• 한국자동차공학회논문집
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• 제18권1호
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• pp.23-30
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• 2010

Trends of the automotive market require the application of new engine technologies, which allows for the use of different types of fuel. Since ethanol is a renewable source of energy and it contributes to lower $CO_2$ emissions, ethanol produced from biomass is expected to increase in use as an alternative fuel. It is recognized that for spark ignition (SI) engines ethanol has advantages of high octane number and high combustion speed. In spite of the advantages of ethanol, fuel supply system might be affected by fuel blends with ethanol like a wear and corrosion of electric fuel pumps. So the on-board hydrogen production out of ethanol reforming can be considered as an alternative plan. This paper investigates the influence of ethanol fuel on SI engine performance, thermal efficiency and emissions. The results obtained from experiments have shown that specific fuel consumption has increased by increasing ethanol amount in the blend whereas decreased by the use of hydrogen-enriched gas. The combustion characteristics with hydrogen-enriched gaseous fuel from ethanol reforming are also examined.

• 한국자동차공학회논문집
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• 제14권3호
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• pp.170-177
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• 2006

Hydrogen can extend the lean misfire limit to a large extent when it is mixed with conventional fuels for a spark ignition engine. In this study, hydrogen-enriched gaseous fuels by reforming process were simulated according to their proportions of $H_2$, CO, $CO_2$ and $N_2$ gases. Pure hydrogen and two different hydrogen-enriched gaseous mixtures(A-, B-composition) were tested for their basic effects on the engine performances and emissions in a single cylinder research engine. A- and B-composition showed different results from 100% $H_2$ addition because air/fuel mixtures were more diluted by their additions. Even though the energy fraction of reformed gases was increased, combustion stabilities and lean misfire limits were not sensitively improved. It means that combustion augmentation by $H_2$ addition was offset by the charge dilution of $N_2$ and $CO_2$. In addition, the low flammability of CO gas deteriorated thermal efficiencies. CO emission was drastically increased with B-composition which included higher CO component. However, $NO_x$ was reduced as energy fraction($X_e$) rised except for the case of 100% $H_2$ addition at $\lambda=1.2$ and was, for A-composition, lowered to a factor of ten when compared with that of $H_2$ addition. HC emissions were largely influenced by $COV_{imep}$ due to misfire and partial burns.

• 한국환경보건학회지
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• 제14권1호
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• pp.11-22
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• 1988

Calcium oxide, lithium oxide and titanium oxide were investigated as additives of zinc oxide for the removal of hydrogen sulfide at high temperature. This experiment was performed in the range of 1.0-2.0 vol.% H$_2$S concentration at 623-873 K reaction temperature, using a thermogravimetric analyzer. A pore blocking model was found to fit the reaction rate and the kinetics data were sucessfully expressed by this model. The reactions between additive sorbents and hydrogen sulfide were first order with respect to hydrogen sulfide concentration in a gaseous mixture with nitrogen. Among the used sorbents, ZnO-CaO 0.5 at.% and ZnO-TiO$_2$ 2.0 at.% sorbents had the best additive effects on the sulfidation reaction between additive sorbents and hydrogen sulfide, whereas the ZnO-Li$_2$O sorbents were ineffective.

• 한국수소및신에너지학회논문집
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• 제13권3호
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• pp.249-258
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• 2002

Thermochemical water-splitting IS(Iodine-Sulfur) process has been investigating for large-scale hydrogen production. For the construction of an efficient process scheme, two kinds of membrane technologies are under investigating to improve the hydrogen producing HI decomposition step. One is a concentration of HI in quasi-azeotropic HIx ($HI-H_2O-I_2$) solution by elecro-electrodialysis. It was confirmed that HI concentrated from the $HI-H_2O-I_2$ solution with a molar ratio of 1:5:1 at $80^{\circ}C$. The other is a membrane reactor to enhance the one-pass conversion of thermal decomposition reaction of gaseous hydrogen iodide (HI). It was found from the simulation study that the conversion of over 0.9 would be attainable using the membrane reactor using the gas permeation properties of the prepared silica hydrogen permselective membrane by chemical vapor deposition (CVD). Design criterion of the membrane reactor was also discussed.

• 소성∙가공
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• 제33권3호
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• pp.185-192
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• 2024

This study examined how varying tempering temperatures affect the susceptibility of Cr-Mo low alloy steels to hydrogen embrittlement. A slow strain-rate test (SSRT) was carried out on the steels electrochemically pre-charged with hydrogen in order to examine the hydrogen embrittlement behavior. The results showed that the hydrogen embrittlement resistance of the Cr-Mo low alloy steels improved with increasing tempering temperature. Thermal desorption analysis (TDA) revealed that diffusible hydrogen content decreased with increasing tempering temperature, accompanied by a slight increase in the peak temperature. This decrease in hydrogen content was likely due to a reduction in dislocation density which served as reversible hydrogen trap sites. These findings underline the significant role of tempering temperature in enhancing the hydrogen embrittlement resistance of Cr-Mo low alloy steels.

• 한국수소및신에너지학회논문집
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• 제30권3호
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• pp.237-242
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• 2019

In the hydrogen refueling station (HRS), it is need the pre-cooling system (PCS) to limit the inside temperature ($85^{\circ}C$) of the onboard thank (700 bar) and to charge the hydrogen at short time (within 3 minutes) to fuel cell electric vehicle (FCEV). From those safety reasons, the temperature of hydrogen gas must be controled $-33^{\circ}C$ to $-40^{\circ}C$ in PCS. The cooling test of the gaseous ($N_2$, He, $H_2$) was carried out using heat exchanger (pre-cooler) by indirect cooling and direct cooling method. It was confirmed that the temperature of hydrogen gas had below $-40^{\circ}C$ at below $-75^{\circ}C$ of chiller temperature in direct cooling.

• 한국광학회:학술대회논문집
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• 한국광학회 2009년도 동계학술발표회 논문집
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• pp.339-340
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• 2009

• 전기학회논문지P
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• 제59권2호
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• pp.218-221
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• 2010

This paper presents energy efficiency about an electrolyser which is related with the hybrid system of solar cell and fuel cell for using the system more fully. The water electrolyser is the exact reverse of a hydrogen fuel cell; it produces gaseous hydrogen and oxygen from water. Electrolyser technology may be implemented at a variety of scales wherever there is an electricity supply to provide hydrogen and/or oxygen for virtually any requirement. Also, this paper shows optimum operating point in the electrolyser for saving cost of the electrical energy with hybrid system.

• International Journal of Naval Architecture and Ocean Engineering
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• 제5권4호
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• pp.559-568
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• 2013

Increased worldwide concerns about fossil fuel costs and effects on the environment lead many governments and scientific societies to consider the hydrogen as the fuel of the future. Many researches have been made to assess the suitability of using the hydrogen gas as fuel for internal combustion engines and gas turbines; this suitability was assessed from several viewpoints including the combustion characteristics, the fuel production and storage and also the thermodynamic cycle changes with the application of hydrogen instead of ordinary fossil fuels. This paper introduces the basic environmental differences happening when changing the fuel of a marine gas turbine from marine diesel fuel to gaseous hydrogen for the same power output. Environmentally, the hydrogen is the best when the $CO_2$ emissions are considered, zero carbon dioxide emissions can be theoretically attained. But when the $NO_x$ emissions are considered, the hydrogen is not the best based on the unit heat input. The hydrogen produces 270% more $NO_x$ than the diesel case without any control measures. This is primarily due to the increased air flow rate bringing more nitrogen into the combustion chamber and the increased combustion temperature (10% more than the diesel case). Efficient and of course expensive $NO_x$ control measures are a must to control these emissions levels.

• Elastomers and Composites
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• 제55권4호
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• pp.270-276
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• 2020

The long-term durability of an FKM O-ring used as parts of a hydrogen station was investigated by exposing it to high-pressure gaseous hydrogen for 1, 3, and 7 days at room temperature. Changes in its sealing force were subsequently measured at 150℃ using intermittent compression stress relaxation (CSR). No changes in the tensile properties of FKM O-ring were observed, but its initial and overall sealing forces at 150℃ significantly decreased with increasing exposure time to hydrogen gas. Microvoid formation in the FKM O-ring upon exposure to high-pressure hydrogen was minimized over time after the ring was exposed to atmospheric pressure at room temperature, which prevented changes in its tensile properties. However, applying heat accelerated FKM O-ring oxidation, which decreased its sealing force. These results indicated that identifying changes in the sealing force of rubber materials using intermittent CSR is not sufficient for monitoring changes in mechanical properties under high-pressure hydrogen atmospheres; however, it is suitable for evaluating the long-term durability of sealing materials for hydrogen station applications under similar conditions.