• Journal of Ocean Engineering and Technology
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• v.35 no.6
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• pp.393-402
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• 2021

As greenhouse gas emissions from maritime transport are increasing, the International Maritime Organization is continuously working to strengthen emission regulations. Liquefied natural gas (LNG) fuel is less advantageous as a point of CO₂ reduction due to the methane leakage that occurs during the bunkering and operation of marine engines. In this study, greenhouse gas emissions from an LNG-fueled ship were analyzed from the perspective of the life cycle. The amount ofmethane emission during the bunkering and operation procedures with various boil-off gas (BOG) treatment methods and gas engine specifications was analyzed by dynamic simulation. The results were also compared with those of other liquid fuel engines. As a result, small LNG-fueled ships without a BOG treatment facility emitted 32% more greenhouse gas than ships utilizing marine gas oil or heavy fuel oil. To achieve a greenhouse gas reduction via a BOG treatment method, a gas combustion unit or re-liquefaction system must be mounted, which results in a greenhouse gas reduction effect of about 25% and 30%. As a result of comparing the amount of greenhouse gas generated according to the BOG treatment method used with each tank size from the perspective of the operating cycle with the amounts from using existing marine fuels, the BOG treatment method showed superior effects of greenhouse gas reduction.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.3
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• pp.216-223
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• 2008

Reburning is a useful technology in reducing nitric oxide through injection of a secondary hydrocarbon fuel. In this paper, an experimental study has been conducted to evaluate the effect of fuel lean reburning on $NO_X/CO$ reduction in LPG flame. Experiments were performed in flames stabilized by a co-flow swirl burner, which was mounted at the bottom of the furnace. Tests were conducted using LPG gas as the reburn fuel as well as the main fuel. The effects of reburn fuel fraction and injection location of the reburn fuel were studied when the fuel lean reburning system was applied. The paper reports data on flue gas emissions and temperature distribution in the furnace for a wide range of experimental conditions. At steady state, temperature distribution and emission formation in the furnace have been measured and compared. This paper makes clear that in order to decrease both NOx and CO concentrations in the exhaust when the fuel lean reburning system was adapted, it is important that the control of some factors such as initial equivalence ratio, reburn fuel fraction and temperature of reburn fuel injection region. Also it shows the fuel lean reburning is also effective method to reduce NOx as much as reburning.

• Journal of Electrochemical Science and Technology
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• v.15 no.1
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• pp.96-110
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• 2024

Polymer electrolyte membrane fuel cells (PEMFCs) are green energy conversion devices, for which commercial markets have been established, owing to their application in fuel cell vehicles (FCVs). Development of cathode electrocatalysts, replacing commercial Pt/C, plays a crucial role in factors such as cost reduction, high performance, and durability in FCVs. PtNi octahedral catalysts are promising for oxygen reduction reactions owing to their significantly higher mass activity (10-15 times) than that of Pt/C; however, their application in membrane electrode assemblies (MEAs) is challenged by their low stability. To overcome this durability issue, various approaches, such as third-metal doping, composition control, halide treatment, formation of a Pt layer, annealing treatment, and size control, have been explored and have shown promising improvements in stability in rotating disk electrode (RDE) testing. In this review, we aimed to compare the features of each strategy in terms of enhancing stability by introducing a stability improvement factor for a direct and reasonable comparison. The limitations of each strategy for enhancing stability of PtNi octahedral are also described. This review can serve as a valuable guide for the development of strategies to enhance the durability of octahedral PtNi.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.5
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• pp.450-457
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• 2018

To design the practical core-shell electrocatalysts, combination of core and shell materials is important to meet catalytic activity and durability target. In general, Pd is considered as a good core material due to its best activity caused by strain/ligand effect. Preparing Pd nanoparticles can be a starting point in fabricating core-shell type electrocatalysts, much simplified Pd preparing process is suggested by using carbon monoxide (CO) as a reducing agent and/or capping agent. The solvent composition and reaction temperature can control to nanosheet, tetrahedron, and sphere without using additional stabilizer. Among them, Pd nanosheet which has mainly (111) plane showed about 3 times higher electrocatalytic activity for oxygen reduction reaction (ORR) to the spherical Pd nanoparticles. The enhanced ORR activity of Pd nanosheets can be attributed to the exposure of Pd (111) surface and the high electrochemical surface area. Therefore, we demonstrated that the shape of Pd nanomaterials is easily controlled via a facile reduction method using CO, and (111) plane-oriented Pd nanosheets can be a promising ORR catalysts and core material for polymer electrolyte fuel cells (PEFCs).

• Tribology and Lubricants
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• v.26 no.5
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• pp.291-296
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• 2010

The purpose of this paper is to study the fuel economy improvement experimentally when the viscosity of engine oil is lowered. The emissions are measured for CVS-75 mode with SAE viscosity grades. The test results indicate that a close correlation has been found between the engine oil viscosity and the fuel economy. The lowering of engine oil viscosity causes the reduction of friction loss which has a very close relation with the fuel economy. These results as the lowering of engine oil viscosity will be a important factor for improvement of the fuel economy and reduction of the $CO_2$ emission.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.4
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• pp.33-42
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• 2002

Recently, our world is faced with very serious and hard problems related to the air pollution due to the exhaust emissions of the diesel engine. In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated fur direct injection diesel engine. It was tested to estimate change of engine performance and exhaust emission characteristics for the commercial diesel fuel and oxygenate blended fuel which has three kinds of mixed ratio. And, it was tried to analyze not only total hydrocarbon but individual hydrocarbon components from Cl to C6 in exhaust gas using gas chromatography to seek the reason far remarkable reduction of smoke emission. This study was carried out by comparing the chromatogram with diesel fuel and diesel feel blended DGM(diethylene glycol dimethyl ether) 5%. The results of this study show that individual hydrocarbon(C1∼C6) as well as total hydrocarbon of oxygenated fuel is reduced remarkably than that of diesel fuel.

• Journal of Power System Engineering
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• v.19 no.3
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• pp.22-28
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• 2015

A compression ignition type of diesel engine makes fuel efficiency better and $CO_2$ in the exhaust gas lower. Also it is suitable to apply alternative fuels(blended fuel) to the engine. The objective of this study is the emissions reduction of diesel engine with EF(Emulsified fuel). The emulsified fuel consists of diesel and peroxide($H_2O_2$) and Soot reduction without worsening of NOx emissions can be achieved by using thermal decomposition of the peroxide, i.e. the chemical effect of the OH radical in actual engine. For manufacturing emulsified fuel, a surfactant which is comprised of span 80 and tween 80 mixed as 9:1, was mixed with a fixed with 3% of the total volume in the emulsion fuel. In addition, considering the mixing ratio of the surfactant, the mixing ratio of $H_2O_2$ in the emulsified fuel was set as EF0, EF2, EF12, EF22, EF32, and EF42, respectively. Consequently, this study aims to obtain the optimization of fuel design(mixing) for the emulsified fuel applying to the diesel engine.

• Applied Chemistry for Engineering
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• v.29 no.5
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• pp.489-496
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• 2018

Fuel cells are seen as eco-friendly energy resources that convert chemical energy into electrical energy. However, proton exchange membrane fuel cells (PEMFCs) have problems such as the use of expensive platinum catalysts for the reduction of conductivity under high temperature humidification conditions. Thus, an anion exchange membrane fuel cell (AEMFC) is attracting a great attention. Anion exchange fuel cells use non - Pt catalysts and have the advantage of better efficiency because of the lower activation energy of the oxygen reduction reaction. However, there are various problems to be solved including problems such as the electrode damage and reduction of ion conductivity by being exposed to the carbon dioxide. Therefore, this mini review proposes various solutions for different problems of anion exchange fuel cells through a wide range of research papers.

• Journal of Mechanical Science and Technology
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• v.18 no.12
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• pp.2303-2309
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• 2004

Flue gas recirculation (FGR) is a method widely adopted to control NOx in combustion system. The recirculated flue gas decreases flame temperature and reaction rate, resulting in the decrease in thermal NO production. Recently, it has been demonstrated that the recirculated flue gas in fuel stream, that is, the fuel induced recirculation (FIR), could enhance a much improved reduction in NOx per unit mass of recirculated gas, as compared to the conventional FGR in air. In the present study, the effect of FGR/FIR methods on NOx reduction in turbulent swirl flames by using N$_2$ and CO$_2$ as diluent gases to simulate flue gases. Results show that CO$_2$ dilution is more effective in NO reduction because of large temperature drop due to the larger specific heat of CO$_2$ compared to N$_2$ and FIR is more effective to reduce NO emission than FGR when the same recirculation ratio of dilution gas is used.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.1967-1972
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• 2008

Reburning is an efficient combustion technology to reduce nitrogen oxide by injecting hydro-carbon fuel to the downstream of the main combustion. In this paper LPG has been used not only as main fuel but also as reburn fuel and air was used as an oxidizer with 15kW swirl burner. Experimental studies have been done to evaluate effect of reburning for NOx reduction. Also to examine the effect of the amount of burnout air for complete combustion by reburn fuel on NOx reduction, test was conducted by reducing the amount of burnout air. Computational fluid dynamic (CFD) simulation was performed using the commercial CFD code FLUENT 6.3 to simulate experimental results and investigate the thermo-chemical characteristics. An evaluation of reaction models for swirl burner has been carried out for propane-air with two step finite-rate eddy-dissipation model in FLUENT.