• Proceedings of the Membrane Society of Korea Conference
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• 1997.10a
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• pp.69-70
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• 1997

Polyimides and related polymers, when synthesized from aromatic monomers, have generally rigid chain structures resulting in a low gas permeability. The rigidity of polymer chains reduces the segmental motion of chains and works as a good barrier against gas transport. To overcome the limit of use as materials of gas separation membranes due to low gas permeability, block copolymers with the incorporation of flexible segments like siloxane linkage and ether linkage have been studied. These block copolymers have microphase-separated structures composed of microdomains of flexible poly(dimethylsiloxane) or polyether segments and of rigid polyimides segments. In case of rigid-flexible block copolymers, the characteristics of both phases for gas permeation are of great difference. The permeation of gas molecules occurs favorably through microdomains of flexible segments, whereas those of rigid segments hinder the permeation of gas molecules. Accordingly the increase of content of flexible segments in a rigid polymer matrix will increase the gas permeability of the membrane linearly. However, this prediction does not satisfy enough many experimental results and in particular the drastic increase of the permeability is observed in a certain volume fraction. It was proposed that the gas transport mechanism is dominated by diffusion rather than gas solubility in a certain content of flexible phase if solution-diffusion mechanism is adopted. However, the transition from solubility-dependent to diffusion-dependent cannot be explained by the understanding of mechanism itself. Therefore, we consider an effective chemical path which permeable phase can form in a microheterogenous medium, and percolation concept is introduced to describe the permeability transition at near threshold where for the first time a percolation path occurs. The volume fraction of both phases is defined as V$_{\alpha}$ and V$_{\beta}$ in block copolymers, and the volume of $\beta$ phase in the threshold forming geometrically a traversing channel is defined as V$_{\betac}$. The formation mechanism of shortest chemical channel is schematically depicted in Fig. 1.

• Journal of the Korean Electrochemical Society
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• v.16 no.1
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• pp.39-45
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• 2013

The water management is one of the key issues in low operating temperature proton exchange membrane fuel cells (PEMFCs). The gas diffusion layer (GDL) allows the reactant gases flow to the reaction sites of the catalyst layer (CL). At high current density, generated water forms droplets because the normal operating temperature is $60{\sim}80^{\circ}C$. If liquid water is not evacuated properly, the pores in the GDL will be blocked and the performance will be reduced severely. In this study, the microchannel GDL was proposed to solve the flooding problem. The liquid water transport through 3-D constructed conventional GDL and microchannel GDL was analyzed varying air velocity, water velocity, and contact angle. The simulation results showed that the liquid water was evacuated rapidly through the microchannel GDL because of the lower flow resistance. Therefore, the microchannel GDL was efficient to remove liquid water in the GDL and gas channels.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.51 no.3
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• pp.107-115
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• 2002

This parer presents the analysis of hot gas flow in puffer-type circuit breakers using FVFLIC method. For the analysis of arc-flow interaction, the flow field is analyzed from the equations of conservation for mass, momentum and energy with the assumption of local thermodynamic equilibrium state. The arc is represented as the energy source term composed of ohmic heating and radiation term in the energy conservation equation. Ohmic heating is computed by the electric field analysis only within the conducting plasma region. An approximate radiation transport model is employed for the evaluation of emission and absorption of the radiation. The analysis method was applied to the real circuit breaker model and simulation results such as pressure rise and arc voltage were compared with the experimental ones.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.4
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• pp.359-364
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• 2000

The paper describes the electron transport characteristics in SP$_{6}$+He gas calculated E/N values 0.1~700[Td] by the Monte Carlos simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters obtained by TOF method. This study gained the values of the electron swarm parameters such as the electron drift velocity the electron ionization or attachment coefficients longitudinal and transverse diffusion coefficients for SF$_{6}$+He gas at a range of E/N.E/N.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.279-283
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• 1998

The electron swarm parameters in the$CF_4$(O.l%, 5%)+Ar mixtures are measured by time of flight method over the E/N(Td) range from 10 to 300LTdl. A two-term approximation of the Boltzmann equation analysis and Monte Carlo simulation have been also used to study electron transport coefficients. We have calculated W, NDL, NDT, $\alpha$ and the limiting breakdown electric field to gas mixtures ratio in pure $CF_4$ gas and$CF_4+Ar$ mixtures. The measured results and the calculated results have been compared each other paper.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.1
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• pp.29-35
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• 2016

It is important to uniformly supply the fuel gas into the reaction activity area in polymer electrolyte membrane fuel cell (PEMFC). Recent studies have shown that the cell performance can be significantly improved by employing metal foam gas distributor as compared with the conventional bipolar plate types. The metal foam gas distributor has been reported to be more efficient to fuel transport. In this study, three-dimensional computational fluid dynamics (CFD) simulations have been performed to examine the effects of metal foam flow field design on the fuel supply to the reaction site. Darcy's law is used for the flow in the porous media. By solving additional advection equation for fluid particle trajectory, the gas transport has been visualized and examined for various geometrical configuration of metal foam gas distributor.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.167-172
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• 1997

The electron swarm parameters and Energy distribution function have been calculated for electrons motion through CH$_4$ pure gas under the action of uniform electric field for 0.1$\leq$E/N(Td)$\leq$300, at the 300( $^{\circ}$K), using MCS method and Boltzmann transport equation. And then the resulting values of electron drift velocity were compared to experimental data and adjustment made in assumed cross sections until good agreement was obtained. The electron drift velocity is very useful in the fields of study relating to the conductive and dielectric phenomena of gas medium. The electron energy distribution in gas discharge are generally nonmaxwellian , and must be calculated by a numerical solution of the Boltzmann equation which takes in the elastic and inelastic collisions. To analyze the physical phenomena and properties (or electron swarm motion in a gas under the influence of an electric field, the energy distribution function of electrons and the theoretical deriveration of the electron drift velocity are calculated by the Backward Prolongation with respect to the Boltzmann transport equation as a parameter of E/N(Td).

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.12
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• pp.1139-1144
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• 2005

This study has been performed to investigate the thermal performance of variable conductance heat pipe (VCHP) with meshed wick. The length of condenser portion in a VCHP is varied by the expansion of inert gas with the operation temperature, and the heat transport capacity is thus varied with the operating temperature. In this study, numerical evaluation of the VCHP is made for the thermal performance of VCHP, based on the diffusion model of inert gas. Water is used as a working fluid and nitrogen as a control inert gas in the copper tube. As a result, the thermal performance of VCHP has been compared with that of constant conductance heat pipe (CCHP) according to the variation of operation temperature. Maximum heat transport capacity of VCHP is mainly presented for operation temperature and the variation of operation temperature is also presented for heat transfer rate of VCHP.

• Nuclear Engineering and Technology
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• v.55 no.5
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• pp.1742-1756
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• 2023

The hydrogen behavior in a nuclear containment vessel is a significant issue when discussing the potential of hydrogen combustion during a severe accident. After the Fukushima-Daiichi accident in Japan, we have investigated in-depth the hydrogen transport mechanisms by utilizing experimental and numerical approaches. Computational fluid dynamics is a powerful tool for better understanding the transport behavior of gas mixtures, including hydrogen. This paper describes a Large-eddy simulation of gas mixing driven by a high-buoyancy flow. We focused on the interaction behavior of heat and mass transfers driven by the horizontal high-buoyant flow during density stratification. For validation, the experimental data of the Containment InteGral effects Measurement Apparatus (CIGMA) facility were used. With a high-power heater for the gas-injection line in the CIGMA facility, a high-temperature flow of approximately 390 ℃ was injected into the test vessel. By using the CIGMA facility, we can extend the experimental data to the high-temperature region. The phenomenological discussion in this paper helps understand the heat and mass transfer induced by the high-buoyancy flow in the containment vessel during a severe accident.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.86-88
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• 2002

The mathematical model was proposed to simulate ozone transport and remediation in unsaturated soils contaminated with phenanthrene. Soil column experiments were also carried out to calibrate the mathematical model. The experimental results successfully matched with the modeling results in various soil conditions. The model proposed nondimensional fraction factor to reveal reactivity between phenanthrene and gas phase ozone and liquid phase ozone. From sensitivity analysis, the fraction factor and stoichiometric coefficient decreased as water content increased. Simulation results showed increased SOM content retarded the ozone transport and the phenanthrene removal due to increased ozone consumption.