• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.368-371
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• 2019

Using first principles calculations we investigated the thermomechanical stability of spent nuclear fuels (SNF), especially how mechanical properties of $UO_2$, such as, bulk, shear and Young's moduli and Poisson's ratio vary through alpha-decay of U into Th with generation of He gas. Our results indicate that substitution of U by Th through alpha decay ($U_{1-x}Th_xO_2$) does not significantly affect the stability of the grain in a fuel matrix. In addition, we studied the transport properties of He in and boundaries of the $U_{1-x}Th_xO_2$ grain. Helium preferentially resides at the grain boundaries through diffusion. Our study can contribute to substantial reduction of environmentally risk and enhancement of our sustainability by safe control of radioactive materials.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.11a
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• pp.159-162
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• 1998

This paper describes the electron transport characteristics in $SF_6$+He gas calculated for range of E/N values from 50~700[Td] by the Monte Carlo simulation and Boltzrnann equation method using a set of electmn collision cross sections determined by the authors and the values of electron swarm parameters are obtained by M F method. The results gained that the values of the electron swarm parameters such as the electron drift velocity, the electron ionization or attachment coefficents, longitudinal and h-ansverse diffusion coefficients agree with the experimental and theoretical for a range of E/N.

• Proceedings of the KIEE Conference
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• 1999.11a
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• pp.16-19
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• 1999

This paper describes the electron transport characteristics in $SF_6$+He gas calculated for range of E/N values from $50{\sim}700[Td]$ by the Monte Carlo simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters are obtained by TOF method. The results gained that the values of the electron swarm parameters such as the electron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients agree with the experimental and theoretical for a range of E/N.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.05a
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• pp.696-699
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• 1999

The electron transport coefficients in $SF_6+N_2$ gas is analysed in range of E/N values from 100~900(Td) by a Monte Carlo simulation and Boltzmann method, using a set of electron collision cross sections determined by the authors. The result of the Monte Carlo simulation such as electron drift velocity, ionization and electron attachment coefficients, longitudinal and transverse diffusion coefficients in nearly agreement with the respective experimental and theoretical for a range of E/N.

• Macromolecular Research
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• v.16 no.6
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• pp.555-560
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• 2008

A series of hydroxyl-group containing polyimides (HPIs) were prepared in order to investigate the structure-gas permeation property relationship. Each polymer membrane had structural characteristics that varied according to the dianhydride monomers. The imidization processes were monitored using spectroscopic and thermog-ravimetric analyses. The single gas permeability of He, $H_2$, $CO_2$, $O_2$, $N_2$ and $CH_4$ were measured and compared in order to determine the effect of the polymer structure and functional -OH groups on the gas transport properties. Surprisingly, the ideal selectivity of $CO_2/CH_4$ and $H_2/CH_4$ increased with increasing level of -OH incorporation, which affected the diffusion of $H_2$ or the solubility of $CO_2$ in HPIs. For $H_2/CH_4$ separation, the difference in the diffusion coefficients of $H_2$ and $CH_4$ was the main factor for improving the performance without showing any changes in the solubility coefficients. However, the solubility coefficient of $CO_2$ in the HPIs increased at least four fold compared with the conventional polyimide membranes depending on the polymer structures. Based on these results, the polymer membranes modified with -OH groups in the polymer backbone showed favorable gas permeation and separation performance.

• Korean Chemical Engineering Research
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• v.45 no.6
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• pp.619-626
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• 2007

It is of special interest in our membrane separation technology due to its low energy consumption and cost, relatively simple equipment, low investment and operation cost, et al. Full scale utilization of such processes can be widely utilized to the various fields. Using the difference of permeability of gas molecules between the filter layers, it is able to separate effectually pure gases from the mixed gases. In this paper, the membranes of PDMS, ${\gamma}-radiated$ PDMS, PTFE, PTFE-X are chosen to develop the predictive model for the separation of pure gases such as oxygen, nitrogen, hydrogen, and other gases from mixed gases. By utilizing the thermodynamic gas properties($\sigma$, $\varepsilon/k$) and experimental data of gas transport characteristics for different polymer membranes, it is able to develop the predictive model equation under the influence of temperature, pressure and polymer characteristics. Predictive model developed in this research showed good agreement with experimental data of gas permeability characteristics for develop four different polymer membranes. The proposed model can also be extended to the general equation for predicting the separation of gases based on the properties of polymeric membranes.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.1
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• pp.32.1-32.1
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• 2012

Radial color gradient of disk galaxies has been a key tool for diagnosing the ages and metallicities of the stars and gas of these galaxies, and thus, the formation process of these disks. In many cases, observational data support the 'inside-out' picture of disk galaxy formation proposed by Larson (1976). In this scenario, gas within dark matter halos cools and accretes on to the outer disk while enhancing star formation in the disk. Recent discoveries of "extended ultra-viloet" (XUV) disks also show that majority of disk galaxy experience active star formation within out disks where gas surface density is quite low (Thilker et al. 2007; Gil de Paz et al. 2007). However, neither gas, nor stars stay put within galaxies. They rather migrate into bulges, disperse throughout galaxies, or flow into and out of galaxies via various mechanisms. There have been a few notable studies to investigate how radial star formation and metal abundance gradients vary across populations of disk galaxies systematically. However, the mechanisms driving gas transport are still poorly understood. Cross-matching various galaxy catalogs including KVAGC and UKIDSS, we are investigating if color gradients of late-type galaxies depend on their physical properties, especially on environmental properties. We will present the result from the pilot study on Karachentsev isolated galaxy catalog.

• Polymer(Korea)
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• v.26 no.2
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• pp.245-252
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• 2002

Thermodynamics and gas transport properties of polymethylmethacrylate (PMMA) blends with polyvinylmethylether (PVME) containing various amount of poly (styrene-b-methylmethacrylate) copolymer (P(S-b-MMA)) as a compatibilizer were studied. To extract interaction energies of binary pairs involved in the blends from the phase separation temperatures using an equation-of-state theory, PVME blends with methylmethacrylate copolymers containing various amount of styrene (SMMA) were prepared. PVME formed miscible blends with methylmethacrylate copolymers containing more than 70 wt% styrene and these miscible blonds showed a LCST-type phase separation behavior. Based on the interaction information obtained here, P(S-b-MMA) copolymer was added to the PMMA/PVME blends to enhance their compatibility. The average diameter of the dispersed rubber particles was gradually decreased for the blends of containing P(S-b-MMA) from 0 to 5 phr and then leveled off at a fixed size. At a fixed bland composition, the gas permeation was also increased as the P(S-b-MMA) content increased from 0 to 5 phr and then leveled off when the P(S-b-MMA) content was higher than 5 phr.

• Membrane Journal
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• v.19 no.2
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• pp.150-156
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• 2009

To improve the permselective efficiency of polysulfone membranes, the bromination was performed and then the resulting membranes were investigated in terms of membrane structures and gas transport characteristics. The brominated Polysulfone membranes were characterized by FT-IR, 1H-NMR, TGA, contact angle measurements, and gas permeation measurements were accomplished with He, $N_2,\;CO_2\;and\;O_2$. In general, the permeation rates were reduced while the selectivities increased as the bromination progressed.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.29 no.4
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• pp.195-201
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• 2017

In this study, the viscosity of a $CO_2-gas$ mixture was investigated for the transportation of the captured $CO_2-gas$ in pipelines and for the designing of a thermal system, both of which involve the utilization of the $CO_2-gas$ mixture. The viscosities of the $CO_2-gas$ mixture, $CO_2+CH_4$, $CO_2+H_2S$, and $CO_2+N_2$ were predicted using three different models as follows : Chung, TRAPP, and REFPROP. The predictability values of the models were validated by comparing the estimated results with the experiment data for the $CO_2+CH_4$ and $CO_2+N_2$ under high-density conditions. The Chung model showed 2.41%, which is the lowest mean deviation of the prediction among the model. Based on the Chung model, the mixture mole fractions were changed from 0.9, 0.95, and 0.97, the mixture pressure was ranged from 80 bar to 120 bar by 10 bar, and the mixture temperature was varied from 310 K to 400 K by 10 K to observe the effects of the parameters on the mixture viscosity. Considering the high mole fraction of the $CO_2$ in the mixture, a significant variation of the mixture viscosity was observed close to the pseudo-critical temperature, and the viscosity for the $CO_2+H_2S$ mixture shows the highest values compared with those of the $CO_2+CH_4$ and $CO_2+N_2$.