• 암석학회지
• /
• 제21권2호
• /
• pp.113-128
• /
• 2012

대륙지각의 화학조성은 지각의 형성과 진화에 대한 이해 및 대륙지각내에서 발생된 여러 과정을 정량화하는데 있어서 중요한 역할을 한다. 이 논문에서는 1990년대 이후 보고된 한반도내 화성암류와 퇴적암류의 지구화학적 자료를 토대로 한반도를 구성하고 있는 대륙지각의 화학조성을 지질시대별로 살펴보았다. 평균상부지각조성을 기준으로 한반도에서의 생성시기별 상부지각의 지구화학적 특성을 비교해보았을 때, 트라이아스기의 화강암이 다른 시대와 비교해서 일부 원소에서 현저하게 부화되었거나 결핍된 특성을 보여주었다. 또한 선캠브리아기와 쥬라기 이후의 화강암은 매우 유사한 주성분, 미량성분, 희토류원소의 지구화학적 특성을 보여준다. 하부지각의 지구화학적 특성을 지시해주는 선캠브리아기 고변성도 편마암의 희토류원소 및 미량원소의 지구화학적 특징은 쥬라기 이후 상부지각을 형성한 화강암의 희토류원소 및 미량원소의 지구화학적 특징과 유사한 특징을 보여주는데, 이는 이들 변성암류가 중생대 쥬라기 이후 화강암질 마그마의 기원물질이 되었을 가능성을 지시해준다. 반면에 한반도내 중생대 트라이아스기의 상부지각의 기원물질은 선캠브리아기나 쥬라기 이후의 상부지각을 형성한 기원물질과는 다른 것으로 나타났다.

• 자원환경지질
• /
• 제33권3호
• /
• pp.205-215
• /
• 2000

The Anyang River runs through highly industrialized area and joins the lower part of the Han River. loading out large amounts of potential pollutants. Attempts were made to understand geochemical behavior of trace elements in the stream sedimens collected from the bottom of the river and the stream water. Bottom sediments, suspended solids and stream waters were collected and analysed for the chemical and mineralogical composition. Heavy metals including Cr, Zn, Ni, and Co in the sediments were enriched appeared to reflect anthropogenic input. Pb, Cu, As were also enriched between several to 10 times , compared to background levels. Although some heavy metals were derived from anthropogeic input, geochemical associations seem to implyh much of the elements are originated from natural sources as well, mainly from granitic rocks . This is also supported by the mineralogical composition of the suspended solids, which are mainly composed of quartz, feldspar and mica. Most of the elements are associated with total carbon and clay sized fractions, with high values of correlation coefficient. Most of the elements are associated with total carbon and clay sized fractions , with high values of correlation coefficient. It was noteworthy that Hg was detected between 2 and 4 ppb in the stream water.

• Ocean and Polar Research
• /
• 제24권2호
• /
• pp.167-175
• /
• 2002

Sediment from six piston cores from the East Sea (Sea of Japan) was analyzed for evidence of paleoceanographic changes and paleoclimatic variation. A distinct geochemical boundary is evident in major element concentrations and organic carbon content of most cores near the 10-ka horizon. This distinctive basal Holocene change is interpreted to be largely the result of changing sediment sources, an interpretation supported by TiO_2/Al_2O_3$ ratios. Organic carbon and carbonate contents also differ significantly between the Holocene and glacial intervals. The C/N ratio of organic matter is greater than 10 during the glacial period, but is less than 10 for the Holocene, suggesting that the influx of terrigenous organic matter was more volumetrically important than marine organic matter during glacial times. The chemical index of weathering (CIW) is higher for the Holocene than the glacial interval, and changes markedly at the basal Holocene geochemical boundary. Silt fractions are higher in the glacial interval, suggesting a strong effect of climate on silt particle transportation: terrigenous aluminosilicates and continental organic carbon transport were higher during glacial times than during the Holocene. Differences in sediment composition between the Holocene and glacial period are interpreted to have been climatically induced.

• 자원환경지질
• /
• 제31권6호
• /
• pp.485-498
• /
• 1998

The water-rock interaction and anthropogenic contamination affecting to geochemical composition of shallow and deep groundwaters were investigated in the agricultural area of Myunggok-ri, Kongju. The shallow groundwater is classified into the chemical types of $Ca-HCO_3$ and $Ca-Cl(SO_4)$ and shows weak acid having an average pH 6.2. Deep groundwater shows the uncontaminated composition of the chemical types of $Na-HCO_3$ and Na $(Ca)-HCO_3$ with pH of 8.4~8.8. The grouping approach of chemical data of waters shows the distinguished trend between water composition influenced anthrophogenic input and water composition mainly determined by natural process such as water-rock interaction. The main anthropogenic inputs affecting chemical composition of shallow groundwater are the contaminants such as $K^+$, $NO_3{^-}$, $Cl^-$ having average values of 4.4 mg/l, 22 mg/l, 13.7 mg/l, respectively. The contaminants were probably derived from fertilizer, sweage, septic tank, and stable, etc. The hydrogen and oxygen isotopic compositions indicate that five deep groundwaters were recharged from different altitudes, and that shallow and deep groundwaters were originated from meteoric water. Tritium contents of waters suggest that deep groundwater was recharged before or just after 1950s, and that shallow groundwater is much younger than deep groundwater. The results of this study may serve as a basic data for the future study of shallow groundwater as a drinking water in agricultural area, in Korea.

• 환경영향평가
• /
• 제9권4호
• /
• pp.301-314
• /
• 2000

Marine surface sediments in the vicinity of Samcheonpo coal-fired power plant were analyzed by a total analysis($HF+HNO_3+HClO_4$) and sequential extraction procedure for heavy metals in order to investigate the total concentrations and geochemical phases of heavy metals. The result showed that the concentrations of Cr, Cu, Fe and Zn were within ranges typical for coastal areas, which reflected the mineralogical composition of the sediments in the studied area. However, the distributions of Cd, Co, Mn, Ni and Pb were rather different from the former, indicating that these heavy metals had a different origin, or that they were affected by a different geochemical mechanism. Chemical partitioning of heavy metals using sequential extraction procedure revealed that Cu, Fe, Pb, Zn were significantly bound to the residual phases of the sediments, whereas carbonate phases contained considerable amounts of Mn. The significant association of Pb with the exchangeable fraction also indicated that Pb was more mobile and bioavailable than Cu, Fe, Mn, Zn.

• 자원환경지질
• /
• 제31권1호
• /
• pp.69-84
• /
• 1998

A geochemical study was carried out to define how marine shore sediments are related to their terrestrial source rocks in the region of Taean and Byunsan Peninsula, western Korea. The lithology of the coastal part of the study area is composed of Pre-Cambrian granite gneiss, schist, Jurassic terrestrial sedimentary rocks, and Cretaceous plutonic intrusives. Shore sediments are transported from three drainage tributaries. The sediments consist of quatrz with clay minerals, such as illite, kaolinite, smectite, chlorite. Heavy minerals include hematite, ilmenite, rare amount of zircon and apatite. Compared to those in coastal rocks, amount of heavy minerals in the sediments is considerably low. The low content of heavy minerals is thought to be attributed to the heavy mineral detainment in the river beds and influences of tidal currents which cause heavy minerals to accumulate in specific spots. Chemical composition of the major and trace elements, trace elements, and REE chondrite normalized pattern suggest that shore sediments transported from the corresponding drainage tributary show close mineralogical and geochemical relationships with the source rocks distributed in the Taean and Byunsan Peninsula.

• 한국환경과학회지
• /
• 제11권3호
• /
• pp.215-225
• /
• 2002

In order to evaluate the relationship between geochemical characteristics and benthic facies of the sediments from the Oenaro Island where red tide proliferation is first observed every year including this year, surface and short multiple core sediment samples were analyzed in terms of geochemical and benthic facies variation. The contents of organic carbon, carbonate, and sulfide gas were relatively low. The variation in C/N ratios, which indicate nature of organic carbon, suggested that the organic carbon recorded in the study area is composed of mixtures of marine and terrigenous organic matters. The concentration of minor elements found at the surface and multiple core sediment samples were also low as well as the enrichment factors(Ef) for the seven heavy metals indicated that the sediment of this area is not polluted significantly. The macrobenthic faunal community comprised 61 species, and their mean density was 708 ind./m2. Polychaete worms were major taxa of this benthic community. A crustacean amphipod, Melita sp. was the most abundant species accounted for 20.7% of total abundance, and the small polychaetes such as Heteromastus filiformis, Paralacydonia poradoxa, Magelona japonica and Sigambra tentaculata were the next dominant species. The macrobenthos around the Oenaro Island were more diverse and abundant than that in Gamak Bay. The benthic communities in the study area sustained somewhat different species composition based on the cluster analysis and the MDS ordination. The benthic community health condition at three stations seemed to be unbalanced, and slightly polluted based on the biological index such as BPI and BC. There was no clear relationship between the geochemistry characteristic and the benthic faunal facies attributed by the micro-algal blooms in this coastal area.

• Ocean and Polar Research
• /
• 제41권3호
• /
• pp.169-181
• /
• 2019

The purpose of this study is to develop geochemical tracers to identify a specific source desert of mineral dust in China using the published data. In addition, we tested the applicability of these tracers to wet-deposits and soil samples collected in Jeju, Korea. Because of similarity in trace elemental compositions of mineral dust from the major arid regions in China, such as Taklimakan, West Ordos (Badain Jaran), East Ordos (Mu Us and Hobq), East Northern China (Horqin), West Northern China (Gurbantunggut), and Chinese Loess Plateau, there has been limited to the use of geochemical data for source identification. Here we propose the four (4) plots using combination of seven (7) geochemical variables as a source indicator to distinguish one from other source regions in China: $\frac{Y}{Tb_N}$ vs. $\frac{Th}{{\Sigma}REE_N}$, $\(\frac{La}{Gd}\)_N$ vs. $\frac{Y}{{\Sigma}REE_N}$, $\frac{Th}{Tb_N}$ vs. $\frac{Y}{Nd_N}$, and $\frac{Th}{Tb_N}$ vs. $\(\frac{Ce}{Ce}\)_N^*$, where $_N$ and $\(\frac{Ce}{Ce}\)_N^*$ stand for values normalized to Post-Archean Average Shale composition and Ce anomaly, respectively. Mineral dusts from aforementioned six major deserts are distinguished one from the others by the combined use of these variables. Jeju rock and soil samples form a separate domain from Chinese mineral dusts in all four plots. In contrast, most of Jeju dust samples were comparable with the West Ordos desert (Badain Jaran) domain, indicative of strong influence of Badain Jaran dust in Jeju in spring season when the mineral dust was collected. A weak positive Ce anomaly in Jeju samples implies minimal local contribution. Our study suggests that the combination of $\frac{Y}{Tb_N}$ vs. $\frac{Th}{{\Sigma}REE_N}$, $\(\frac{La}{Gd}\)_N$ vs. $\frac{Y}{{\Sigma}REE_N}$, $\frac{Th}{Tb_N}$ vs. $\frac{Y}{Nd_N}$, and $\frac{Th}{Tb_N}$ vs. $\(\frac{Ce}{Ce}\)_N^*$ can be used to identify a specific source region of mineral dust in China as well as Jeju mineral particles.

• 한국환경과학회지
• /
• 제25권11호
• /
• pp.1563-1573
• /
• 2016

The aim of this study was to evaluate the occurrence of vanadium in Jeju Island groundwater, focusing on the spatio-temporal patterns and geochemical controlling factors of vanadium. For this, we collected two sets of groundwater data: 1) concentrations of major constituents of 2,595 groundwater samples between 2008 and 2014 and 2) 258 groundwater samples between December 2006 and June 2008. The concentrations of groundwater vanadium were in the range of $0.2{\sim}71.0{\mu}g/L$ (average, $12.0{\mu}g/L$) and showed local enrichments without temporal/seasonal variation. This indicated that vanadium distribution was controlled by 1) the geochemical/mineralogical composition and dissolution processes of original materials (i.e., volcanic rock) and 2) the flow and chemical properties of groundwater. Vanadium concentration was significantly positively correlated with that of major ions ($Cl^-$, $Na^+$, and $K^+$) and trace metals (As, Cr, and Al), and with pH, but was negatively correlated with $NO_3-N$ concentration. The high concentrations of vanadium (>$15{\mu}g/L$) occurred in typically alkaline groundwater with high pH (${\geq}8.0$), indicating that a higher degree of water-rock interaction resulted in vanadium enrichment. Thus, higher concentrations of vanadium occurred in groundwater of $Na-Ca-HCO_3$, $Na-Mg-HCO_3$ and $Na-HCO_3$ types and were remarkably lower in groundwater of $Na-Ca-NO_3$(Cl) type that represented the influences from anthropogenic pollution.

• 자원환경지질
• /
• 제32권3호
• /
• pp.247-260
• /
• 1999

Geochermical characteristics of the fluvial sediments deprnding on particle size distribution size were investigated in the respect of majir, minor and rare eath element chemisitry. Ratios of $Al_{2}O_{3}/Na_{2}O$ and $K_{2}O/Na_{2}O$ of the sediments show the homogeneous valus, and partly positive correlation with $SiO_{2}/Al_{2}O_{3}$, respecively. Characteristics of minor element ratios (V/Ni, Cr/V, Ni/Co and Zr/Hf)are within the lower and narrow range. Thesesuggested that sediment sources may be acidic to intermediate granitic rock, and may be explained by simple weathering and sedimentation. With increasing SiO2 contents, concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, CaO and MgO decreased, but those of $K_{2}O$ and $Na_{2}O$ increased, Concentrations of Ba, Be, Cs, Cu, Li, Ni, Sr, V and Zr show comparatively normal negative and some positive trends. Compared with the mean composition of granite, concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, MnO, CaO and MgO in the sediments of the study area were highly enriced. Among some minor and rare earth elements, concentrations of As, Cd, Cu, and V were enriched, but those of Be, Ce, Rb, Sc, Sr and Zn were depleted when compared with average composition of granite. By decreasing of particle size fractions, SiO2, Rb and Sr conterts decreased, but concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, CaO, MgO, $TiO_{2}$, MgO, $P_{2}O_{5}$, Be, Cu, Hf, Pb, V and Zr increased. From the correlations between particle size fractions and element concenreations, some elements of $Fe_{2}O_{3}$, CaO, MgO, $P_{2}O_{5}$, Cu, Ni, Zn and Zr showed typical trends in the secondary contramination sediments. These trends are typically shown under 100 mesh fractions. It indicates that the fraction of minus 100 mesh is the optimum size fraction for geochemical and environmental survey.