• 제목/요약/키워드: functional properties

검색결과 3,700건 처리시간 0.056초

ASYMPTOTIC PROPERTIES OF THE CONDITIONAL HAZARD FUNCTION ESTIMATE BY THE LOCAL LINEAR METHOD FOR FUNCTIONAL ERGODIC DATA

  • MOHAMMED BASSOUDI;ABDERRAHMANE BELGUERNA;HAMZA DAOUDI;ZEYNEB LAALA
    • Journal of applied mathematics & informatics
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    • 제41권6호
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    • pp.1341-1364
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    • 2023
  • This article introduces a method for estimating the conditional hazard function of a real-valued response variable based on a functional variable. The method uses local linear estimation of the conditional density and cumulative distribution function and is applied to a functional stationary ergodic process where the explanatory variable is in a semi-metric space and the response is a scalar value. We also examine the uniform almost complete convergence of this estimation technique.

Magnetic Properties and Electronic Structure of $Pt_3Ni$ (001), (110) and (111) Surfaces: Density Functional Study

  • Kumar, Sharma Bharat;Kwon, O-Ryong;Odkhuu, Dorj;Hong, Soon-Cheol
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2011년도 임시총회 및 하계학술연구발표회
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    • pp.129-129
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    • 2011
  • The limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of properties and electronic structures of seven layered $Pt_3Ni$ (001), (110), and (111) surfaces. The first principle method based on density functional theory (DFT) is carried out. It is found that the bulk $Pt_3Ni$ has a ferromagnetic ground state with the ordered fcc type L12 structure, which is in good agreement with other results. Non magnetic Pt has the induced magnetic moment due to the strong hybridization between 3d Ni and 5d Pt. The magnetic moment of Pt and Ni enhanced on the surface of each due to surface effect however the magnetic moment of surface Pt in the Pt-segregated Pt3Ni (111) decreased and the magnetic moment of Ni in Ni rich subsurface increased significantly. The calculated d band centers of Pt explain the possibilities for oxygen absorption and play the important roles in altering the catalytic properties. The spin polarized densities of states are presented in order to understand physical properties of Pt in different surfaces in detail.

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밀도함수 이론법을 이용한 마그네슘 합금의 재료특성 예측에 관한 연구 (A Study on the Prediction of the Material Properties of Magnesium Alloys Using Density Functional Theory Method)

  • 백민숙;원대희;김병일
    • 한국재료학회지
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    • 제17권12호
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    • pp.637-641
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    • 2007
  • The total energy and strength of Mg alloy doped with Al, Ca and Zn, were calculated using the density functional theory. The calculations was performed by two programs; the discrete variational $X{\alpha}\;(DV-X{\alpha})$ method, which is a sort of molecular orbital full potential method; Vienna Ab-initio Simulation Package (VASP), which is a sort of pseudo potential method. The fundamental mixed orbital structure in each energy level near the Fermi level was investigated with simple model using $DV-X{\alpha}$. The optimized crystal structures calculated by VASP were compared to the measured structure. The density of state and the energy levels of dopant elements was discussed in association with properties. When the lattice parameter obtained from this study was compared, it was slightly different from the theoretical value but it was similar to Mk, and we obtained the reliability of data. A parameter Mk obtained by the $DV-X{\alpha}$ method was proportional to electronegativity and inversely proportional to ionic radii. We can predict the mechanical properties because $\Delta{\overline{Mk}}$is proportional to hardness.

재활용 고밀도 폴리에틸렌의 가교에 의한 물성 향상 연구 (Enhancement of Physical Properties in Partially Crosslinked Waste High Density Polyethylene)

  • 이종록;이동근;홍순만;강호종
    • 폴리머
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    • 제31권1호
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    • pp.25-30
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    • 2007
  • 재활용 고밀도 폴리에틸렌(HDPE)에 Perbutyl peroxide(PBP)를 첨가하여 반응 용융가공에 의한 가교 특성 및 물성 변화를 살펴보았다. 그 결과, 재활용 HDPE에 포함되어 있는 다양한 이물질의 성분을 EDS를 이용하여 분석하였으며 수지의 재활용 시 포함된 유, 무기물이 가교 반응에 영향을 미침을 확인하였다. 또한 물성 측정을 통해 재활용 가교 HDPE가 신재 HDPE와 비교하여 낮은 밀도, 용융엔탈피 그리고 높은 용융점도를 가짐으로 보아 상대적으로 신재 가교 HDPE에 비하여 가교가 더 잘 일어남을 알 수 있으며 이러한 재활용 HDPE의 가교 특성은 가교에 의한 재환용 HDPE의 기계적 물성 증가에 기여함을 확인하였다.

Rheological anomalies of the poly(ethylene 2, 6-naphthalate) and poly(ethylene terephthalate) blends depending on the compositions

  • Lee, Hyang-Mok;Suh, Duck-Jong;Kil, Seung-Bum;Park, O-Ok;Yoon, Kwan-Han
    • Korea-Australia Rheology Journal
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    • 제11권3호
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    • pp.219-223
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    • 1999
  • The effects of the transreactions on the rheological properties have been found in the poly(ethylene 2, 6-naphthalate) (PEN) and poly (ethylene terephthalate) (PET) blends. The rheological properties were very much dependent on the blend compositions, which, in turn, were related to extent of the reactions. In particular, a blend with 50/50 wt% composition exhibits an unusual and remarkable decrease in complex viscosity and it may be related to the randomness of the copolymer structure through transreactions. It has been identified by investigating the extent of transreactions and block length of the copolymer from the (ethylene 2, 6-naphthalate) (EN) and (ethylene terephthalate) (ET) units from $^1{H}$ n.m.r. spectra.

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천연색소를 이용한 건축내장용 색한지 제조(제2보) - Super Eight Color 창호지의 기능성 연구- (Manufacture of Colores Hanji for Interior Materials from Natural Pigments(Part 2) - Study on Functional Properties of Super Eight Colors Changhoji -)

  • 이상현;신유수;최태호
    • 펄프종이기술
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    • 제44권5호
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    • pp.46-53
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    • 2012
  • The purpose of this study was to investigate the functional properties of Changhoji with natural dyeing. This research would provide a basic information for interior material Changhoji. To estimate functional properties of super eight colors Changhoji, water staining, lightfastness, and floodlight color test were executed. In term of the water staining test, blue color showed the clear and other colors showed the little spot. As a result of measuring the lightfastness, Magenta color dyed with sappanwood showed the worst. But blue color dyed with indigo and Turquoise color dyed with indigo and Pagoda tree flower showed the highest. As a result of floodlight color test was no difference between sample color and floodlight color.