• Title/Summary/Keyword: gas cross-over

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The Character of Electron Ionization and Attachment Coefficients in Perfluoropropane(C3F8) Molecular Gas by the Boltzmann Equation (볼츠만 방정식에 의한 C3F8분자가스의 전리 및 부착 계수에 관한 연구)

  • Song, Byoung-Doo;Jeon, Byoung-Hoon;Ha, Sung-Chul
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.4
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    • pp.375-380
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    • 2005
  • CF₄ molecular gas is used in most of semiconductor manufacture processing and SF/sub 6/ molecular gas is widely used in industrial of insulation field. but both of gases have defect in global warming. C₃F/sub 8/ gas has large attachment cross-section more than these gases, moreover GWP, life-time and price of C₃F/sub 8/ gas is lower than them, therefor it is important to calculate transport coefficients of C₃F/sub 8/ gas like electron drift velocity, ionization coefficient, attachment coefficient, effective ionization coefficient and critical E/N. The aim of this study is to get these transport coefficients for imformation of the insulation strength and efficiency of etching process. In this paper, we calculated the electron drift velocity (W) in pure C₃F/sub 8/ molecular gas over the range of E/N=0.1∼250 Td at the temperature was 300 K and gas pressure was 1 Torr by the Boltzmann equation method. The results of this paper can be important data to present characteristic of gas for plasma etching and insulation, specially critical E/N is a data to evaluate insulation strength of a gas.

Mean energy of electrons in $SF_6$-Ar Mixtures Gas ($SF_6$-Ar 혼합기체(混合氣體)의 전자(電子) 평균(平均)에너지)

  • Kim, Sang-Nam;Seong, Nak-Jin
    • Proceedings of the KIEE Conference
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    • 2003.07e
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    • pp.75-78
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    • 2003
  • Energy distribution function for electrons in $SF_6$-Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range $30\sim300$[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6$-Ar mixtures were measured by time-of-flight(TOF) method. The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values. The transport coefficients for electrons in (0.2[%])$SF_6$-Ar and (0.5[%]$SF_6$ - Ar mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

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Analysis on the Mean energy of electrons in $SF_6-Ar$ Mixtures Gas used by MCS-BEq Algorithm ($SF_6-Ar$ 혼합기체(混合氣體)의 MCS-BEq알고리즘에 의한 전자(電子) 평균(平均)에너지 해석(解析))

  • Kim, Sang-Nam;Ha, Sung-Chul
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2004.05a
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    • pp.281-284
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    • 2004
  • Mean energy of electrons in $SF_6-Ar$ Mixtures Gas used by MCS-BEq algorithm has been analysed over the E/N range $30{\sim}300[Td]$ by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6-Ar$, 0.1[%] and 5.0[%], $SF_6-Ar$ mixtures were measured by time-of-flight(TOF) method. The transport Coefficients for electrons in (100[%])$SF_6$. (100[%])Ar, (0.2[%])$SF_6-Ar$ and (0.5[%]) $SF_6-Ar$, (5.0[%]) $SF_6-Ar$, (0.1[%])$SF_6-Ar$ mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

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A study on the electron transport coefficients in $GeH_4$ gas ($GeH_4$기체의 전자수송계수에 관한 연구)

  • Ryu, Sun-Mi;Jeon, Byung-Hoon
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1404_1405
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    • 2009
  • For quantitative understanding of gas discharge phenomena, we should know electron collision cross section. $GeH_4$ is used in many applications with $Si_2H_6$ gas, such as amorphous alloy, a thin film of silicon and solar cell. Therefore, we understand the electron transport characteristics and analysed the electron transport coefficients, the electron drift velocity W, the longitudinal and transverse diffusion coefficient $ND_L$ and $ND_T$, and the ionization coefficient $\alpha$/N in $GeH_4$gas over the E/N range from 0.01 to 1000 Td by two-term approximation of the Boltzmann equation.

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Corrosion and Strength Degradation Characteristics of 1.25Cr-0.5Mo Steel under SO2 Gas Environment (SO2 가스 환경 하에서 1.25Cr-0.5Mo 강의 부식 및 강도 저하 특성)

  • Jung, Kwang-Hu;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.51 no.3
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    • pp.149-156
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    • 2018
  • The corrosion and strength degradation characteristics of 1.25Cr-0.5Mo steels were studied under $650^{\circ}C$ in $76%N_2+6%O_2+16%CO_2+2%SO_2$ gas condition up to 500 hrs. Corroded specimens were characterized by weight gain, scanning electron microscope(SEM), energy dispersive X-ray spectroscopy(EDS), and X-ray diffraction(XRD). The tensile test was conducted to evaluate the mechanical strength and fracture mode with corrosion at high temperature. As the results of the experiments, thick Fe-rich oxide layers over $200{\mu}m$ were formed on the surface within 500 hrs. The thick oxide layers are formed with reduction of the cross-sectional area of the specimens. Thus, the strength tended to decrease with reduction of the cross-sectional area.

Ionization and Attachment Coefficients in Mixtures of $SF_6$ and Ar ($SF_6$-Ar 혼합기체에서의 전리와부착계수)

  • 김상남;하성철
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.9
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    • pp.773-778
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    • 2001
  • In this dissertation the results of the combined experimental and theoretical studies designed to understand and predict the spatial growth and transport coefficients for electrons in SF$_{6}$ and SF$_{6}$-Ar mixtures have described. The ionization and attachment coefficients in pure SF$_{6}$ and SF$_{6}$-Ar mixtures have been calculated over the range of 10$_{6}$ molecule and for Ar atom proposed by other authors. The transport coefficients for electrons in (0.2%)SF$_{6}$-Ar and (0.5%)SF$_{6}$-Ar mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained in this work will provide valuable information on the fundamental haviors of electrons in weakly ionized gases and the role of electron attachment in the choice of better gases and unitary gas dielectrics or electro negative components in dielectric gas mixtures. gas mixtures.

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Static displacement and elastic buckling characteristics of structural pipe-in-pipe cross-sections

  • Sato, M.;Patel, M.H.;Trarieux, F.
    • Structural Engineering and Mechanics
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    • v.30 no.3
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    • pp.263-278
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    • 2008
  • Structural pipe-in-pipe cross-sections have significant potential for application in offshore oil and gas production systems because of their property that combines insulation performance with structural strength in an integrated way. Such cross-sections comprise inner and outer thin walled pipes with the annulus between them fully filled by a selectable thick filler material to impart an appropriate combination of properties. Structural pipe-in-pipe cross-sections can exhibit several different collapse mechanisms and the basis of the preferential occurrence of one over others is of interest. This paper presents an elastic analyses of a structural pipe-in-pipe cross-section when subjected to external hydrostatic pressure. It formulates and solves the static and elastic buckling problem using the variational principle of minimum potential energy. The paper also investigates a simplified formulation of the problem where the outer pipe and its contact with the filler material is considered as a 'pipe on an elastic foundation'. Results are presented to show the variation of elastic buckling pressure with the relative elastic modulus of the filler and pipe materials, the filler thickness and the thicknesses of the inner and outer pipes. The range of applicability of the simplified 'pipe on an elastic foundation' analysis is also presented. A brief review of the types of materials that could be used as the filler is combined with the results of the analysis to draw conclusions about elastic buckling behaviour of structural pipe-in-pipe cross-sections.

Characteristics of Electron Beam Extraction in Cold Cathode Type Large Cross-Sectional Pulsed Electron Beam Generator (냉음극형 대면적 펄스 전자빔 가속기의 빔인출 특성)

  • Woo, S.H.;Lee, K.S.;Lee, D.I.;Lee, H.S.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1609-1611
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    • 2001
  • A large cross-section pulsed electron beam generator of cold cathode type has been developed for industrial applications, for example, waste water cleaning, flue gas cleaning, and pasteurization etc. The operational principle is based on the emission of secondary electrons from cold cathode when ions in the plasma hit the cathode, which are accelerated toward exit window by the gradient of an electric potential. The conventional electron beam generators need an electron scanning beam because the small cross section thermal electron emitter is used. The electron beam of large cross-section pulsed electron beam generator do not need to be scanned over target material because the beam cross section is large by 300$cm^2$. We have fabricated the large cross-sectional pulsed electron beam generator with the peak energy of 200keV and beam diameter of 200mm and obtained the large area electron beam in the air. The electron beam current has been investigated as a function of accelerating voltage, glow discharge current, helium pressure, distance from the exit window and radial distribution in front of the exit window.

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Ionization and Attachment Coefficients in CF4, CH4, Ar Mixtures Gas (CF4, CH4, Ar 혼합기체의 전리와 부착계수)

  • Kim, Sang-Nam
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.61 no.1
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    • pp.13-17
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    • 2012
  • Ionization and Attachment Coefficients in pure $CH_4$, $CF_4$ and mixtures of $CF_4$ and Ar, have been analyzed over a range of the reduced electric field strength between 0.1 and 350[Td] by the two-term approximation of the Boltzmann equation (BEq.) method and the Monte Carlo simulation (MCS). The calculations of electron swarm parameters require the knowledge of several collision cross-sections of electron beam. Thus, published momentum transfer, ionization, vibration, attachment, electronic excitation, and dissociation cross-sections of electrons for $CH_4$, $CF_4$ and Ar, were used. The results of the Boltzmann equation and the Monte Carlo simulation have been compared with the data presented by several workers. The deduced transport coefficients for electrons agree reasonably well with the experimental and simulation data obtained by Nakamura and Hayashi. The energy distribution function of electrons in $CF_4$-Ar mixtures shows the Maxwellian distribution for energy. That is, f(${\varepsilon}$) has the symmetrical shape whose axis of symmetry is a most probably energy. The proposed theoretical simulation techniques in this work will be useful to predict the fundamental process of charged particles and the breakdown properties of gas mixtures.