• Title/Summary/Keyword: gel property

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Technological Studies on Textured Soybean Protein (Part I) -Effect of Drying Process on Gelling Properties of Soybean Protein Isolate- (대두단백육(大豆蛋白肉)의 제조(製造)에 관한 연구(硏究) (제 1 보(第 1 報)) -건조공정(乾燥工程)이 분리대두단백(分離大豆蛋白)의 Gel 성질에 미치는 영향-)

  • Moon, Juhn-Woong
    • Korean Journal of Food Science and Technology
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    • v.2 no.2
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    • pp.49-55
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    • 1970
  • In preparation of textured soybean protein, drying process of the isolated protein affected its gelling property and other related characteristics such as water holding capacity and viscosity. In model systems, denaturation of the protein, as determined in terms of nitrogen solubility index (NSI), was appeared to be a parameter of the gel strength of soybean protein isolate. The gel strength was maximum when the protein was denatured properly during drying process of which the NSI was 43 in this experiment and decreased at either the higher or the lower NSI. It indicated that proper denaturation of the protein during drying operation is advantagous for the preparation of textured soybean protein but not neccesary to make highly undenatured one.

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Effect of Glycolysis Rate in Porcine Muscle Postmortem on Gel Property of Pork Surimi (돼지 근육의 사후 해당속도가 돈육 수리미의 젤 특성에 미치는 영향)

  • Kang Guen-Ho;Yang Han-Sul;Jeong Jin-Yeon;Joo Seon-Tea;Park Gu-Boo
    • Food Science of Animal Resources
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    • v.25 no.4
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    • pp.423-429
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    • 2005
  • Properties of pant surimi derived from porcine longissimus muscle were investigated Rapid glycolysis of muscle reduced yield $\%$ of water-washed pork and moisture $\%$ of pent surimi because of ie lower ultimate pH. Gel Hardness was significantly (p<0.05) higher in pork surimi from rapid glycolysis muscle, but springiness was higher (p<0.05) in pork surimi from normal glycolysis muscle. SDS-PAGE pattern showed denaturation of sarcoplasmic proteins onto myofibrillar proteins in rapid glycolysis muscle, resulted in dark color and hard texture of pork surimi. Color and texture of gels were related with water-holding capacity of muscle proteins and moisture $\%$ in gel matrix. Results imply that glycolysis rate of porcine muscle at postmortem could affect gel properties of pork surimi, and muscle with rapid glycolysis muscle could produce a hard texture of pork surimi and dark color.

Studies on the Correlation between Coated Paper and Physical Properties of Latices (라덱스의 물성이 도공지 품질에 미치는 상관성에 대한 연구)

  • 박동국;조교동;고문찬;윤재한;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.1
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    • pp.22-29
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    • 2002
  • The coated paper was greatly affected by the basic physical properties of the binder as well as the amount of the coating formula. High glass transition temperature (Tg) of the styrene-butadiene (SB) latex, selected as the binder in our study, gave the high stiffness to the coated paper, but lowered the binding force and print gloss. The average particle size of the SB latex also greatly affected to the coated paper so that the smaller particle size improved the rheological property of the coating formula and increased the binding force and print gloss. Another property of the SBR latex, gel content, was important because when its value was small, the latex was easily deformed at the high temperature and increased air permeability to the coated paper. Therefore, the lower gel content consequently resulted in the higher blistering resistance, especially in the web paper. The larger portion of the SB latex in the coated formula improved the binding force and print gloss, but decreased the ink set-off and ink-trapping to the coated paper. The heavier coating improved optical properties such as opacity, paper gloss and paper smoothness, to the coated paper.

Characteristics of La0.2Ca0.8MnO3 Powder and Pellet Prepared by Sol-Gel Process (졸-겔법으로 합성한 La0.2Ca0.8MnO3의 분말과 펠렛의 특성)

  • Jung, Miewon;Lee, Jiyun;Kim, Hyunjung
    • Applied Chemistry for Engineering
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    • v.16 no.1
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    • pp.150-152
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    • 2005
  • $La_{0.2}Ca_{0.8}MnO_3$ colossal magnetoresistance (CMR) powders and pellets were synthesized by sol-gel process involving a stable metal chelate complex with acetylacetone. The structural changes of reaction mixture were monitored by FT-IR spectroscopy and X-ray diffractometry. The microstructure of sintered samples and the cation composition of gel powder were studied by FE-SEM/EDS and ICP-AES. The magnetic property was investigated as a function of temperature.

Effect of Microstructural Change on the Optical Property of Ormosil Embedded Organic Molecules (유기염료의 기저체로 사용된 세라믹/고분자 복합체의 미세구조변화가 광학특성에 미치는 영향)

  • 김구대;이동아;김재동;박지애
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1365-1372
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    • 1996
  • In order to obtain a transparent and dimer-free Ormosil embedded with orgainc dye variations of gel struc-ture and optical properties were studied as a functiion of the change of gel composition. The Ormosils which have good optical property were produced in the 90/10 ratio of TEOS/PDMS and the structural variations of the gel were achived by the change of ratio of HCl/TEOS. As the ratio of HCl/TEOS was increased pore size of the Ormosil enlarged and porosity increased. Increasing HCl concentration led to gradually lower trans-mittance values. In the xerogel doped with the organic dye Rhodamine 6G perchlorate a dimer peak near 500nm was observed with the increase of the ratio of HCl/TEOS

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Zirconium Titanate Thin FIlm Prepared by Surface Sol-Gel Process and Effects of Thickness on Dielectric Property

  • Kim, Chy-Hyung;Lee, Moon-Hee
    • Bulletin of the Korean Chemical Society
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    • v.23 no.5
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    • pp.741-744
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    • 2002
  • Single phase of multicomponent oxide ZrTiO4 film could be prepared through surface sol-gel route simply by coating the mixture of 100 mM zirconium butoxide and titanium butoxide on $Pt/Ti/SiO_2Si(100)$ substrate, following pyro lysis at $450^{\circ}C$, and annealing it at 770 $^{\circ}C.$ The dielectric constant of the film was reduced as the film thickness decreased due to of the interfacial effects caused by layer/electrode and a few voids inside the multilayer. However, the dielectric property was independent of applied dc bias sweeps voltage (-2 to +2 V).The dielectric constant of bulk film, 31.9, estimated using series-connected capacitor model was independent of film thickness and frequency in the measurement range, but theoretical interfacial thickness, ti, was dependent on the frequency. It reached a saturated ti value, $6.9{\AA}$, at high frequency by extraction of some capacitance component formed at low frequency range. The dielectric constant of bulk ZrTiO4 pellet-shaped material was 33.7 and very stable with frequency promising as good applicable devices.

Synthesis of direct-patternable ZnO film incorporating Pt Nanoparticles

  • Choi, Yong-June;Park, Hyeong-Ho;Reddy, A.Sivasankar;Park, Hyung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.369-369
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    • 2007
  • ZnO film has been investigated during several decades because it has excellent optical property like a transmittance among the range of visible light for using transparent conducting oxide (TCO) films. But ZnO film has not enough conductivity for applying to TCO devices. Therefore we synthesized platinum nanoparticles and they incorporated into ZnO due to improve the electrical property of ZnO film by sol-gel synthesis method. Also, we fabricated photosensitive ZnO thin film containing Pt nanoparticles by sol-gel process and spin-coating for using photochemical solution deposition. Photosensitive ZnO film could carry out the direct-pattern which allow the etching process to be convenient. The optical and electrical properties of ZnO film with or without various atomic percent of Pt nanoparticles annealed at various temperatures were investigated by using UV-Vis spectroscopy and 4-point probe method, respectively. We characterized the ZnO thin film containing Pt nanoparticles using X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy.

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Thermal property of geopolymer on fly ash-blast furnace slag system with the addition of alumina aggregate (알루미나 골재 첨가에 따른 플라이애쉬-고로슬래그계 지오폴리머의 열적특성)

  • Kim, Jin-Ho;Nam, In-Tak;Park, Hyun;Kim, Kyung-Nam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.1
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    • pp.47-56
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    • 2017
  • In this study, the higher temperature thermal property of the fly ash-blast furnace slag system Geopolymer including alumina aggregate was investigated whether that Geopolymer will be or not useful as thermal-resistant construction materials. Under every mixing conditions, the crack on the surface of hardened body was not observed up to $800^{\circ}C$ and it corresponded with fact that level of changes was not significant before and after heating process. Residual compressive strength is most high when mixing Blast-Furnace Slag ratio is 60 wt% until temperature reaches $800^{\circ}C$. The major hydrates of hardened body of Geopolymer; amorphous halo pattern between $20{\sim}35^{\circ}$ (2theta) and mullite ($3Al_2O_3{\cdot}2SiO_2$) and quartz ($SiO_2$) was found during the experiment. Amorphous halo pattern was a aluminosilicate gel generated by geopolymeric polycondensation and it was found that the halo pattern of aluminosilicate gel was preserved up to $800^{\circ}C$. The patterns of aluminosilicate gel disappeared from $1,000^{\circ}C$ and crystal phases like gehlenite, calcium silicate, calcium aluminum oxide, microcline was observed with the increase of exposure temperature.

Acrylamide Polymerization on Ceramic Powders(II) : Effect of MeOH on Si$_3$N$_4$ Gelcasting (세라믹분체 표면에서 아크릴아마이드 중합(제2보) : MeOH가 질화규소 겔캐스팅에 미치는 영향)

  • 류병환;김은영;이재도
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.220-224
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    • 1999
  • For the process control of silicon nitride gelcasting, the effect of MeOH on the apparent gel induction time of slip, drying rate, and mechanical property of gelcast body were investigated. The apparent gel induction time showed maximum at 10~20 vol% MeOH and the drying rate of gelcast body increased in the ranged of 25~40%. The gelcast body was still machinable in the 40% of MeOH, though the mechanical property and relative density slightly decreased with increasing the amount of MeOH.

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Insulation resistance property of EVA (Ethylene-vinyl acetate) photovoltaic module encapsulants

  • Jin, Ga-Eon;Jeong, Tae-Hui;Ju, Yeong-Cheol;Gang, Gi-Hwan;Jang, Hyo-Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.424.1-424.1
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    • 2016
  • 태양전지 모듈의 봉지재로 사용되는 EVA(Ethylene-Vinyl acetate)는 외부의 환경으로부터 태양전지를 보호해주는 역할을 한다. 하지만 frame의 실링재나 glass edge 부분의 결함으로 인해 수분이 침투되어 모듈의 내부자재에 영향을 미치게 되며, 모듈의 효율 감소나 수명 단축의 원인이 된다. 이러한 결함을 줄이기 위해서는 EVA의 crosslinking degree, 절연 저항 특성을 향상시키는 것이 중요하다. 이에 본 연구에서는 EVA의 crosslinking degree를 보기 위해 soxhlet extraction method를 이용하여 gel content를 측정하였으며, 라미네이션 과정 중 curing time에 따른 gel content 변화를 확인하였다. 또한 이 실험을 바탕으로 gel content에 따른 절연 저항을 측정하여 EVA의 crosslinking degree에 의한 절연 저항 특성을 확인하였다.

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