• 대한기계학회논문집B
• /
• 제37권8호
• /
• pp.767-773
• /
• 2013

본 연구는 높은 압력으로 체결되어 있는 고분자전해질연료전지(PEMFC) 스택의 구성부품중 가장 크게 변형되는 가스확산층(GDL)의 공극률과 기체투과율의 변화를 제시하였다. 압축하중에 따른 체적변화를 실험을 통하여 측정하고 기존에 제시된 관계식을 이용하여 공극률과 기체투과율의 변화을 예측하였다. 또한 물의 배출을 향상시키기 위하여 첨가되는 PTFE 가 압축상태의 GDL 의 공극률과 기체투과율에 미치는 영향을 연구하였다. 물질전달에 직접 영향을 미치는 기체투과율은 PTFE 가 많이 포함된 GDL에서 급격하게 감소하였다. 결과적으로 같은 압축하중으로 체결하는 경우 GDL 의 PTFE 함량에 따라서 공극네트워크를 통한 물질전달은 크게 달라질 수 있다. 본 결과를 이용하면 GDL 에서의 전달현상에 대한 개선된 상관식을 개발할 수 있고 그로 인하여 모델링의 정확성을 향상시킬 수 있다.

• 한국전기전자재료학회논문지
• /
• 제18권4호
• /
• pp.375-380
• /
• 2005

CF₄ molecular gas is used in most of semiconductor manufacture processing and SF/sub 6/ molecular gas is widely used in industrial of insulation field. but both of gases have defect in global warming. C₃F/sub 8/ gas has large attachment cross-section more than these gases, moreover GWP, life-time and price of C₃F/sub 8/ gas is lower than them, therefor it is important to calculate transport coefficients of C₃F/sub 8/ gas like electron drift velocity, ionization coefficient, attachment coefficient, effective ionization coefficient and critical E/N. The aim of this study is to get these transport coefficients for imformation of the insulation strength and efficiency of etching process. In this paper, we calculated the electron drift velocity (W) in pure C₃F/sub 8/ molecular gas over the range of E/N=0.1∼250 Td at the temperature was 300 K and gas pressure was 1 Torr by the Boltzmann equation method. The results of this paper can be important data to present characteristic of gas for plasma etching and insulation, specially critical E/N is a data to evaluate insulation strength of a gas.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1998년도 하계학술대회 논문집 E
• /
• pp.1752-1754
• /
• 1998

Recently the research about electron transport characteristic and energy distribute function in mixture gases within Helium, has been used and developed widely as industrial quality improvement of extinguish characteristic, electrical dielectric strength ability of application of each species high voltage apparatus, gas plasma etching progress of work to use manufacture of semiconductor, thin film molding by CVD, insulation film to use ultra LSI, etc. This paper analyze electron transport characteristic in the range E/N $1{\sim}60$[Td], pressure $0.1{\sim}6.0$[Torr] by MCS. It is necessary to seek electron drift velocity, diffusion coefficient, lonization coefficients, characteristic energy, mean energy and electron energy distribution function as electron transport characteristic.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
• /
• pp.164-167
• /
• 2001

The electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient $ND_L$ and $D_L/{\mu}$, in pure $CO_2$ were calculated over the wide E/N range from 0.01 to 500 Td at 1 Torr by two-term approximation of the Boltzmann equation for determination of electron collision cross sections set and for quantitative characteristic analysis of $CO_2$ molecular gas. And for propriety of two-term approximation of Boltzmann equation analysis, the calculated results compared with the electron transport coefficients measured by Nakamura.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2007년도 춘계학술대회
• /
• pp.511-514
• /
• 2007

Gas hydrate has a unique property that can store a large volume of gas in water as a solid form. Even though investigations for natural gas storage technology have been carried out for several decades, there are still a lot of unsolved problems due to complex formation process, low formation speed, high energy consumption and so on. So, lots of experiments were conducted to overcome these weaknesses and to develop artificial NGH formation technology applicable to industrial-scale storage and commercial transport. In this study, some series of experiments were performed to analyze both stirred and unstirred system especially about the influences of several gas hydrate formation factors such as agitation speed, system temperature, SDS concentration, etc. As a result, optimum range of SDS concentration and temperature that could enhance the storage capacity and shorten the formation time were found. And it is obviously presented that SDS such a kind of surfactant promotes gas hydrate formation dramatically and the quantity of stored gas are proportional to agitation speed in stirred system.

• Environmental Engineering Research
• /
• 제9권5호
• /
• pp.214-222
• /
• 2004

• 한국해양환경ㆍ에너지학회지
• /
• 제5권1호
• /
• pp.19-29
• /
• 2002

본 논문에서는 운송시간과 운송비용으로 구성되는 희생량 모델과 각 운송경로별 CO₂배출량을 고려한 수출입 컨테이너화물의 운송경로 선택에 관하여 고찰한다. 먼저 부산항을 이용하는 수출입 컨테이너화물의 물동량과 운송경로별 분담, 국내외 CO₂배출량 현황, 희생량 모델, 수출입 컨테이너화물의 시간가치에 대하여 간단히 살펴본다. 그리고 서울에서 발생한 수출입 컨테이너화물을 부산항으로 운송하는 경우를 가정하고 희생량 모델을 이용하여 계산한 각 운송경로별 희생량에 기초한 운송경로의 선택에 대하여 고찰한다. 또한 화물의 운송에 의하여 발생하는 CO₂배출량을 고려하여 결정한 환경부하 희생량을 추가한 희생량 모델을 이용한 운송경로의 선택에 대해서도 고찰한다. 본 연구의 결과, 희생량 모델에 기초한 컨테이너화물의 운송경로 선택이 수출입 컨테이너화물의 국내 수송 현황을 잘 나타내고 있는 것을 확인하였다. 또한 연안운송의 운송분담율을 높이기 위해서는 운송시간의 단축이 가장 효과적인 것을 확인하였다.

• 한국전기전자재료학회논문지
• /
• 제28권6호
• /
• pp.403-407
• /
• 2015

Generally, MWCNT, with thermal, chemical and electrical superiority, is manufactured with CVD (chemical vapor deposition). Using MWCNT, it is comonly used as gas sensor of MOS-FET structure. In this study, in order to repeatedly detect gases, the author had to effectively eliminate gases absorbed in a MWCNT sensor. So as to eliminate gases absorbed in a MWCNT sensor, the sensor was applied heat of 423[K], and in order to observe how the applied heat was diffused within the sensor, the author interpreted the diffusion process of heat, using COMSOL interpretation program. In order to interpret the diffusion process of heat, the author progressed modeling with the structure of MWCNT gas sensor in 2-dimension, and defining heat transfer velocity($u={\Delta}T/{\Delta}x$), accorded to governing equation within the sensor, the author proposed heat transfer mechanism.

• 한국막학회:학술대회논문집
• /
• 한국막학회 1995년도 제3회 심포지움 (분리막 연구의 최신동향)
• /
• pp.1-13
• /
• 1995

A review is presented for various gas tranport mechanisms through microporous membranes of both polymeric and inorganic materials. Different transport modes manifest depending on the pore size and the flow regime, which is a function of pressure, temperature, and the inateraction between gas molecules and the pore walls. For microporous membranes whose pores are small and the intenal surface area huge, the surface diffusion becomes a significant factor. If the pores become even smaller, them the transport mechanism will be more of an activated diffusion type. When conditions are right capillary condensation will take place to create an enormous capillary pressure gradient, which will greatly enhance the permeation flux. At the same time the capillary condensate of the heavier component may block the membrane pores denying the passage of the lighter gas molecules. All of these phenomena will influence the separation of mixtures.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2011년도 추계학술대회 초록집
• /
• pp.99.1-99.1
• /
• 2011

Reactant mixing has a critical role in ensuring reformate quality and an important design objective is to achieve sufficiently complete mixture of reactants. For that purpose it is required to understand the coupled transport-kinetics phenomena in the mixing region. Three-dimensional computational fluid dynamics model was developed and validated in previous works. The mixing characteristics in various alternatives of a prototype mixing chamber were compared, and then a reduced reaction kinetics was applied to two extreme designs for investigating the impact of gas-phase reactions. Both designs did not reach threshold ethylene mole fraction of 0.001, but surprisingly more ethylene was generated in the design having better mixing characteristics. The presentation will deliver the development process of coupled transport and kinetics model briefly and the detailed information about the mixing characteristics and gas-phase reactions in two mixer designs.