• Title/Summary/Keyword: functional composites

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Synthesis and Properties of the New Photorefractive Material (새로운 광굴절재료의 제작 및 특성)

  • Min, Wan-Ki;Kim, Nam-Ou;Sssabe, Hiroyuki
    • Proceedings of the KIEE Conference
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    • 2002.06a
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    • pp.120-124
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    • 2002
  • Considerable progress has been made in organic photorefractive materials, since the first observation of photorefractive phenomena from organic materials. Within recent years, a large number of organic photorefractive materials, especially amorphous materials. have been developed based on polymeric composites, fully functional polymers and the multifunctional chromophore approach. Among these organic photorefractive materials, some of them containing carbazole components as a charge transporting function have been demonstrated to exhibit high performance photorefractive effects. The carbazole building blocks with charge transporting functionality or multifunctions play a very important role in photorefraction and have been widely used in the molecular design approach to new organic photo- refractive materials.

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Preparation of $TiB_2$ Dispersed Cu Alloy by Spark Plasma Sintering

  • Kim, Kyong-Ju;Lee, Gil-Geun;Park, Ik-Min
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.523-524
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    • 2006
  • The $TiB_2$ dispersion strengthened copper alloy was attracted as thermal and electrical functional material for the high mechanical strength, high thermal stability and good conductivity of $TiB_2$. In the present study, the focus is on the synthesis of $TiB_2$ dispersed copper alloy by spark plasma sintering process using copper oxide and titanium diboride as raw materials. The mechanical, thermal and electrical properties of sintered bodies were discussed with the sintering parameters, and developed microstructure and phase of sintered bodies.

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Boron Nit ride Nanotube Synthesis and Applications (보론 나이트라이드 나노튜브 합성 및 응용기술)

  • Cho, Hyun Jin;Kim, Jun Hee;Kim, Myung Jong
    • Vacuum Magazine
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    • v.3 no.3
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    • pp.19-23
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    • 2016
  • BNNTs (Boron nitride nanotubes) is an analogue of CNTs (Carbon Nanotubes) in terms of lattice structure. In BNNTs, a boron atom forms sp2 hybridized bonding with three nitrogen atoms, and so does a nitrogen with three boron atoms in the honeycomb structure. Its innovative properties, such as high thermal conductivity, neutron shielding capability, superb oxidation resistance at $900^{\circ}C$, excellent chemical resistance, and superior mechanical properties are advantageous for a wide range of applications, especially for electric device packages, neutron shielding, protective coating materials, and functional composites. In this paper, boron nitride nanotube synthesis, properties and application are reviewed.

Improvement of Absorption Performances of Superabsorbent Hydrogel Nanocomposites Using Clay Mineral

  • Kim, Dong Hyun
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.201-208
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    • 2019
  • Superabsorbent hydrogel (SAH) is a lightly crosslinked hydrophilic functional polymer material comprising a flexible chain structure, which can absorb and retain high amounts of water or aqueous fluids even under high pressure. Therefore, it is important to improve their characteristics such as absorption performance, residual monomer content, and water permeability. SAH nanocomposites were prepared using clay mineral as an inorganic filler and the influence of post-treatment processes such as quenching and aging process on their properties was studied. In addition, surface-crosslinking process was applied to improve the absorption performance associated with mechanical properties and water permeability. The structure of the SAH was characterized using attenuated total reflectance Fourier transform infrared spectroscopy, X-ray diffraction analysis, and scanning electron microscopy.

Predicting Thermo-mechanical Characteristics from the 2nd Phase Fraction of Al-AlN Composites for LED Heat Sinks with FEM (유한요소해석을 이용한 방열용 Al-AlN 복합재의 제2상 분율에 따른 열-기계적 특성예측)

  • Yoon, Juil
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.5
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    • pp.137-142
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    • 2018
  • With the development of the electronic-materials industry, multi-functional metal-composite materials with high thermal conductivity and low thermal expansion must be developed for high reliability and high life expectancy. This paper is a preliminary study on the manufacturing technology of gas reaction control composite material, focusing on the prediction of the equivalent thermal properties of Al-AlN composite materials. Numerical equivalent property values are obtained by using finite element analysis and compared with theoretical formulas. Al-AlN composite materials should become the optimal composite material when the proportion of the reinforcing phase is less than 0.5.

Chemically Bonded Thermally Expandable Microsphere-silica Composite Aerogel with Thermal Insulation Property for Industrial Use

  • Lee, Kyu-Yeon;Phadtare, Varsha D.;Choi, Haryeong;Moon, Seung Hwan;Kim, Jong Il;Bae, Young Kwang;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.2
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    • pp.23-29
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    • 2019
  • Thermally expandable microsphere and aerogel composite was prepared by chemical compositization. Microsphere can produce synergies with aerogel, especially an enhancement of mechanical property. Through condensation between sulfonated microsphere and hydrolyzed silica sol, chemically-connected composite aerogel could be prepared. The presence of hydroxyl group on the sulfonated microsphere was observed, which was the prime functional group of reaction with hydrolyzed silica sol. Silica aerogel-coated microsphere was confirmed through microstructure analysis. The presence of silicon-carbon absorption band and peaks from composite aerogel was observed, which proved the chemical bonding between them. A relatively low thermal conductivity value of $0.063W/m{\cdot}K$ was obtained.

Molecular interactions between pre-formed metal nanoparticles and graphene families

  • Low, Serena;Shon, Young-Seok
    • Advances in nano research
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    • v.6 no.4
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    • pp.357-375
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    • 2018
  • Two dimensional (2D) atomic layered nanomaterials exhibit some of the most striking phenomena in modern materials research and hold promise for a wide range of applications including energy and biomedical technologies. Graphene has received much attention for having extremely high surface area to mass ratio and excellent electric conductivity. Graphene has also been shown to maximize the activity of surface-assembled metal nanoparticle catalysts due to its unique characteristics of enhancing mass transport of reactants to catalysts. This paper specifically investigates the strategy of pre-formed nanoparticle self-assembly used for the formation of various metal nanoparticles supported on graphene families such as graphene, graphene oxide, and reduced graphene oxide and aims at understanding the interactions between ligand-capped metal nanoparticles and 2D nanomaterials. By varying the functional groups on the ligands between alkyl, aromatic, amine, and alcohol groups, different interactions such as van der Waals, ${\pi}-{\pi}$ stacking, dipole-dipole, and hydrogen bonding are formed as the 2D hybrids produced.

Production of NH2-HNT Using Organic Solvent Reducing Dry Mechanical Device with Different Conditions and with Scale Up Settings (유기용매 사용 감소를 위한 건식 기계 장치를 이용한 NH2-HNT 제조의 조건 변화와 스케일업)

  • Moon il Kim
    • Journal of the Korean Society of Industry Convergence
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    • v.27 no.2_2
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    • pp.357-361
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    • 2024
  • Halloysite nanotube (HNT) has a nanotube structure with the chemical formula of Al2Si2O5(OH)4·nH2O and is a natural sediment of aluminosilicate. HNT has been used as additive to improve the mechanical properties of epoxy composites with exchange of amine group as a terminal functional group using huge amount of organic solvents. In order to save time and simplify complicated procedures, a dry coating machine was designed and used for amine group exchange in previous research. For better applications, it was conducted with different parameters and with scale up settings. Best condition was found to reduce usage of solvent, time and man power.

Properties of Acrylic Pressure Sensitive Adhesive Performance and Evaluation Using Combinatorial Methods (조합기법을 활용한 아크릴 점착제의 점착물성 평가)

  • Park, Ji Won;Lim, Dong-Hyuk;Kim, Hyun Joong;Kim, Kyoung Mahn;Kim, Hyung Il;Ryu, Jong Min
    • Journal of Adhesion and Interface
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    • v.10 no.3
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    • pp.127-133
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    • 2009
  • Acrylic pressure sensitive adhesives (PSAs) are used in various field of high-technology industries such as semiconductor, display, mobile, automobile, and so on. Because of they have high durabilities and can be easily introduced functional groups in their molecular structures. PSA perfomances has an effect on their applications in industry process operation, reliability of final products. In this study, PSA performances as a function of fim thickness which is one of the impact factors effects on PSA performances will be investigated using combinatorial methods. Acrylic PSAs are synthesized using 2-ethylhexyl acrylate and acrylic acid. Thickness-gradient of acrylic PSA sample is made by a micro applicator. We compare general coating method with thickness-gradient coating method and evaluate the reappearance of combinatorial methods compared with existing coating method. Thickness-gradient of acrylic PSA sample shows rough and broad data tendency.

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Chemical and Thermal Characterizations of Electron Beam Irradiated Jute Fibers (전자빔 조사된 황마섬유의 화학적 및 열적 특성분석)

  • Ji, Sang Gyu;Cho, Donghwan;Lee, Byung Cheol
    • Journal of Adhesion and Interface
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    • v.11 no.4
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    • pp.162-167
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    • 2010
  • In the present work, the effect of electron beam irradiation on the chemical and thermal characteristics of cellulose-based jute fibers was explored by means of chemical analysis, electron spin resonance analysis, ATR-FTIR spectroscopy, thermogravimetric analysis and thermomechanical analysis. Jute fiber bundles were uniformly irradiated in the range of 2~100 kGy by a continuous method using a conveyor cartin an electron beam tunnel. Electron beam treatment, which is a physical approach to change the surfaces, more or less changed the chemical composition of jute fibers. It was also found that the radicals on the jute fibers can be increasingly formed with increasing electron beam intensity. However, the electron beam irradiation did not change significantly the chemical functional groups existing on the jute fiber surfaces. The electron beam irradiation influenced the thermal stability and thermal shrinkage/expansion behavior and the behavior depended on the electron beam intensity.