• 제목/요약/키워드: geoaccumulation

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휴폐광산 지역에서 폐석의 중금속 존재 형태와 지화학적농축계수 평가 (Fraction and Geoaccumulation Assessment Index of Heavy Metals in Abandoned Mines wastes)

  • 김휘중;박병길;공성호;이재영;옥용식;전상호
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제10권6호
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    • pp.75-80
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    • 2005
  • 남한강 상류지역의 금속광산인 거도, 만정, 조일광산은 1988년 석탄광산합리화 사업과 더불어 폐광되었으며, 휴$\cdot$폐광된 이후 다량의 광산 폐기물을 방치하여 주변환경을 오염시키고 있는 실정이다. 그러나 광미, 폐석 등의 이동에 의한 주변의 토양오염에 대한 정량적 평가가 없기 때문에 이들 광산폐기물에 의한 오염정도를 확인하기 어렵다. 따라서 폐광된 거도, 만정, 조일 광산의 광산 폐석에 의한 수질 오염 가능성 평가를 위해 각 광산에서 폐석 시료를 채취하였으며, HCl 처리 농도에 따라 지화학적 농축 계수(Index of geoaccumulation), 중금속 존재 형태와 이동성에 관하여 조사하였다. 카드뮴, 납, 아연, 구리, 니켈 그리고 크롬의 지화학적 농축 계수는 각각 6, $4\~6,\;0\~6,\;4\~5$, 2, 0을 나타냈다. 광산 폐석에서 카드미뮴, 납, 아연, 구리의 지화학적 농축계수 분석을 통하여 이러한 지역이 상당한 오염 가능성을 알 수 있었다. 광산 폐석에서 중금속의 존재 형태는 구리의 경우 유기물 형태, 납은 탄산염 형태, 니켈과 아연은 잔류상 형태로 나타났다.

Assesment of soil pollution by Abandoned Mines wastes

  • Kim Hee-Joung;Yang Jae-E.;Lee Jai-Young;Park Beang-Kil;Kong Sung-Ho;Jun Sang-Ho
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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    • pp.363-370
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    • 2005
  • There are approximately 2,000 metallic mines which have been abandoned in Korea. Most of the mines are located in the watershed area, which is main source of drinking water for Seoul Metropolitan area. Untreated mining wastes are remained around abandoned mines in study area. These mining wastes, flowing into farmland and stream in the downstream of abandoned mines, would cause water and soil pollution. The mining waste samples from Guedo mine, Manjung mine and Joil mine recently abandoned were collected for the evaluation of the potential of water pollution by mine waste. Index of geoaccumulation($M\"{u}ller$, 1979), fractional composition and removal efficiency of some heavy metals by different concentration of HCl treatment were analyzed. Index of geoaccumulation of Cd, Pb, Zn, Cu, Ni and Cr are 6, $4{\sim}6,\;0{\sim}6,\;4{\sim}5$, 2 and 0 respectively. Index of geoaccumulation of Cd, Pb, Zn and Cu reveals the mining wastes has high pollution pottential in the area. Organic fraction of Cu, reducible fraction of Pb, residual fraction of Ni and Zn were the most abundant fraction of heavy metals in mining wastes.

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만경강 퇴적물의 중금속 함량 및 분포 (Heavy Metals in Fine-Grained Bed Sediments of the Mangyeong River, Korea)

  • 조영길
    • 한국환경과학회지
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    • 제16권5호
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    • pp.657-664
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    • 2007
  • The content and distribution of some heavy metals (Fe, Mn, Cr, Co, Cu, Ni, Zn and Pb) were investigated in the <$63{\mu}m$ bed sediments of the Mangyeong river to recognize the extent of contamination. Results showed that a wide range of concentrations was apparent for every metal. These variations were particularly significant at the confluence of tributaries. High levels of metals occur mainly in the confluence of tributaries. Geoaccumulation indexes have been calculated to assess whether the concentration observed represent background or contaminated levels. It is proved that the Mangyeong River is moderately to strongly polluted for Mn, Cr, Cu, Zn and Pb. The spatial extent of pollution was examined, and it was found that the most polluted area is located in the confluence of Iksan and Jeonju tributaries.

광안대교 인근 퇴적토 중의 중금속 농도 및 오염도 조사 연구 (Distribution and Pollution Assessment of Heavy Metals in Surface Sediments Near Gwangan Bridge)

  • 이준호;양창근;이태윤
    • 한국지반환경공학회 논문집
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    • 제19권11호
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    • pp.15-22
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    • 2018
  • 본 연구는 광안대교 인근의 해저퇴적토에 포함된 중금속을 분석하여 퇴적토의 오염도를 평가하고자 하였다. 오염도 평가를 위해 Enrichment Factor(EF), Geoaccumulation index, Potential ecological risk factor(PERF), mean PEL quotient와 같은 평가방법을 사용하였다. 각 평가방법에 따라 대상 지역의 중금속 오염 정도를 확인하였고 이를 종합적으로 고려하여 어떤 지역에서 어떤 중금속이 문제가 되는지를 확인하였다. Cr, Cu, Ni, Pb, Zn의 경우 전 지역에서 비오염 혹은 영향없음으로 판별되었으나(EF<1) Cd의 경우에는 모든 지역에서 외부영향으로 인한 농도증가 양상을 보여주었다(1$I_{geo}$에 의한 평가에서는 Cd의 경우 G4에서 다소 오염으로 분류되었으나 다른 지역에서는 모두 비오염으로 평가되었다. 각 평가방법에 의한 결과를 요약하면 Cd의 경우 전 지역에서 높게 검출되었고 지역별로는 G4와 G5 지역에서 Cd를 비롯하여 Pb와 Zn의 농도가 다른 지역보다 다소 높은 것으로 확인되었다.

부산지역 도시하천 표층 퇴적물 오염도 평가에 관한 연구 (Contamination Assessment of Surface Sediments in Urban Rivers, Busan)

  • 곽진숙;손정원;김주인;송복주
    • 한국물환경학회지
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    • 제37권4호
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    • pp.296-305
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    • 2021
  • This work investigated heavy metal pollution in surface sediments of rivers in Busan, Korea. Surface sediments were analyzed in order to conduct contamination assessment of organic matter, nutrients, and heavy metal concentrations. Contamination assessment of heavy metals was conducted using geoaccumulation index (Igeo), pollution load index (PLI), and potential ecological risk index (RI). Accumulation of organic matter and nutrients were affected by water discharged from sewage treatment plant. The concentrations of organic matter and nutrients were found to be greater in points which were close to the sewage treatment plant more than points furthest. The concentrations of Pb, Zn, Cu, Cd, Hg, As, Cr, and Ni were found to be greater in surface sediment more than in the background. The mean concentrations of heavy metals were in the order of Zn (323.5 mg/kg) > Cu (70.5 mg/kg) > Pb (39.8 mg/kg) > Cr (33.4 mg/kg) > Ni (13.5 mg/kg) > As (9.4 mg/kg) > Cd (0.84 mg/kg) > Hg (0.092 mg/kg). The result of geoaccumulation indices indicated that Hg > Cr > Cu > Ni > Zn > As > Pb > Cd were found in order of severe contamination by heavy metals. From PLI and RI analysis, it was evident that the Suyeonggang 2 was the most contaminated river.

The Effect of Aircraft Traffic Emissions on the Soil Surface Contamination Analysis around the International Airport in Delhi, India

  • Ray, Sharmila;Khillare, P.S.;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • 제6권2호
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    • pp.118-126
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    • 2012
  • To investigate the effect of aircraft traffic emissions on soil pollution, metal levels were analyzed for 8 metals (Fe, Cr, Pb, Zn, Cu, Ni, Mn and Cd) from the vicinity of the Indira Gandhi International (IGI) airport in Delhi, India. The texture of the airport soil was observed to be sandy. Among the metals, Cd showed minimum concentration ($2.07{\mu}g\;g^{-1}$), while Fe showed maximum concentration ($4379{\mu}g\;g^{-1}$). The highest metal accumulation was observed at the landing site. Significant correlations were observed between metals and different textures (sand, silt, and clay) as well as with organic carbon (OC). The results indicate that grain size play a major role in OC retention in soil and subsequently helps in adsorption of metals in soil. M$\ddot{u}$ller's geoaccumulation index (I-geo) showed that airport soil was contaminated due to Cd and Pb with the pollution class 2 and 1, respectively. Pollution load index of the airport site was 1.34-3 times higher than the background site. The results of factor analysis suggested that source of the soil metal is mainly from natural weathering of soil, aircraft exhaust, and automobile exhaust from near by area. With respect to Dutch target values, the airport soils showed ~3 times higher Cd concentration. The study highlighted the future risk of enhanced metal pollution with respect to Cd and Pb due to aircraft trafficking.

상류수계 영산강 하상퇴적물의 지화학적 특성과 오염 (Geochemical Characteristics and Contamination of Surface Sediments in Upper Yeongsan River System)

  • 오강호;김주용;고영구;윤석태;서구원;박배영;신상은;김해경
    • 한국물환경학회지
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    • 제21권5호
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    • pp.520-527
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    • 2005
  • In order to investigate the geochemical characteristics of surface sediments in streams of upper Yeongsan River drainage system, sediment samples from the main stream of Yeongsan river, Hwangryong river, Gwangju and Jiseok streams were collected and analyzed for grain size and metal and organic carbon contents. The metal contents in the sediments are mainly dependent on organic matter contents in the domestic sewage, grain size of the sediments and geology around the streams. Enrichment factor (EF) and index of geoaccumulation (Igeo) representing the degree of metal contamination in the sediments are relatively low in the main stream of Yeongsan river main stream, Hwangryong river and Jiseok stream. However, those of Gwangju stream show the EF maximum values of P=8.30, Cu=5.55, Zn=14.29 and Pb=7.45 and the Igeo maximum values of P=3.58, Cu=4.43, Zn=3.22 and Pb=1.59.

전남 남부 도서갯벌 퇴적물의 유기물 및 미량금속 오염 평가 (Evaluation of Organic Matter and Trace Metal Contaminations of Intertidal Sediments from Coastal Islands in the Southern Region of Jeollanam Province)

  • 황동운;김평중
    • 한국수산과학회지
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    • 제46권5호
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    • pp.626-637
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    • 2013
  • We measured the grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS) and trace metals (Al, Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, and As) of intertidal surface sediment collected from 11 islands (62 stations) in the southern region of Jeollanam Province. The objective of this research was to evaluate the organic matter and trace metals contaminations of sediments from coastal island tidal flats. Surface sediment texture was characterized as follows: mud, sandy silt, muddy sand, and slightly gravelly sand facies. The finer sediments are mainly dominated in the northern part of each island. The concentrations of IL, COD, AVS and some trace metals (Al, Fe, Zn, Cr, Cu, and Hg) were higher in the northwestern part of Wan Island and the area between Gogeum and Sinji Islands, and were associated with relatively finer sediment, as compared to other locations. The concentrations of Mn, Pb, Cd, and As were higher in the northwestern and southeastern parts of Geoguem and Pyungil Islands, but were not correlated with mean grain size. Based on sediment quality guidelines (SQGs), the concentrations of trace metals were lower than the values of effect range low (ERL), used in United States, and threshold effects level (TEL), used in Korea, with exception of As. Similarly, the intertidal sediments were moderately contaminated with As, based on the the enrichment factor (EF) and the geoaccumulation index ($I_{geo}$). The high concentration of As in intertidal sediments from this study region may be due to the input of naturally or artificially contaminated submarine groundwater, contaminated waste from seaweed aquaculture operations and/or land-based seaweed processing facilities. Further studies are needed to identify the sources of As in this study region, and to determine the effects of As contamination on coastal ecosystem.

인천 H항 표층 퇴적물의 오염도 평가 (Estimation of Pollution Degree of Surface Sediment from Incheon H Wharf)

  • 김정호;남세용
    • 해양환경안전학회지
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    • 제20권5호
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    • pp.504-510
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    • 2014
  • 본 연구에서는 2014년 03월에 인천 H항의 5개 정점(S1~S5)에서 채취된 표층 퇴적물의 물리화학적 특성을 조사하고, COD, AVS, IL 및 중금속(Cd, Cu, Ni, Pb, Zn, Cr, Hg)을 분석하여 오염도를 평가하였다. 입도분석, 비표면적분석, XRD 및 XRF 분석을 통하여 채취된 퇴적물 시료 모두 거의 동일한 산화물과 광물로 구성되었음을 확인하였다. 국내기준으로 COD, AVS 및 IL 세 항목의 총점에 대한 오염도는 S2, S3, S5 지점은 2등급으로 S1, S4 지점은 3등급으로 평가되었다. 중금속 오염의 경우 Cd, Ni, Pb은 USEPA 기준으로 중간오염에 해당하였고, Cu, Zn 및 Cr은 심한오염으로 분류되었다. 농집지수를 이용한 오염도 평가결과 Cd가 Class 3으로 평가되었고, 농축계수를 이용한 평가결과 모든 지점에서 Cd, Pb, Zn의 경우 1보다 큰 것으로 나타났다. 또한 총농축계수는 S4지점이 3.1로 가장 높은 것으로 나타났다.