17-27
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• 1988

The Cretaceous Jinsan gold-bearing hydrothermal veins occur within the Late Proterozoic to Mid Ordovician metasedimentary rocks, intruded by Early Cretaceous pink-feldspar granite($142{\pm}2.0m.y.$). Electrum-galena-sphalerite mineralization was deposited in three stages of quartz and calcite veins. Quartz sulfide-bearing stage I and II evolved from initial high temperatures (near $360^{\circ}C$)to later lower temperatures(near $220^{\circ}C$)from lower salinity fluids(1.0 to 3.2 wt.% NaCl eq.). Fluid inclusion data from the post ore carbonate stage reflects much cooler($110^{\circ}$ to $180^{\circ}C$). Evidence of boiling indicates pressure of<85 bars, corresponding to depths of 400m to 1050m assuming lithostatic and hydrostatic loads. Au-deposition was likely a result of boiling, coupled with declining temperatures. The ${\delta}^{34}S$ $H_2S$ values calculated for sulfides are consistent with an igneous source of sulfur with a ${\delta}^{34}S_{{\Sigma}S}$ value near 4.0‰.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.4 no.1
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• pp.25-32
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• 1999

In order to examine the degree of heavy metal pollutions around Samcheonpo and Youngkwang power plants, marine sediment samples were analyzed to determine heavy metal contents. Some of these sediment samples were also analyzed by using of a sequential extraction technique to know geochemical forms of the metals. The results showed that the spatial distribution of heavy metals coincided very well with those of mean grain size, carbonates and organic matters. The chemical speciation data using sequential extraction analysis also showed that a considerable amount of heavy metals except for Mn were bounded in the residual fraction, which mode of occurrence of heavy metals was generally interpreted as being the result of the lithogenic origin.