• Journal of ILASS-Korea
• /
• v.7 no.1
• /
• pp.7-13
• /
• 2002

This paper is study on simultaneous reduction of NOx and soot for direct injection diesel engine using high and low cetane fuels. The stratified injection system was applied for diesel engine to use high and low cetane fuel. In this study, diesel fuel was used as high cetane fuels, methanol was used as low cetane fuels. Some parts of the injection system, ie. Nozzle holder. delivery vale, was remodeled to inject dual fuel sequentially from one injector. The leak injection quantity ratio of dual fuel was certificated by volumetric ratio at injection quantity experiment. According as concentration of low cetane fuel was varied, combustion experiment was performed using Toroidal and Complex chamber. Also, exhaust gas and fuel consumption were measured at the same time. Simultaneous reduction of NOx and soot was achieved at complex chamber regardless of concentration of low cetane fuel. However, according as concentration of low cetane fuel was increased, THC and CO was increased.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.17 no.6
• /
• pp.1556-1571
• /
• 1993

Nitrogen oxides ($NO_x$) are air pollutants which are generated from the combustion of fossil fuels. Stage combustion is an effective method to reduce $NO_x$ emissions. The effects of $NO_x$ reduction by stage combustion in a pilot scale combustor(6.6kW) have been investigated using propane gas flames laden with NH$_{3}$ as Fuel-N. The results in this study are follows; (1) $NO_x$ emissions are dependent on the reducing environment of fuel-rich zone regardless of total air ratio. The maximum $NO_x$ reduction is at the stoichiometric ratio of 0.8 to 0.9 in the reducing zone. (2) $NO_x$ reduction is maximum when burnout air is injected at the point where the oxygen in reducing zone is almost consumed. (3) $NO_x$ reduction is dependent upon the temperature of reducing zone with best effect above 950.deg. C in the reducing zone. (4) The fuel stage combustion is more effective to reduce $NO_x$ formation in the wide range of stoichiometric ratio than two stage combustion. (5) The results of this study could be utilized mainly in a design strategy for low $NO_x$ emission from the combustion of high fuel-nitrogen in energy sources ratio than as an indication of the absolute levels of $NO_x$ which can be achieved by stage combustion techniques in large scale facilities.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.32 no.10
• /
• pp.729-753
• /
• 2008

Oxy-fuel combustion is a reliable way for the reduction of pollutants, the higher combustion efficiency and the separation of carbon dioxide. The review of recent research trends and the prospects of oxy-fuel combustion were presented. The difference in characteristics among oxy-fuel combustion, conventional air combustion, oxy-fuel combustion with flue gas recirculation (FGR) technique was investigated. Recent experiments of oxy-fuel combustion with/without FGR were surveyed in various ways which are optimized burner design, flame characteristics, the soot emission, the radiation effect, the NOx reduction and the corrosion of combustor. Numerical simulation is more important in oxy-fuel combustion because flame temperature is so high that conventional measurement devices have a restricted application. Equilibrium and non-equilibrium chemical reaction mechanisms for oxy-fuel combustion were investigated. Combustion models suitable for the numerical simulation of non-premixed oxy-fuel flame were surveyed.

• Journal of the Korean Society of Combustion
• /
• v.14 no.4
• /
• pp.17-24
• /
• 2009

Reburning is one of the most useful technologies for reducing nitric oxide in economically and technically. The reburning process was demonstrated as an effective NOx reduction method through injection of a secondary hydrocarbon fuel. An experimental study has been conducted to evaluate the effect of biomass reburning on NOx and CO formation in a light oil flamed combustion furnace. Reburning tests on NOx reduction of air-carried rice husk powder as the reburn fuel and light oil as the main fuel were performed in flames stabilized by a co-flow swirl and fuel staged burner, which was mounted at the front of the furnace. The results included flue gas emissions and temperature distribution in the furnace for several kinds of experimental conditions. It was observed clearly that NOx concentrations in the exhaust have considerably decreased due to effect of biomass reburning. The maximum NOx reduction rate was 42% when the reburn fuel fraction was 0.18. The CO emissions were kept under 42 ppmv in all experimental tests. And this paper makes clear that in order to decrease NOx concentration in the exhaust when the biomass reburning system is adapted, the control of some factors such as reburn fuel fraction and reburn zone fraction is very important.

• Journal of Electrochemical Science and Technology
• /
• v.7 no.4
• /
• pp.269-276
• /
• 2016

Carbon-supported ordered Pt-Ti alloy nanoparticles were prepared as a durable and efficient oxygen reduction reaction (ORR) electrocatalyst for polymer electrolyte membrane fuel cells (PEMFCs) via wet chemical reduction of Pt and Ti precursors with heat treatment at $800^{\circ}C$. X-ray diffraction analysis confirmed that the prepared electrocatalysts with Ti precursor molar compositions of 40% (PtTi40) and 25% (PtTi25) had ordered $Pt_3Ti$ and $Pt_8Ti$ structures, respectively. Comparison of the ORR polarization before and after 1500 electrochemical cycles between 0.6 and 1.1 V showed little change in the ORR polarization curve of the electrocatalysts, demonstrating the high stability of the PtTi40 and PtTi25 alloys. Under the same conditions, commercial carbon-supported Pt nanoparticle electrocatalysts exhibited a negative potential shift (10 mV) in the ORR polarization curve after electrochemical cycling, indicating degradation of the ORR activity.

• Journal of the Korean Society of Visualization
• /
• v.21 no.2
• /
• pp.8-13
• /
• 2023

The primary challenge in improving fuel efficiency and reducing air pollution for commercial vehicles is reducing their aerodynamic drag. Various flow control devices, such as cab-roof fairing, gap fairing, cab extender, and side skirt have been introduced to reduce drag, however, the drag reduction effect and applicability are different depending on each commercial vehicle model. To evaluate the fuel consumption of heavy vehicles, a comprehensive research approach, including drag force measurement, flow field analysis is required. This study investigated the effect of a cab extender, which installed rear region of cab, on a drag coefficient of commercial vehicle through wind tunnel experiments and CFD. The results showed that the cab extender significantly modified the flow structure around the vehicle, leading to 8.2% reduction in drag coefficient compared to the original vehicle model. These results would provide practical application for enhancing the aerodynamic performance and fuel efficiency of heavy vehicle.

• Environmental Engineering Research
• /
• v.11 no.3
• /
• pp.149-155
• /
• 2006

NOx reduction experiments were conducted by direct injection of urea into a diesel fueled, combustion-driven flow reactor which simulated a single engine cylinder ($966cm^3$). NOx reduction tests were carried out over a wide range of air/fuel ratios (A/F=20-40) using an initial NOx level of 530ppm, and for normalized stoichiometric ratios of reductant to NOx (NSR) of 1.5 to 4.0. The results show that effective NOx reduction with urea occurred over an injection temperature range of 1100 to 1350K. NOx reduction increased with increasing NSR values, and about a 40%-60% reduction of NOx was achieved with NSR=1.5-4.0. Most of the NOx reduction occurred within the cylinder and head section (residence time <40msec), since temperatures in the exhaust pipe were too low for additional NOx reduction. Relatively low NOx reduction is believed to be due to the existence of higher levels of CO and unburned hydrocarbons (UHC)inside the cylinder, and large temperature drops along the reactor. Injection of secondary combustible additives (diesel fuel/$C_2H_6$) into the exhaust pipe promoted further substantial NOx reduction (5%-30%) without shifting the temperature windows. Diesel fuel was found to enhance NOx reduction more than $C_2H_6$, and finally practical implications are further discussed.

• Carbon letters
• /
• v.4 no.3
• /
• pp.121-125
• /
• 2003

The Pt-Ru/Carbon as an anode catalyst supported on the commercial activated carbon (AC) having high surface area and micropore was characterized for application of Direct Methanol Fuel Cell (DMFC). The Pt-Ru/AC anode catalyst used in this experiment showed the performance of $600\;mA/cm^2$ current density at 0.3 V. The borohydride reduction process using $NaBH_4$, denoted as a process A, showed much higher current and power densities than process B prepared by changing the reduction and washing process of process A. The particle sizes are strongly affected by the reduction process than the specific surface area of raw active carbon and the sizes are almost constant when the specific surface area of carbon are over than the $1200\;m^2/g$. Smaller particle size of catalyst and more narrow intercrystalite distance increased the performance of DMFC.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.6
• /
• pp.1577-1582
• /
• 2010

A 20 wt % Pt/C is fabricated and characterized for use as the cathode catalyst in a polymer electrolyte membrane fuel cell (PEMFC). By using the polyol method, the fabrication process is optimized by modifying the carbon addition sequence and precursor mixing conditions. The crystallographic structure, particle size, dispersion, and activity toward oxygen reduction of the as-prepared catalysts are compared with those of commercial Pt/C catalysts. The most effective catalyst is obtained by ultrasonic treatment of ethylene glycol-carbon mixture and immediate mixing of this mixture with a Pt precursor at the beginning of the synthesis. The catalyst exhibits very uniform particle size distribution without agglomeration. The mass activities of the as-prepared catalyst are 13.4 mA/$mg_{Pt}$ and 51.0 mA/$mg_{Pt}$ at 0.9 V and 0.85 V, respectively, which are about 1.7 times higher than those of commercial catalysts.

• Journal of Korean Society for Atmospheric Environment
• /
• v.10 no.E
• /
• pp.303-310
• /
• 1994

The effects of NOx reduction by new staged fuelling system in a small scale combustor (6.6 ㎾$_{T}$) have been investigated using propane gas flames laden with ammonia as fuel-nitrogen. The variables which had the greatest influence on NOx reduction were temperature, reducing stoichiometry( related to main combustion zone stoichiometry, air fraction and returning fuel fraction ) and residence time. The best NOx reduction was observed at the reburning zone stoichiometry of 0.85. In terms of residence time of the reburning zone, NOx reduction was effective when burnout air was injected at the Point where the reburning zone has been already established.d.