• Title/Summary/Keyword: fundamental solution.

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Codoped ZnO films by a co-spray deposition technique for photovoltaic applications

  • Zhou, Bin;Han, Xiaofei;Tao, Meng
    • Advances in Energy Research
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    • v.2 no.2
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    • pp.97-104
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    • 2014
  • A co-spray deposition technique has been developed to bypass a fundamental limitation in the conventional spray deposition technique, i.e., the deposition of metal oxides from incompatible precursors in the starting solution. With this technique, ZnO films codoped with F and Al have been successfully synthesized, in which F is incompatible with Al. Two starting solutions were prepared and co-sprayed through two separate spray heads. One solution contained only the F precursor, $NH_4F$. The second solution contained the Zn and Al precursors, $Zn(O_2CCH_3)_2$ and $AlCl_3$. The deposition was carried out at $500^{\circ}C$ on soda-lime glass in air. A minimum sheet resistance, $55.4{\Omega}/{\square}$, was obtained for Al and F codoped ZnO films after vacuum annealing at $400^{\circ}C$, which was lower than singly-doped ZnO with either Al or F. The transmittance for the codoped ZnO samples was above 90% in the visible range. This co-spray deposition technique provides a simple and cost-effective way to synthesize metal oxides from incompatible precursors with improved properties for photovoltaic applications.

A Study on the Direction for the Institutional Improvement of Financial Supply Chain Management Solution under Global e-Trade (글로벌 전자무역에서의 금융지원체인관리 솔루션의 운용현황과 개선방향 - Bolero를 중심으로 -)

  • Chae, Jin-Ik
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
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    • v.33
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    • pp.247-275
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    • 2007
  • This paper is to propose the Direction for the institutional improvement of Financial Supply Chain Management(FSCM) Solution which are currently coming into operation under Global e-Trading Platform. The Financial Supply Chain compromise the entire trade processes and information that manage a trader's cash, Accounts payable and receivable, Risk, working capital, and so on in international trade transaction. From a buyer's perspective, this involves the full procurement-to-payment process. For the seller, it is the order-to-cash cycle. Bolero provides the party concerned a e-trade platform which conformed to these fundamental pre-requisites to underpin fully electronic trade. But this FSCM solution have failed to provide the efficient platform to effectively manage the process of Global e-Trade because it does not correspond with e-Trade environment. Therefore, present FSCM system need the institutional improvement as follows: AA) Strengthening the role of the correspondent Bank under e-Trade System, BB) Extending the function of e-Trade intermediary institution, CC) The introduction of Trade Insurance System, etc. So, by streamlining and automating these processes on an open and flexible platform, The party concerned can optimize their trade transaction and maintain better relations with their business partners

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An Investigation for the Adsorption of Heavy Metal Ions by Polyamine Organic Adsorbent from the Aqueous Solution - The Influence of Molecular Weight and Degree of Deacetylation of Chitosan - (수용액 중에서 Polyamine계 유기응집제를 이용한 중금속 이온의 흡착 - 키토산의 분자량과 탈아세틸화도 -)

  • Park, Young-Mi;Jeon, Dong-Won
    • Fashion & Textile Research Journal
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    • v.8 no.4
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    • pp.458-464
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    • 2006
  • The adsorption ability of heavy metal ions from the aqueous solution by chitosan, which it is well known natural biopolymer, has been investigated. The fundamental study in this research is focusing on the physicochemical adsorption utilizing the chitosan as a organic chelating adsorbent, adsorb especially heavy metal ions from the waste liquid solution. The adsorption ability of the chitosan between metal ions, having different characteristics with Mw of 188,600, 297,200, and 504,200 g/mol and degree of deacetylation (DD) of 86.92% and 100% were investigated targeting on the $Ni^{2+}$, $Co^{2+}$, $Zn^{2+}$, and $Pb^{2+}$ ions, respectively. The uptake of heavy metal ions with chitosan was performed by atomic absorption flame emission spectrophotometer (AAS) as conducted residual metal ions. It was found that chitosan has an strong adsorption capacity for some metals under certain conditions. Chitosan, which have 100% degree of deacetylation showed high adsorption recovery ratio and have an affinity for all kinds of heavy metals. In contrast, the molecular weight of chitosan was not completely affected on metal ion adsorption.

Analysis of Multi-Layered Structural Systems Using Nonlinear Finite Elements-Boundary Elements (반무한 다중 구조계의 비선형 유한요소 - 경계요소 해석)

  • 김문겸;장정범;이상도;황학주
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1992.04a
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    • pp.58-64
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    • 1992
  • It is usual that underground structures are constructed within multi-layered medium. In this paper, an efficient numerical model ling of multi-layered structural systems is studied using coupled analysis of finite elements and boundary elements. The finite elements are applied to the area in which the material nonlinearity is dominated, and the boundary elements are applied to the far field area where the nonlinearity is relatively weak. In the boundary element model 1 ins of the multi-layered medium, fundamental solutions are restricted. Thus, methods which can utilize existing Kelvin and Melan solution are sought for the interior multi-layered domain problem and semi infinite domain problem. Interior domain problem which has piecewise homogeneous layers is analyzed using boundary elements with Kelvin solution; by discretizing each homogeneous subregion and applying compatibility and equilibrium conditions between interfaces. Semi-infinite domain problem is analyzed using boundary elements with Melan solution, by superposing unit stiffness matrices which are obtained for each layer by enemy method. Each methodology is verified by comparing its results which the results from the finite element analysis and it is concluded that coupled analysis using boundary elements and finite elements can be reasonable and efficient if the superposition technique is applied for the multi-layered semi-infinite domain problems.

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The Effect of Learning Cycle Model in Solution Concept on the Cognitive Development for Primary Student (용액 개념의 순환학습이 초등학생의 인지수준발달에 미치는 영향)

  • 최영주;김세경;고영신
    • Journal of Korean Elementary Science Education
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    • v.23 no.4
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    • pp.273-278
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    • 2004
  • According to Piaget, children aged 11 are in the middle of concrete operation period and formal operation period. So, it is necessary to adopt the Learning Cycle Model (LCM) which helps students improve their cognitive development. After determining the test for the Science Concept of Matter (SCOM), the experimental group showed higher average than the comparative group in the post-test. In the sound understanding, the experimental group showed higher ratio than the comparative group. And in the ratio of imperfect, wrong understanding and no response, the experimental group was lower than the comparative group. On the questions that were needed the complicated inquiry, many students of both groups still couldn't find the fundamental cause. In forming the scientific conceptualization, there was a meaningful difference (p < .001) after post-test Analysis of Covariance (ANCOVA) with pre-test result. After determining the test for the Test Inquiry Science Process (TISP), the experimental group showed higher average than the comparative group in the post-test. In the category of basic inquiry process which is needed in concrete operation, there was a meaningful difference (p < .05). In the category of unified inquiry process which is needed in formal operation, they showed no meaningful difference (p > .05). Therefore, applying the LCM to the chapter of 'Solution and Dissolving' is more effective on improving the scientific conceptualization and on helping the concrete operation abilities than the teacher centered learning.

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현장 규모 biobarrier의 수리학적 특성과 기초 설계

  • 최영화;오재일;왕수균;배범한
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.426-430
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    • 2003
  • Subsurface biobarrier technology has potential applications to contain contaminated groundwater and/or to degrade toxic pollutants in groundwater. Effective biobarrier formation is need to assess of hydrogeologic characteristics and to conduct practical operation strategies and design based on this prior to design biobarrier. Thus, in this study, we examined hydrogeologic characteristics in biobarrier construction site. Hydraulic conductivities which calculated from slug test data have shown difference with each well as 1.20$\times$10$^{-3}$ -6.00$\times$10$^{-5}$ cm/sec. Tracer test is a method in which concentration of tracer solution during withdrawal in each well by vacuum extraction system is measured with time. Tracer solution was continuously injected by constant head tank. Measured tracer concentration versus time data were fitted to analytical solution of convection dispersion equation (CDE). The fitting data of CDE to the measured data at each extraction well yielded were 0.61cm/min(pore velocity), 5.38$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.47 1/min and 1.75cm/min(pore velocity), 36.34$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.93 1/min. As a result, we acquired fundamental parameters which need to design biobarrier and operation strategies.

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Fundamental Investigation of Functional Property of Concrete Mixed with Functional Materials

  • Lee, Jong-Chan;Lee, Moon-Hwan;Lee, Sae-Hyun;Park, Young-Sin;Park, Jae-Myung
    • International Journal of Concrete Structures and Materials
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    • v.18 no.3E
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    • pp.165-171
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    • 2006
  • Environment-friendly materials are increasingly used as building construction materials nowadays, and the market share of those is growing. Accordingly, the research and developments in terms of environmental value are progressing steadily now. The main characteristics of environmental products are far-infrared radiation, negative-ion emission, electromagnetic wave shielding, and antimicrobial property. These products are often used in mortar and as spray on the finishing material. Nevertheless, there are hardly any research on the functional properties of concrete, the main material in construction field. Thus, we evaluated such basic properties of concrete as slump, compressive strength and air content while using such functional materials as sericite, wood-pattern sandstone, carbon black and nano-metric silver solution to focus on their functional properties like far-infrared radiation, negative ion emission, electro magnetic wave shielding, and antimicrobial activity in this research. The results indicated that the most useful material in the functional materials was carbon black. Sericite and nano-metric silver solution had a little effect on the functional property. Moreover, although wood-pattern sandstone had very high functional property, it exhibited too low compressive strength to be applied, to concrete as a factory product. Antimicrobial property of nano-metric silver solution in the concrete was not clear demonstrated, but if these specimens were to be aged in $CO_2$ gas for a long time, it might be apparent.

A Study on the Distribution of Injected Urea into the Exhaust Pipe in a SCR System (선택적 환원촉매(SCR)장치에서 배기관내에 분사된 환원제 분포에 관한 연구)

  • Choi, J.H.;Lee, Y.C.;LEE, S.W.;Cho, Y.S.;LEE, S.H.;Oh, S.K.;Dong, Y.H.
    • Journal of Power System Engineering
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    • v.14 no.1
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    • pp.16-21
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    • 2010
  • This research focused on the spray and distribution characteristics of urea solution by applying flow visualization techniques and did durability and driver test on injectors as well. The spray characteristics of urea solution was observed by CCD camera. Also, the distribution characteristics of urea solution was evaluated quantitatively as well by using 3D laser scanner equipment. It was considered that it was reasonable to use the injector for gasoline engine in order to inject the urea. The best distribution chart result was observed near 45cm distance difference between catalyst and urea spray injector. As a result of trapped urea distribution chart analysis, optimal pressure and volumetric flow rates of air and urea were derived in order to improve the distribution of Urea. This information may contribute to provide fundamental data in the future.

Analytical solutions for crack initiation on floor-strata interface during mining

  • Zhao, Chongbin
    • Geomechanics and Engineering
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    • v.8 no.2
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    • pp.237-255
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    • 2015
  • From the related engineering principles, analytical solutions for horizontal crack initiation and propagation on a coal panel floor-underlying strata interface due to coal panel excavation are derived in this paper. Two important concepts, namely the critical panel width of horizontal crack initiation on the panel floor-underlying strata interface and the critical panel width of vertical fracture (crack) initiation in the panel floor, have been presented. The resulting analytical solution indicates that: (1) the first criterion can be used to express the condition under which horizontal plane cracks (on the panel floor-underlying strata interface or in the panel floor because of delamination) due to the mining induced vertical stress will initiate and propagate; (2) the second criterion can be used to express the condition under which vertical plane cracks (in the panel floor) due to the mining induced horizontal stress will initiate and propagate; (3) this orthogonal set of horizontal and vertical plane cracks, once formed, will provide the necessary weak network for the flow of gas to inrush into the panel. Two characteristic equations are given to quantitatively estimate both the critical panel width of vertical fracture initiation in the panel floor and the critical panel width of horizontal crack initiation on the interface between the panel floor and its underlying strata. The significance of this study is to provide not only some theoretical bases for understanding the fundamental mechanism of a longwall floor gas inrush problem but also a benchmark solution for verifying any numerical methods that are used to deal with this kind of gas inrush problem.

Dynamic analysis for anti-symmetric cross-ply and angle-ply laminates for simply supported thick hybrid rectangular plates

  • Benhenni, Mohamed Amine;Daouadji, Tahar Hassaine;Abbes, Boussad;Adim, Belkacem;Li, Yuming;Abbes, Fazilay
    • Advances in materials Research
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    • v.7 no.2
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    • pp.119-136
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    • 2018
  • In this paper, static and vibration analysis for anti-symmetric cross-ply and angle- ply carbon/glass hybrid laminates rectangular composite plate are presented. In this analysis, the equations of motion for simply supported thick laminated hybrid rectangular plates are derived and obtained through the use of Hamilton's principle. The closed-form solutions of anti-symmetric cross-ply and angle- ply laminates are obtained using Navier solution. The effects of side-to-thickness ratio, aspect ratio, and lamination schemes on the fundamental frequencies loads are investigated. The study concludes that shear deformation laminate theories accurately predict the behavior of composite laminates, whereas the classical laminate theory over predicts natural frequencies. The excellent accuracy of the present analytical solution is confirmed by making some comparisons of the present results with those available in the literature. It can be concluded that the proposed theory is accurate and simple in solving the free vibration behaviors of anti-symmetric cross-ply and angle- ply hybrid laminated composite plates.