• Title/Summary/Keyword: gas recovery

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Thermodynamic analysis of a combined gas turbine power plant with a solid oxide fuel cell for marine applications

  • Welaya, Yousri M.A.;Mosleh, M.;Ammar, Nader R.
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.4
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    • pp.529-545
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    • 2013
  • Strong restrictions on emissions from marine power plants (particularly $SO_x$, $NO_x$) will probably be adopted in the near future. In this paper, a combined solid oxide fuel cell (SOFC) and gas turbine fuelled by natural gas is proposed as an attractive option to limit the environmental impact of the marine sector. It includes a study of a heat-recovery system for 18 MW SOFC fuelled by natural gas, to provide the electric power demand onboard commercial vessels. Feasible heat-recovery systems are investigated, taking into account different operating conditions of the combined system. Two types of SOFC are considered, tubular and planar SOFCs, operated with either natural gas or hydrogen fuels. This paper includes a detailed thermodynamic analysis for the combined system. Mass and energy balances are performed, not only for the whole plant but also for each individual component, in order to evaluate the thermal efficiency of the combined cycle. In addition, the effect of using natural gas as a fuel on the fuel cell voltage and performance is investigated. It is found that a high overall efficiency approaching 70% may be achieved with an optimum configuration using SOFC system under pressure. The hybrid system would also reduce emissions, fuel consumption, and improve the total system efficiency.

Parametric Study of Regenerative System with Oxy-Fuel Combustion (순산소 축열 연소시스템에서의 설계 파라미터에 관한 연구)

  • Hong, Sungkook;Noh, Dongsoon;Lee, Eunkyung
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.13-14
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    • 2013
  • The aim of this study is to investigate the parametric characteristics on regenerative system with oxy-fuel combustion by experiment. Regenerative system with a pair of oxygen burners and regenerators is used for evaluating regenerator characteristics according to design parameters such as ball (regenerator medium) size, regenerator weight, and bypass of exhaust gas. The temperature profiles with time are varied by ball size and regenerator weight. The bypass of exhaust gas shows that the heat recovery ratio increases while the regenerating temperature efficiency slightly decreases.

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Recovery of Ammonia Nitrogen using Gas-permeable Membranes (기체투과막을 이용한 암모니아성 질소 회수방안)

  • Lee, Sang-hun;Chae, Sang Yeop
    • Membrane Journal
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    • v.32 no.3
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    • pp.191-197
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    • 2022
  • Ammonia nitrogen can be effectively recovered from livestock manure waste, etc. by using the gas permeable membrane technology. In this case, ammonia gas in the waste passes through the pores in one-side of membrane, impregnated in waste, and then reach the opposite side of the membrane. The permeated ammonia gas molecules are captured and recovered by acid (such as sulfuric acid) in the solution existing on the opposite side of the membrane. In order to improve ammonia nitrogen removals in the inlet part, high pH should be maintained in the feed waste including ammonia nitrogen to recover, which requires the cost of the chemical. To resolve this issue, previous studies tested various methods, for example, utilization of cheap calcium hydroxide or aeration together with inhibition of unwanted nitrification. The gas permeable membranes used for the recovery of ammonia nitrogen may be characterized, not only by proper heat and chemical resistance, but also by hydrophobicity, allowing selective ammonia gas permeation through the hydrophobic membrane pores. Future research should consider the relevant pilot or upscale processes using on-site wastes with various properties, and identify the optimal design/operation conditions as well as economic feasibility improvement plans.

Study on Measurement Method of Dielectric Recovery Voltage to analysis Dielectric Recovery Characteristic of Molded Case Circuit Breaker (저압 배선용차단기 절연회복특성 파악을 위한 절연회복전압 측정기법 연구)

  • Song, Tae-Hun;Cho, Young-Maan;Ko, Kwang-Cheol
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.8
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    • pp.49-54
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    • 2015
  • Molded Circucit Breaker(MCCB) is a most widely used device to protect loads from the over-current in low power level distribution system. When the MCCB interrupts the over-current, the arc discharge occurred between fixed contact and moving contact to create hot gas. By the Lorentz force due to arc current, the occurred arc is bent to the grids. The grids extend and cool and divide it for arc extinguish. In the majority cases, the MCCB protects loads by interrupting the over-current successfully but in some cases the re-ignition is occurred by hot-gas created during process of interruption. The re-ignition arises when the recovery voltage(RV) is more higher than the recovery strength between contacts and it leads to interruption fault. Therefore to find out the dielectric recovery characteristics of protecting device has a great importance for preventing interruption fault. In this paper, we studies measurement method of the dielectric recovery characteristics considering inherent attribute of the MCCB. To measure the dielectric recovery characteristic of MCCB, we makes an experiment circuit for applying the over-current and the randomly recovery voltage. The measurement methode to find out the dielectric recovery voltage of the MCCB was established and the result was based on experiment results.

NO Gas Sensing Characteristics of Single-Walled Carbon Nanotubes and Heating Effect (단층 탄소나노튜브의 일산화질소 가스에 대한 감응특성과 열처리 효과)

  • Kim, Min-Ju;Yun, Kwang-Hyun;Huh, Jeung-Soo
    • Journal of Sensor Science and Technology
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    • v.13 no.4
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    • pp.292-297
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    • 2004
  • Carbon nanotubes (CNT) were synthesized by arc-discharge method. To fabricate CNT sensor, CNT powder was dispersed in ${\alpha}$-Terpinol($C_{10}H_{17}OH$) solution. The CNT tilms were fabricated by screen printing method on the interdigitated Pt/Pd alloy electrode. The microstructure of CNT film was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In order to investigate the gas sensing characteristics of the film, the CNT film was experimented to measure NO response and recovery time. The CNT sensor with a heater was compared to that without a heater. And this sensor shows better reproductibility and faster recovery time than another CNT sensors. We suggest the possibility to utilize a CNT as new sensing materials for environmental monitoring.

Analysis of Benzophenone in Sediment and Soil by Gas Chromatography/Mass Spectrometry (기체크로마토그래피/질량분석기에 의한 저질 및 토양시료 중 벤조페논의 분석법 연구)

  • 권오승;김은영;류재천
    • Environmental Analysis Health and Toxicology
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    • v.16 no.3
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    • pp.121-126
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    • 2001
  • Analytical method of benzophenone (BP) in sediment and soil was developed by gas chromatography/mass selective detector/selected ion monitoring (GC/MSD/SIM). The ultrasonic extraction of US EPA (method 3550B) method and liquid-liquid extraction for sediment and soil samples were used for the analysis of BP from sediment and soil. BP was extracted with n-hexane. Organic layer was washed with 5% sodium chloride solution. 1∼2 l of the concentrated solution of organic layer was applied to GC/MSD. The retention time of BP peak was 11.10 min. Recovery (%) of BP by ultrasonication from sediment and soil samples was 96.0∼100.6% and 40.0∼83.0%, respectively. Recovery of BP by liquid-liquid extraction was 51∼59% in soil samples. The detection limit of BP in sediment and soil samples were determined to 0.1 ng/g.

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MEMBRANE PROCESSES IN ENVIRONMENTAL TECHNOLOGY

  • Blume, I.;Smolders, C.A.
    • Membrane Journal
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    • v.2 no.1
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    • pp.1-20
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    • 1992
  • Classical membrane processes like microfiltration (MF), ultrafiltration (UF) and reverse osmosis (RO) are being applied in the last years more frequently in environmental and effluent process problems. Newer technologies and developments like pervaporation (PV) and gas sepaxation (GS) recently found commercial applications in the treatment of waste waters and gas streams. The incentive here is either the clean-up from organic components to comply with federal emission regulations or the recovery of the organics for economical reasons. Processes still in their development stage are combinations of chemical reactions with membrane processes to separate and treat $SO_x$ and $NO_x$ laden waste gas streams in the clean-up of stack-gases. In this paper we will first give a short overview of the more recent developments in MF, UF and RO. This is followed by a closer look on newer technologies applied in environmental problems. The applications looked at are the recovery of organic components from solvent laden gas streams and the separation of organic volatiles from aqueous waste waters via pervaporation. Technical solutions, the advantages and disadvantages of the processes and. where possible, cost estimations will be presented.

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A NOx gas sensor based on thennopile and embedded tin oxide catalyst (Thermopile과 삽입된 $SnO_2$ catalyst를 이용한 NOx 센서)

  • Lee, Chung-Il;Yoon, Seung-Il;Kim, Yong-Jun
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1829-1832
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    • 2008
  • This paper reports a novel gas sensing method by using a thermoelectric device, thermopile in this case, with an embedded tin oxide catalyst. By using a thin catalyst film, the response time and recovery time were remarkably improved. The fabricated gas sensor was characterized through detecting NOx gas with various concentrations.

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Formation and Dispersion of Nitric Acid Vapor from Stack Flue Gas

  • Park, Mi Jeong;Wu, Shi Chang;Jo, Young Min;Park, Young Koo
    • Asian Journal of Atmospheric Environment
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    • v.8 no.2
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    • pp.96-107
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    • 2014
  • Extreme recovery of the thermal energy from the combustion of flue gas may bring about early gas condensation resulting in the increased formation of nitric acid vapor. The behavior of the nitric acid formed inside the stack and in the atmosphere was investigated through a computer-aided simulation in this study. Low temperatures led to high conversion rates of the nitrogen oxide to nitric acid, according to the Arrhenius relationship. Larger acid plumes could be formed with the cooled flue gas at $40^{\circ}C$ than the present exiting gas at $115^{\circ}C$. The acid vapor plume of 0.1 ppm extended to 25 m wide and 200 m high. The wind, which had a seasonal local average of 3 m/s, expanded the influencing area to 170 m along the ground level. Its tail stretched 50 m longer at $40^{\circ}C$ than at $115^{\circ}C$. The emission concentration of the acid vapor in the summer season was a little lower than in the winter. However, a warm atmosphere facilitated the Brownian motion of the discharged flue gas, finally leading to more vigorous dispersion.

Hydrate Production Performance Analysis with Multi-Well, Plate-Type Apparatus Using Depressurization and Thermal Methods (다중공 평판형 장비를 이용한 감압법과 열자극법에 의한 하이드레이트 가스 생산성 분석)

  • Lee, Youngsoo;Wang, Jihoon;Park, Jungkyoon;Sung, Wonmo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.133-140
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    • 2009
  • This paper presents the experimental study to analyze the pressure and production behavior using depressurization and thermal methods in order to evaluate the hydrate productivity in the 2-D multi-well, plate-type apparatus which has 80 md permeability and 30% hydrate saturation. Injecting methane gas through multi-well allowed to set up the highly saturated hydrate system and combining two different sorts of sands made possible to build up the low permeability system. In this system, both depressurization and electric stimulation methods were applied. When operating pressure was low, according to the depressurization experiments results, the gas recovery was high, however strong pulses which appeared at initial stage of production would damage the operation system. Moreover, cases that hydrate reformed have occurred by endothermic reaction. We have conducted experiments four and six times for the depressurization magnitudes of 140 psi and 320 psi, respectively, to analyze production behavior for the method more in detail. For the cases that the depressurization magnitude was set as 140 psi, the unstable period appears in the results, but stabilized soon. In the experiment results for 320 psi the discontinuous and intermittent behavior has been observed. Thermal stimulation experiments was conducted with depressurizing 80 psi which is the case that shows stable behavior and low recovery. In the results, the gas recovery was high and the energy efficiency was low for long stimulating time. The energy efficiency and gas recovery increased for the soaking time of 1 minute after 2 minute-preheating. In the cases of which the soaking time exceeds 1 minute, energy loss by long soaking time caused low gas recovery and poor energy efficiency.