• 제목/요약/키워드: gas measurement method

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지방산 LB초박막의 수평방향에 대한 유기가스 반응특성 (Organic Gas Response Characteristics for Horizontal Direction of Fatty Acid LB Ultra-thin Films)

  • 이준호;최용성;김도균;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권5호
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    • pp.379-384
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    • 1999
  • Langmuir-Blodgett(LB) films which have high ordered orientation and ordering structure are fabricated by LB method which deposit the ultra-thin films of organic materials at a molecular level. The electrical characteristics of stearic acid LB ultra-thin films for the horizontal direction were investigated to develop the gas sensor using LB ultra-thin films. The optimal deposition condition to deposit the LB ultra-thin films was obtained from $\pi-A$ isotherms and the deposition status of stearic acid LB ultra-thin films was verified by the measurement of deposition ratio, UV-absorbance, and electrical properties for LB ultra-thin films. The conductivity of stearic acid LB ultra-thin films for horizontal direction was about $10_{-8}[S/cm]$. The activation energy for LB ultra-thin films with respect to variation of temperature was about 1.0[eV], which was correspond to semiconductor material. The response characteristics for organic gas were confirmed by measuring the response time, recovery time, and reproducibility of the LB ultra-thin to each organic gas. Also, the penetration and adsorption behavior of gas molecule were confirmed through the organic gas response characteristics of LB ultra-thin films with respect to temperature.

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LNG 밀도계를 이용한 저장 탱크 내 LNG 발열량 실시간 측정방법에 관한 연구 (A Study on the Method for Measuring the live Calorific Value of LNG in storage tank using LNG Densitometer)

  • 하영철;이성민
    • Korean Chemical Engineering Research
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    • 제49권1호
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    • pp.35-40
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    • 2011
  • 가스호환성에 문제가 있는 저열량의 LNG가 도입되기 시작한 것은 2005년 동절기부터이다. 이러한 LNG의 도입량은 매년 증가하고 있으며 향후에는 극저열량(발열량 ${\leq}$ 9,500 kcal/$Nm^3$)의 CBM(Coal Bed Methane), Shale LNG도 대량 도입될 예정에 있다. 따라서 호환 가능한 발열량의 가스를 인수기지에서 송출하기 위해서는 저장 탱크별 LNG 발열량을 실시간으로 모니터링할 수 있는 방법이 필요하게 되었다. 본 연구에서는 이러한 방법의 일환으로 저장 탱크 내설치된 밀도계를 이용하여 LNG 발열량을 실시간으로 측정할 수 있는 방법을 개발하고자 하였다. 이를 위해 액상 LNG와 발열량 간의 정밀 정확한 상관식을 도출하고 이 방법의 불확도를 계산하였으며 또 인수기지 내 발열량 측정 시스템을 시험 구축하였다. 본 방법의 유효성을 확인하기 위해 현장 LNG 분석데이터와 비교하였으며 그 결과 0.17~0.47%정도의 편차를 확인하였다.

CO2 EMISSION MEASURING METHODOLOGY DEVELOPMENT FOR ACCURACY IMPROVEMENT OF CO2 EMISSION OF CONSTRUCTION EQUIPMENT

  • Won-Suk Jang;Sun-Chan Bae;Sang-Dae Park;Suk-Hyun Kwon;Byung-Soo Kim
    • 국제학술발표논문집
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    • The 5th International Conference on Construction Engineering and Project Management
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    • pp.204-208
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    • 2013
  • CO2 emission makes up more than 80% of whole green gas. Therefore CO2 is recognized as the main culprit of global warming. IPCC (Intergovernmental Panel on Climate Change) is advising the 3 methods measuring CO2 emission. TIER1 is measured CO2 emission by criteria the energy consumption, TIER2 measure by criteria the emission factor according to the emission control technique each kind of vehicle, TIER3 is measured by criteria the distance each kind of vehicle. Currently, the most of CO2 emission measurement is used by TIER1. But it is not standardized that CO2 emission measurement method have the factor as work condition each distance. Specially, it is not suggest that methodology has the condition changing load of equipment according to site condition and the same position work as construction equipment. So, this study is suggested the CO2 emission measurement methodology of construction equipment.

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수소가스분위기하에서의 SnO2 박막의 전기적 거동 (Electrical Behaviors of SnO2 Thin Films in Hydrogen Atmosphere)

  • 김광호;박희찬
    • 한국세라믹학회지
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    • 제25권4호
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    • pp.341-348
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    • 1988
  • Thin films of tin-oxide were prepared by chemical vapor deposition technique using the direct of SnCl4. Resistivity and carrier concentration of deposited SnO2 thin film were measured by 4-point probe method and Hall effect measurement. The results showed the remarkable dependence of electrical properties on the deposition temperature. As the deposition temperature increased, resistivity of deposited film initially decreased to a minimum value of ~10-3$\Omega$cm at 50$0^{\circ}C$, and then rapidly increased to ~10$\Omega$cm at $700^{\circ}C$. Electrical conductance of these films was measured in exposure to H2 gas. It was found that gas sensitivity was affected combination of film thickness and intrinsic resistivity of deposited film. Gas sensitivity increased with decrease of film thickness. Fairly high sensitivity to H2 gas was obtained for the film deposited at $700^{\circ}C$. Optimum operation temperature of sensing was 30$0^{\circ}C$ for H2 gas.

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분광학적 방법에 의한 Plasma Jet의 온도분석 측정 (Spectroscopic Measurement of Temperature Distribution in Some Plasma Jets)

  • 전춘생;박용관;임명선
    • 전기의세계
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    • 제26권2호
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    • pp.104-110
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    • 1977
  • This paper investigates temperature distribution of plasma jets which used argon gas, and nitrogen gas mixed with argon as working fluids in spectroscopic method, and studies correlations between them main results are as follows; 1) The temperature at the center of plasma jet increases with are current and gas flow, and decreases with magnetic flux density along the axial direction. 2) The changing rate of temperature of plasma jet in the radial direction decreases rapidly beyond 2mm from central axis. 3) Temperature drop rate of plasma jet in the central axis direction appears most apparant beyond 13mm above the nozzle exit. 4) When argon gas mixed with a small amount of nitrogen, plasma temperature increases at same are current compared with the case of argon gas only.

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과산화수소 가스발생기 설계와 터보차저를 이용한 동력 측정 방법 검토 (Hydrogen Peroxide Gas Generator Design and Investigation of Power Measurement Method Utilizing Turbocharger)

  • 박대종;안성용;권세진
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년도 제31회 추계학술대회논문집
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    • pp.41-44
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    • 2008
  • 터빈 제너레이터 구동을 위한 과산화수소 촉매분해반응을 이용한 가스발생기를 설계하였다. 90 wt%의 rocket grade 과산화수소 가스발생기는 이산화망간을 촉매로 사용하였으며 온도와 압력조절이 용이하여 다양한 조건으로 터빈을 작동시키는데 적합하여 선정되었다. 가스발생기를 이용한 터빈 제너레이터에 대해 조사를 하고 소형 터빈 제너레이터를 개발하는데 앞서 차량용 터보차저를 이용하는 선행연구를 기획하였다.

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저압 배선용차단기 절연회복특성 파악을 위한 절연회복전압 측정기법 연구 (Study on Measurement Method of Dielectric Recovery Voltage to analysis Dielectric Recovery Characteristic of Molded Case Circuit Breaker)

  • 송태헌;조영만;고광철
    • 조명전기설비학회논문지
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    • 제29권8호
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    • pp.49-54
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    • 2015
  • Molded Circucit Breaker(MCCB) is a most widely used device to protect loads from the over-current in low power level distribution system. When the MCCB interrupts the over-current, the arc discharge occurred between fixed contact and moving contact to create hot gas. By the Lorentz force due to arc current, the occurred arc is bent to the grids. The grids extend and cool and divide it for arc extinguish. In the majority cases, the MCCB protects loads by interrupting the over-current successfully but in some cases the re-ignition is occurred by hot-gas created during process of interruption. The re-ignition arises when the recovery voltage(RV) is more higher than the recovery strength between contacts and it leads to interruption fault. Therefore to find out the dielectric recovery characteristics of protecting device has a great importance for preventing interruption fault. In this paper, we studies measurement method of the dielectric recovery characteristics considering inherent attribute of the MCCB. To measure the dielectric recovery characteristic of MCCB, we makes an experiment circuit for applying the over-current and the randomly recovery voltage. The measurement methode to find out the dielectric recovery voltage of the MCCB was established and the result was based on experiment results.

Preliminary Study of Micro Cold Gas Thruster

  • Moon, Seonghwan;Oh, Hwayollng;Huh, Hwanil
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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    • pp.617-621
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    • 2004
  • Miniaturization of subsystems including propulsion systems is recent trends in spacecraft technology. Small space vehicle propulsion is not only a technological challenge of a scaling system down, but also a combination of fundamental flow/combustion constraints. In this paper, physical constraints of micronozzle for cold gas micro-thruster are reviewed and discussed. Method to measure small thrust are also described.

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Analytical Techniques for Measurement of Crosslink Densities of Rubber Vulcanizates

  • Son, Chae Eun;Choi, Sung-Seen
    • Elastomers and Composites
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    • 제54권3호
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    • pp.209-219
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    • 2019
  • It is important to analyze crosslink densities of rubber articles because the physical properties are dependent on the crosslink densities. In this paper, analytical techniques for the measurement of crosslink densities of rubber vulcanizates are described. The most widely used method to measure the crosslink density is a swelling method combined with the Flory-Rehner equation. Application of the interaction parameter (${\chi}$) of rubber and swelling solvent is critical because the crosslink density is absolutely dependent on the ${\chi}$ value. Methods for obtaining ${\chi}$ employ not only solubility parameters of the polymer and swelling solvent but also inverse gas chromatography (IGC). The solubilities of rubbers can be obtained using micro differential scanning calorimetry (${\mu}DSC$), intrinsic viscosity measurement, and UV-visible spectroscopy. Nuclear magnetic resonance (NMR) spectroscopy has been also used for the measurement of the crosslink density using the $T_2$ relaxation time, which is determined by spin-spin relaxation in solid-state NMR. For sulfur-cured rubber vulcanizates, crosslink densities according to the crosslink types of mono-, di-, and polysulfides are measured by treating the rubber samples with a chemical probe composed of thiol and amine compounds. Measurement methods of physical crosslinking by filler, crystallization, and ionic bonding have also been introduced.

UV-Vis 분광분석에 의한 전기변압기 내 절연지 열화도 측정 (Application of UV-Vis Spectroscopic Analysis for Transformer Insulating Paper Degradation)

  • 공호성;한흥구
    • Tribology and Lubricants
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    • 제35권3호
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    • pp.151-157
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    • 2019
  • Insulated oil degradation produces charged by-products, such as acids and hydro-peroxides, which tend to reduce the insulating properties of the oil. In this study, UV-vis spectroscopy measurement technology is developed and experimentally compared with other measurement methods, such as the titration method and IR spectroscopy, to validate its ability to monitor the degradation of electrical insulating paper. The degradation characteristics of the insulating paper are appropriately represented through various types of measurement methods, such as the Tan (delta) method, $CO_2$ gas production measurement, the titration method, and IR spectroscopy. The results are demonstrated to be well comparable to a change in the fluorescence emission ratio (FER), which is defined as the shift in fluorescence intensity in the measured wavelength range, and also to the chromatic ratio, which is defined as a color shift to longer wavelength ranges. The results also show that, by using UV-vis spectroscopy, it is possible to detect the degradation of the insulating paper. This study suggests that UV-vis spectroscopy can be applied as an alternative to high-performance liquid chromatography, which is the internationally recognized measurement technology for cellulose paper degradation. The FER detector is also verified to be useful as an effective condition-monitoring device for power transformers.