• Title/Summary/Keyword: gas diffusion

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Studies on Food Preservation by Controlling Water Activity 1. Measurement of Sorption Isotherm of Dried Filefish Muscle by Equilibration in Dynamic Stream of Conditioned Air (식품보장과 수분활성에 관한 연구 1. 조절기류에 의한 건조말쥐치육의 등온흡습곡선의 측정)

  • HAN Bong-Ho;CHOI Soo-Il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.189-193
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    • 1981
  • An apparatus for continuous measurements of sorption isotherm of dried food was manufactured to shorten the time required for equilibration. The apparatus was so designed that the temperature, air velocity and relative humidity in the experimental chamber could be controlled. The use of dynamic stream of conditioned air with a velocity of 0.2m/sec, instead of static atmosphere, allowed a faster equilibration of dried filefish muscle at $25^{\circ}C$. The mean time necessary for the equilibration of dried filefish muscle at the water activity of a given state to a higher water activity was about 45 hours. The monolayer moisture content of dried filefish muscle calculated from BET-equation was 0.092 kg water /kg dry matter at $25^{\circ}C$.

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Antifungal Activities of the Essential Oils in Syzygium aromaticum (L.) Merr. Et Perry and Leptospermum petersonii Bailey and their Constituents against Various Dermatophytes

  • Park, Mi-Jin;Gwak, Ki-Seob;Yang, In;Choi, Won-Sil;Jo, Hyun-Jin;Chang, Je-Won;Jeung, Eui-Bae;Choi, In-Gyu
    • Journal of Microbiology
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    • v.45 no.5
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    • pp.460-465
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    • 2007
  • This study was carried out in order to investigate the potential of using plant oils derived from Leptospermum petersonii Bailey and Syzygium aromaticum L. Merr. Et Perry as natural antifungal agents. The antifungal effects of essential oils at concentrations of 0.05, 0.1, 0.15, and 0.2 mg/ml on the dermatophytes Microsporum canis (KCTC 6591), Trichophyton mentagrophytes (KCTC 6077), Trichophyton rubrum (KCCM 60443), Epidermophyton floccosum (KCCM 11667), and Microsporum gypseum were evaluated using the agar diffusion method. The major constituents of the active fraction against the dermatophytes were identified by gas chromatography-mass spectrometry and high-performance liquid chromatography analysis. The antifungal activities of S. aromaticum oil (clove oil) against the dermatophytes tested were highest at a concentration of 0.2mg/ml, with an effectiveness of more than 60%. Hyphal growth was completely inhibited in T. mentagrophytes, T. rubrum, and M. gypseum by treatment with clove oil at a concentration of 0.2 mg/ml. Eugenol was the most effective antifungal constituent of clove oil against the dermatophytes T. mentagrophytes and M. canis. Morphological changes in the hyphae of T. mentagrophytes, such as damage to the cell wall and cell membrane and the expansion of the endoplasmic reticulum, after treatment with 0.11 mg/ml eugenol were observed by transmission electron microscopy (TEM). At a concentration of 0.2 mg/ml, L. petersonii oil (LPO) was more than 90% effective against all of the dermatophytes tested, with the exception of T. rubrum. Geranial was determined to be the most active antifungal constituent of L. petersonii oil. Taken together, the results of this study demonstrate that clove and tea tree oils exhibited significant antifungal activities against the dermatophytes tested in this study.

Development of an Automated and Continuous Analysis System for PM2.5 and Chemical Characterization of the PM2.5 in the Atmosphere at Seoul (자동연속측정시스템 개발 및 이 시스템을 이용한 서울 대기 중 PM2.5의 화학적 조성과 특성에 관한 연구)

  • Lee Bo Kyoung;Kim Young Hoon;Ha Jae Yoon;Lee Dong Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.4
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    • pp.439-458
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    • 2005
  • An automated analysis system for water soluble constituents in $PM_{2.5}$ has been developed. The system consists of a high capacity multi tube diffusion scrubber (MTDS), a low temperature particle impactor (LTPI), and two ion (anion and cation) chromatography (IC) systems. Atmospheric particles have been collected by passing sample air through a thermostated MTDS followed by a LTPI. This system allows simultaneous measurements of soluble ions in $PM_{2.5}$ at 30 minutes interval. At the air sampling flow rate of 1.0L/min, the detection limits of the overall system are in the order of tens of $ng/m^3$. This system has been successfully used for the measurement of particulate components of Seoul air from April 2003 to January 2004. $SO_4^{2-},\;NO_3^-,\;NH_4^+,\;NO_2^-,\;Cl^-,\;Na^+,\;K^+,\;Ca^{2+},\;and\;Mg^{2+}$ are the major ionic species for $PM_{2.5}$ at Seoul. Among them, $SO_4^{2-},\;NO_3^-\;and\;NH_4^+$ are the most abundant ions, contributed up to $86\%$ of the total and the concentrations were higher than those in any other urban sites in the world except for Chinese cities. There are high pollutant episodes which contribute about $15\~20\%$ of annual average values of the major ions. During the episode, the all parcels were transported from the asian continent and $PM_{2.5}$ were significantly neutralized. This suggests that aged and long range transported pollutants caused the high pollutant episodes. They showed a distinct daily and seasonal variations:they showed a peak in the early morning caused by the night-time accumulation of particulate matters. Atmospheric reactions including gas-to-particle reactions and inter-particle reactions and meteorological parameters including relative humidity and ambient temperature were described with related to the $PM_{2.5}$ 5 concentrations. All of the ionic species showed higher concentrations during the spring than those for summer and winter.

Friction Factor in Micro Channel Flow with Electrochemical Reactions in Fuel Cell (전기화학반응을 수반한 유로채널 형상에 따른 마찰계수에 대한 연구)

  • Cho, Son-Ah;Lee, Pil-Hyong;Han, Sang-Seok;Choi, Seong-Hun;Hwang, Sang-Soon
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.245-251
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    • 2007
  • The performance of fuel cell is enhanced with increasing reaction surface. Narrow flow channels in flow plate cause increased pumping power. Therefore it is very important to consider the pressure drops in the flow channel of fuel cell. Previous research for pressure drop for micro channel of fuel cell was focused on effects of various configuration of flow channel without electrochemical reaction. It is very important to know pressure loss of micro flow channel with electrochemical reaction because fluid density in micro channel is changed due to chemical reaction. In this paper, it is investigated that the pressure drops in micro channel of various geometries at anode and cathode with electrochemical reaction and compared them to friction coefficient (fRe), velocity, pressure losses for corresponding non reacting flow channel. The results show that friction factors for cold flow channel could be used for parallel and bended flow channel for flow channel design of fuel cell. In the other hand, pressure drop for serpentine flow channel is the lowest among flow channels due to bypass flow across gas diffusion layer under reacting flow condition although its pressure drop is highest for cold flow condition.

Mössbauer Study of Silver Nanoparticle Coated Perovskites La0.7Sr0.3Co0.3Fe0.7O3-δ (LSCF) (은(Ag) 나노입자가 코팅된 페롭스카이트 La0.7Sr0.3Co0.3Fe0.7O3-δ의 Mössbauer 분광연구)

  • Uhm, Young-Rang;Rhee, Chang-Kyu;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.22 no.2
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    • pp.37-41
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    • 2012
  • The Ag nanoparticles attached $La_{0.7}Sr_{0.3}Co_{0.3}Fe_{0.7}O_{3-{\delta}}$ (LSCF) perovskites were prepared by plasma method. The Ag nanoparticles with size of several nanometers deposited from the Ag target were coated on the surface of LSCF powders with size range from 0.2 to 3 ${\mu}m$. The agglomeration of Ag particles annealed at $800^{\circ}C$ under inert gas of Ar were rarely observed. The inter-diffusion between surface Ag and core LSCF is effectively strong to prevent aggregation of Ag nanoparticles. The wave number of FT-IR spectra for LSCF were largely shifted as the concentration of Ag on LSCF up to 2.11 wt.%. The ionic states of irons in LSCF were measured by M$\ddot{o}$ssbauer spectroscopy. The small amount of $Fe^{4+}$ ions are converted to $Fe^{3+}$ ions after Ag nanopartcles were coated on LSCF.

Characteristics of Fe-6.5wt%Si Core Material by Chemical Vapor Deposition Method (화학기상증착에 의한 Fe-6.5wt%Si철심재료의 특성평가)

  • Yun, Jae-Sik;Kim, Byeong-Il;Park, Hyeong-Ho;Bae, In-Seong;Lee, Sang-Baek
    • Korean Journal of Materials Research
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    • v.11 no.6
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    • pp.512-518
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    • 2001
  • It has been well known that 6.5wt% Si steel sheets have excellent magnetic properties such as low core loss. high maximum permeability and low magnetostriction. In this work, we studied a method for producing 6.5wt% Si steel sheets using a chemical vapor deposition (CVD) method. The following is the procedure adopted in this work to produce 6.5wt% Si steel sheets; SiCl$_4$ gas is applied onto a low content-Si steel sheet placed in a tube furnace. Silicon atoms resulted from the decomposition of SiCl$_4$ are permeated through the surface of the steel sheet. Finally, by the diffusion process maintaining it under a high temperature the silicon atoms diffuse uniformly into the sheet. Through this process, 6.5wt% Si steel sheets can be obtained. The manufactured Fe-6.5wt% Si steel sheet with a thickness of 0.5mm exhibited a high frequency core loss (W$_{2}$1k/) of 8.92 W/kg. Its permeability increased from 37,100 to 53,300 at 1 tesular(T). The mechanical properties of the manufactured steel sheets were also estimated and the result showed that the workability was significantly improved by annealing in vacuum at 773k. Increased plastic deformation was also observed prior to fracture and the amount of grain boundary rupture was reduced.

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Toxicity Monitoring and Assessment of Nanoparticles Using Bacteria (박테리아를 이용한 나노입자의 독성평가 및 탐지)

  • Hwang, Ee-Taek;Lee, Jung-Il;Sang, Byoung-In;Gu, Man-Bock
    • KSBB Journal
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    • v.22 no.6
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    • pp.414-420
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    • 2007
  • Nanomaterials have been applied to various fields due to their advantageous characteristics such as high surface area, rapid diffusion, high specific surface areas, reactivity in liquid or gas phase, and a size close to biomacromolecules. Up to date, increased manufacturing and frequently use of the materials, however, revoke people's concerns on their hazard impact including toxicity the materials. Many research groups have carried out different protocols to evaluate toxic effects of nanomaterilas on different organisms, and consequently, nanomaterials are known to cytotoxicity. In this paper, we reviewed some of the most reports on toxic effects of several nanoparticles specifically on bacteria. There are numbers of reports focused on antibacterial effect of nanoparticles based on bacterial cell viability. Therefore, the application of each nanomaterial should be concerned with its toxicity and its toxic effect should be evaluated in terms of concentrations and sizes of the nanomaterials used, prior to use of a nanomaterial.

Effect of Current Density on Ion Conductivity of Membrane in Proton Exchange Membrane (고분자전해질 연료전지에서 고분자막의 이온전도도에 미치는 전류밀도의 영향)

  • Hwang, Byungchan;Oh, Sohyung;Lee, Daewoong;Chung, Hoi-Bum;You, Seung-Eul;Ku, Young-Mo;Na, Il-Chae;Lee, Jung-Hoon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.1-5
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    • 2018
  • In this work, we study the ion conductivity by analyzing the impedance to the high current density range that the PEMFC (Proton Exchange Membrane Fuel Cell) is actually operated. The effect of GDL (Gas Diffusion Layer)presence on impedance was investigated indirectly by measuring hydrogen permeability. When the RH (Relative Humidity)was higher than 60% in the low current range (< $80mA/cm^2$), the moisture content of the polymer membrane was sufficient and the ion conductivity of the membrane was not influenced by the current change. However, when RH was low, ion conductivity increased due to water production as current density increased. The ion conductivity of the membrane obtained by HFR (High Frequency Resistance) in the high current region ($100{\sim}800mA/cm^2$)was compared with the measured value and simulated value. At RH 100%, both experimental and simulated values showed constant ion conductivity without being influenced by current change. At 30~70% of RH, the ionic conductivity increased with increasing current density and tended to be constant.

Performance of Hybrid Solar Still Under Operating Conditions (하이브리드 태양열 해수담수기의 운전 조건별 성능실험)

  • Yeo, Se Dong;Lim, Byung Ju;Yu, Sang Seok;Chung, Kyung Yul;Park, Chang Dae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.8
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    • pp.511-519
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    • 2017
  • In this study, we have performed tests to improve the productivity of hybrid solar stills, which can be operated by solar thermal energy and/or waste heat of exhaust gas from electrical generators. The experimental apparatus is a hybrid solar still with a $1m{\times}2m$ collecting area, which consists of a conventional simple solar still and a vertical multi-effect diffusion(MED) section. The experiments were conducted under various operating conditions, with two identical hybrid solar stills, using solar radiation as the energy source. The results of the tests showed that the yield of the hybrid solar still depends on the various operating conditions. Insulation at the side glasses and a lower basin seawater level increased the productivity of the hybrid solar still. Reflecting fins with less than 47% reflectivity unexpectedly decreased the total productivity. However, the various feeding flow rate of the seawater into MED part did not show clear effects on productivity in the tested range.

Right Ventricle Ejection Fraction Contributes Severity of Dyspnea in Chronic Obstructive Pulmonary Disease (COPD) (만성폐쇄성폐질환 환자의 호흡곤란 평가에서 우심실 박출계수의 의의)

  • Lee, Jung Eun;Min, Bo Ram;Park, Jae Seok;Park, Hun Pyo;Jun, Mi Jung;Won, Kyung Sook;Choi, Won Il
    • Tuberculosis and Respiratory Diseases
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    • v.60 no.6
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    • pp.631-637
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    • 2006
  • Background: Patients with COPD generally complain of very different degrees of dyspnea regardless of their pulmonary function. The study, we assessed the right ventricular ejection fraction in relation to dyspnea in COPD patient. Methods: The pulmonary function including the diffusion capacity was measured. The right ventricle ejection fraction (RVEF) was measured using a first-pass radionuclide scan by multigated acquisition (MUGA). Forty patients with chronic obstructive pulmonary disease (COPD) were stratified for dyspnea according to the Medical Research Council (MRC) scale. Moderate dyspnea and severe dyspnea is defined as MRC 2/3 (n = 16) and MRC 4/5 (n = 24) respectively. Results: The baseline pulmonary function tests including DLCO and the resting arterial blood gas were similar in the moderate and severe dyspnea group, with the exception of the residual volume (% predicted) (moderate $160{\pm}27$, severe $210{\pm}87$, p < 0.03). The right ventricle ejection fraction was significantly (p < 0.001) lower in the severe dyspnea group ($25{\pm}8$) than in the moderate group ($35{\pm}6$). The independent factor assessed by multiple logistic regression revealed only the severity of dyspnea to be significantly associated with RVEF (p < 0.02). Conclusion: This study showed that the right ventricle ejection fraction would contributes to severity of dyspnea in patients with a similar pulmonary function.