• Title/Summary/Keyword: gamma ray dose

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Functionalization of polyethylene by graft copolymerization for separation processes

  • Kaur, Inderjeet;Gupta, Nitika;Kumari, Vandna
    • Advances in materials Research
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    • v.2 no.1
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    • pp.15-36
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    • 2013
  • Incorporation of polar functional moieties into polyethylene (PE) film has been achieved by graft copolymerization of polar monomers such as methacrylic acid (MAAc) and acrylamide (AAm) on to PE film, preirradiated with ${\gamma}$-rays from $^{60}Co$ source, using benzoyl peroxide (BPO) as initiator in aqueous medium. Percentage of grafting of MAAc and AAm was determined as a function of irradiation dose, monomer and initiator concentration, temperature, reaction time and amount of water. Maximum percentage of grafting of MAAc (1453%) and AAm (21.28%) was obtained at [MAAc] = $235.3{\times}10^{-2}$ mol/L, [AAm] = $23.4{\times}10^{-2}$ mol/L, [BPO] = $5.5{\times}10^{-2}$ mol/L and $16.5{\times}10^{-2}$ mol/L at $80^{\circ}C$, $90^{\circ}C$ in 180 min and 90 min respectively. The grafted PE films were characterized by FTIR, Thermogravimetric analysis (TGA) Scanning Electron Micrography (SEM) and X-ray diffraction methods. Some selective properties of grafted films such as swelling behavior, ion and metal uptake have been carried out. The biodegradation studies of the grafted PE films have also been investigated. The grafted films developed superior swelling behavior with maximum swelling (480%) in water as compared to pristine PE (13.55%), better thermal stability and ion and metal uptake studies showed promising results that can be effectively used for desalination of brackish water and separation of metals from the industrial effluents.

Radiation-Induced Graft Copolymerization of Methacrylic Acid and Methyl methacrylate onto Polyester.

  • Kang, Young-Kun;Chang, Hoon-Seun;Lee, Chong-Kwang;Park, Jae-Ho
    • Nuclear Engineering and Technology
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    • v.10 no.4
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    • pp.195-201
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    • 1978
  • The radiation-induced graft polymerization of methacrlic acid and methyl methacrylate onto a polyester fabric was investigated with ${\gamma}$-ray as the radiation source, and the rate of grafting was examined. When acrylic acid, methacrylic acid, and methyl methacrylate were grafted onto a polyester fabric, grafting efficiency was depened upon the dielectric constant of the solvent in the monomer mixture. The yield of the graft polymerization was related to the total dose, the concentration of the monomer, and the concentration of the swelling agent. The melting point and the glass transition temperature of MA and MMA grafted copolymers were analysed by means of DTA. Physical properties, such as the moisture regain, the antistatic property, and the wicking time were measured.

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Detection of Irradiated Potato and Garlic by Thermoluminescence Measurement (Thermoluminescence 측정에 의한 감자와 마늘의 방사선 조사유무 확인)

  • Chung, Hyung-Wook;Kwon, Joong-Ho
    • Korean Journal of Food Science and Technology
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    • v.30 no.2
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    • pp.283-287
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    • 1998
  • Potato and garlic irradiated with gamma ray and electron beam at sprout-inhibition doses, 0.15 and 0.30 kGy were subjected to the detection whether they are irradiated or not by measuring thermoluminescence(TL) for the minerals adhering to the samples. Minerals extracted from the samples showed a high correlation coefficients between absorbed doses and corresponding TL responses. Nonirradiated samples, however, did not exhibit characteristic TL glowcurves. Major glowcurve peaks were observed at 200 to $260^{\circ}C$ in all irradiated samples. TL intensity was proportional to irradiated doses, but it varied with the samples tested even at the same dose. It can be concluded from the results that detection of irradiated potato and garlic is possible by measuring TL for extracted minerals from the unknown samples.

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A high energy radiation evaluation test of the 74AC04 Hex Inverter (고준위 감마방사선 환경에서의 원격계측을 통한 74AC04 의 내방사선 영향평가 및 분석)

  • Oh, Seung-Chan;Lee, Hyun-Jin;Lee, Nam-Ho;Lee, Heung-Ho
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1788_1789
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    • 2009
  • 본 논문에서는 핵폭발과 같은 고준위방사선환경에서의 전자부품소자의 피해평가분석을 통하여 군용전자장비의 내방사선화를 하기 위한 기반기술의 확립을 위한 연구의 일환으로 74AC04(Inverter) IC에 대한 고준위감마선조사시험을 통하여 Co-60 Gamma-ray 선원을 사용하여 총 400Krad[si] 누적 선량에 대한 74AC04 소자의 동작특성 및 전기적 파라메터의 변화분석을 진행하였다. 시험평가 방법 및 절차는 MIL-STD-883G 1019.7[1] 및 ESA/SCC Basic Specification No.22900[2] 절차를 기준으로 하여 동일 lot에 대한 5개의 샘플을 이용하여 동작특성에 영향을 미치는 주요한 전기 적파라메터인 정지소비전류, 입력누설전류, VIL(Maximum Low Level Input Voltage)에 대한 변화추이를 분석하였다. 이번 조사시험을 통하여 입력게이트에서의 누적선량에 따른 TID(Total Ionizing Dose) 효과로 인한 VIL의 감소 추이를 확인 할 수 있었으며 총 누적선량 160Krad 이상에서의 VIL은 허용기준치이하로 감소하였고 정지소비전류의 경우 누적선량에 따른 점진적 증가 현상과 200Krad부근에서의 설계스펙허용치를 초과하는 결과를 확인하였다.

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Distribution of natural radioactivity in soil and date palm-pits using high purity germanium radiation detectors and LB-alpha/beta gas-flow counter in Saudi Arabia

  • Shayeb, Mohammad Abu;Baloch, Muzahir Ali
    • Nuclear Engineering and Technology
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    • v.52 no.6
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    • pp.1282-1288
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    • 2020
  • In the first study, the Radon emanation and radiological hazards associated with radionuclides in soil samples, collected from 9 various date palm farms located in 3 different districts in Saudi Arabia were determined through a high purity Germanium (HPGe) gamma-ray spectrometer. The estimated average values of Radon emanation coefficient and Radon mass exhalation rate for soil samples were 0.535 ± 0.016 and 50.063 ± 7.901 mBqkg-1h-1, respectively. The annual effective dose of radionuclides in all sampling locations was found to be lower than UNSCEAR's recommended level of 0.07 mSvy-1 for soil in an outdoor environment. In the secondary study, gross α and gross β activities in soil and date palm pits samples were measured by a low background α/β counting system. Average values of gross α and gross β activities in soil and date palm pits samples were 5.761 ± 0.360 Bqkg-1, 38.219 ± 8.619 Bqkg-1 and 0.556 ± 0.142 Bqkg-1, 24.266 ± 1.711 Bqkg-1, respectively.

Effect of CJ-50001 (rG-CSF) on the Recovery of the Neutrophil Numbers in the Mice with Bone Marrow Transplantation BMT) (CJ-50001 (rG-CSF)의 골수이식모델 마우스에 대한 호중구수 회복 촉진효과)

  • 임동문;조효진;김종호;김달현;고형곤;김제학;김현수
    • Biomolecules & Therapeutics
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    • v.5 no.4
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    • pp.376-379
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    • 1997
  • The peripheral neutrophil recovery test was conducted to determine the efficacy of CJ-50001, a drug developed in Cheil Jedang R&D center as a recombinant granulocyte-colony stimulating factor (rG-CSF). Grasin was used as control drug. CJ-50001 and Gratin were subcutaneously administered to ${\gamma}$-ray irradiated mice for 21 days at a dose of 10$\mu$g/kg after bone marrow transplantation and the recovery of neutrophil number was examined on the days of 9, 13, 17, and 21 after the drug administration. It was observed that the peripheral neutrophil number of the vehicle control group was recovered to the normal level on the day of 13 after the transplantation whereas the group administered with CJ-50001 and Grasin respectively, showed the normal level of peripheral neutrophil number on 9th day after the bone marrow transplantation. The number of peripheral neutrophils reached the highest level on the 21 st day of drug administration, and was recovered to the normal level on the 4th day after ceasing of the drug administration (on the 25th day of the transplantation). Thus, it was presumed that CJ-50001 showed efficacy similar to Grasin on the peripheral neutrophil recovery after bone marrow transplantation.

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An Experimental Study on the Change of Bone Mineral Metabolism After Irradiation (방사선 조사후 골무기질 함량의 변화에 관한 실험적 연구)

  • Hong, Sung-Woon;Lim, Sang-Moo;Jang, Ja-June;Lee, Jhin-Oh;Kang, Tae-Woong
    • The Korean Journal of Nuclear Medicine
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    • v.24 no.2
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    • pp.307-316
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    • 1990
  • Irradiation is widely used for the treatment of malignant diseases, and possibly cause the osteoporosis. The densitometry and bone scintigraphy are valuable when used to monitor the patients longitudinally to access the progression of osteoporosis and risk of osteoradionecrosis. To evaluate the osteoporosis after irradiation of Cobalt-60 gamma ray on the lumbar spines of New Zealand white rabbits, bone densitometry by dual photon absorptiometry and bone scintigraphy were performed weekly. The decrease of bone density began at the first week after irradiation, and were in the nadir at 4-6th week. The osteoblastic activity measured by bone scintigraphy decreased in the first week, and was in the nadir at 4-6th week. The severity of these changes were related to the radiation dose. In conclusion, the osteoporosis before the presentation of the osteoradionecrosis can be diagnosed early with the dual photon absorptionmetry and bone scintigraphy.

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Effects of Plasticizer to Polyvinylchloride on Radio-resistance of Organic Stabilizer,Dielectric and Mechanical Characteristics under the Influence of Radiation (Polyvinylchloride에 있어 가소제의 첨가가 유기안정제의 내 방사성 및 유전, 기계적 특성에 미치는 영향)

  • 김봉흡;강도열;이재인
    • 전기의세계
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    • v.26 no.2
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    • pp.89-94
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    • 1977
  • In order to investigate the properties of radiation resistance together with dielectric, and mechanical relaxation behaviors of polyvinylcholoride exposed to several different doses under the .gamma.-ray of Co$^{60}$ source, several observations were carried out on the exposed specimens propared by mixing dibutyl-tin-dilaulate and dibutyl-tin-dimaleate as stabilizer with or without adding dioctyl-phthalate as plasticizer. Conclusions obtained from the study are as follows: The origin of the absorption band at 1,540-1,640$cm^{-1}$ / on I.R. spectrum seems to be RCOO- ion originated from ionization of the stabilizer, and this peak can be useful as a measure of radiation resistance on polyvinylchloride. Addition of increasing plasticizer to polyvinylchloride exhibits increasing radiation resistance and the reason for this result may be attributed to aromatic resonance absorption of radiation energy by diotylphthalate. On dose dependent dielectric characteristics, nonplastized specimen shows a peak at about 10 Mrad and that this peak disappears on the plastification of specimens. Those phenomena may be explainable in considering the statistical distribution of scissored chain molecular segments as well as the plastification process of plasticizer to polyvinylchloride chain molecules.

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Radiation Degradation Detection of LDPE Using Thermoluminescence Method (열발광 특성을 이용한 저밀도 폴리에틸렌의 방사선 열화 검출)

  • Lee, C.;Lee, K.W.;Park, J.N.;Lim, K.J.;Ryu, B.H.;Park, Y.G.;Kang, S.H.;Kim, K.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.43-46
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    • 2001
  • Polymers are widely used as insulating materials at various part of power industry. However, electrical properties of these polymers are easily degraded with their working environments, especially radiation areas. In this research, radiation degradation of low density polyethylene (LDPE) used as cable insulation was evaluated with thermoluminescence characteristics. LDPE was irradiated with gamma ray up to 1000 kGy at a dose rate of 5 kGy/hr in the presence of air at room temperature. Each of the irradiated samples were carried out thermoluminescence analysis as a function of temperature. Interrelationships between thermoluminescence and dielectric characteristics and volume resistivity are investigated as well. The results of thermoluminescence analysis showed that those would be significant factors for evaluation of radiation degradation.

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Isolation and Characterization of Ultra-Violet and Gamma-radiation Resistant Bacteria from Natural Habitats (자연 생태계로 부터 자외선 및 방사선 내성 박테리아의 분리 및 특성 연구)

  • 이영남;이인정
    • Korean Journal of Microbiology
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    • v.27 no.3
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    • pp.297-303
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    • 1989
  • Attempts to isolate the naturally occurring ultra-violet resistant bacteria from environmental sources were made. The isolates, designated No.29, 100, and 107, among numbers of bacterial isolates revealed a remarkable resistance to UV ray, whose degree of resistance in dose/response kinetics was comparable to that of an endospore-former, Bacillus subtilis. In a range of 100-300 $Jm^{-2}$/min of UV irradiation, the isolates exhibited 500-1000 fold resistance compated with E. coli. The isolated appeared to possiss cell-bound pigment of organge or crimson-red. The isolate 29 is spherical in pairs or tetrads, whereas the isolates 100 and 107 are rod. All are Gram-gositive bacteria and seemed to be non-endospore-bearer. A number of biochemical studies pursued on the isolates suggested that they are quite different to each other. Electron microscopic examination and the physiological characters of the isolate 29 suggested that this UV resistant spherical bacterium might be one species of Deinococcus, probably Deinococus radiophilus. Since there is no documents on UV resistant, Gram-positive, non-sporeformer bacillus so far, the isolates 100 and 107 might be turned out as new kinds of UV resistant bacteria occurring in nature by further investigation.

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