• Title/Summary/Keyword: fuel composition

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Prediction of MCFC Performance Using Three Dimensional Heat and fluid Flow Analysis with Electrochemical Reaction (전기 화학 반응을 포함한 3차원 열유동 해석을 이용한 용융탄산염 연료전지의 성능예측)

  • Cho H. M.;Lee K. W.;Choi D. H.
    • 한국전산유체공학회:학술대회논문집
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    • 2003.08a
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    • pp.219-224
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    • 2003
  • An analysis procedure for the MCFC channel flow has been developed to predict the fuel cell performance. As for the electrochemical reaction, among several chemical reaction models, one that fits the data best is adopted after a comprehensive comparative study. The Wavier-Stokes, energy, and species equations are solved to obtain the velocity, temperature and concentration fields for a specified average current density. The procedure is iterative as the local current density, or the reaction rate, is allowed to vary with the gas composition. A series of calculations are then carried out to examine the effects of gas flow rate, gas composition, gas usage rate, inlet gas temperature, and average current density on the fuel cell performance. The fuel cell characteristics, such as the temperature, current density distributions, and the concentration fields, for various operating conditions are presented and discussed.

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INFLUENCE OF ALLOY COMPOSITION ON WORK HARDENING BEHAVIOR OF ZIRCONIUM-BASED ALLOYS

  • Kim, Hyun-Gil;Kim, Il-Hyun;Park, Jeong-Yong;Koo, Yang-Hyun
    • Nuclear Engineering and Technology
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    • v.45 no.4
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    • pp.505-512
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    • 2013
  • Three types of zirconium base alloy were evaluated to study how their work hardening behavior is affected by alloy composition. Repeated-tensile tests (5% elongation at each test) were performed at room temperature at a strain rate of $1.7{\times}10^{-3}s^{-1}$ for the alloys, which were initially controlled for their microstructure and texture. After considering the yield strength and work hardening exponent (n) variations, it was found that the work hardening behavior of the zirconium base alloys was affected more by the Nb content than the Sn content. The facture mode during the repeated tensile test was followed by the slip deformation of the zirconium structure from the texture and microstructural analysis.

A Study on Performance Characteristics of Ti-Zr Type Metal Hydrides and Hydrogen Storage Cylinders with the Hydrides (Ti-Zr계 금속수소화물 및 수소저장실린더의 성능특성 연구)

  • Kim, Ki-Youl
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.4
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    • pp.519-526
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    • 2012
  • Recently fuel cell is considered to be a new technology that can substitute the ICE(Internal Combustion Engine) as well as overcome environmental issues. In military applications, fuel cell has an unique advantages, which are quietness, namely, stealth. The environmental requirement such as shock and vibration in military application, however, is very severe comparing to civilian demand. Especially, the safety concerning hydrogen storage is the most important problem. Among the candidate methods to store hydrogen, the metal hydride storage is promising method owing to the storage mechanism of chemical absorption of hydrogen to metal hydrides. In this study, the new composition of Ti-Zr type metal hydride(A composition) was suggested and investigated to increase the hydrogen storage capacity. For comparison, the hydrogen charge-discharge properties were investigated with the commercialized Ti-Zr type metal hydride(B composition) using PCT(Pressure-Composition-Temperature) measurement. Also two hydrogen storage cylinders were loaded with each metal hydride and their hydrogen charging and discharging characteristics were investigated. As a result, it was found that the new Ti-Zr type metal hydride has a slightly higher hydrogen storage capacity compared to commercial Ti-Zr type metal hydride.

Combustion Characteristics of the SOFC Products for SOFC/Gas Turbine Hybrid Power Generation System (SOFC/가스터빈 혼합발전을 위한 SOFC 생성물의 연소특성)

  • Lee, Byeong Jun;Bae, Chul Han
    • Journal of the Korean Society of Combustion
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    • v.19 no.3
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    • pp.44-52
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    • 2014
  • Solid oxide fuel cell(SOFC) makes electric power using hydrogen or reformed from methane and emits high temperature products that contain flammable species like hydrogen, carbon monoxide and methane which varies with operation condition. SOFC/gas turbine integrated system which uses thermal and chemical energy of the discharges is more efficient than SOFC itself. Burning character of the SOFC products will affect the efficiency and stability of the system. Experiments were conducted to know the characteristics of the flame for two typical composition of SOFC products, i.e. start-up and steady state composition. When coflowing air temperature was higher than $600^{\circ}C$, auto-ignitin occurred for both fuels. Though start-up fuel has higher contents of hydrogen, it makes longer flame than steady state composition. It was inferred that the amount of oxidizer necessary to burn makes this phenomenon. Steady state composition fuel was unstable since it contains lots of water. Nozzle that had 6 holes, distance between each hole was 16.7 times of hole diameter, improved the stability of the flame.

A Study on the Fluid Network Analysis for the LPG Supply System of the Gaseous Fuel Injection Type (LPG 가스분사 방식 연료공급시스템의 관로 유동해석에 관한 연구)

  • Yun, Jeong-Eui;Kim, Myung-Hwan;Nam, Hyeon-Sik;Jeong, Tae-Hyuung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.2
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    • pp.35-40
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    • 2007
  • The gaseous fuel injection (GFI) type in LPG fuel supply system has more advantage than the liquified fuel injection type from the viewpoint of durability and cost reduction. But in GFI system, to control pressure and temperature of gaseous fuel is needed to get precision fuel metering for the compressible characteristic of gaseous fuel. In this study, the effects of pressure and temperature on the fuel metering was simulated by commercial flow network analysis package, Flowmaster. And the fuel composition effects on the fuel metering were also studied to figure out the fuel metering characteristics.

Determination of Air Fuel Ratio According to Fuel Composition (II) -Compensation of Unburned Gas Concentration in Eltinge Chart- (연료 조성에 따른 공연비 산정 (II) -Eltinge 차트에서 미연 성분의 보상-)

  • Ohm, In-Yong;Park, Chan-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.11
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    • pp.1563-1571
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    • 2003
  • This paper is the second part of several companion papers which compare the method of Air-fuel ratio(AFR) determination. In the previous paper, Eltinge chart was applied to the arbitrary fuel composition and the charts for gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane and butane were illustrated. In Eltinge chart, however, unburned hydrocarbon (UHC) is not used for determination of AFR. For improving accuracy, Eltinge suggested UHC compensation after the AFR reading in the chart. This compensation reduced the difference between real and reading value. In the compensation, however, the correction of oxygen and carbon dioxide is uncertain and there might be a mistake in conversion of UHC reading value. Therefore, the error is overestimated comparing with Spindt one which is most widely used. In addition, there is no comparison of the value with other useful methods. In this paper, the compensation of unburned HC was performed in Eltinge chart and the compensated value was compared with Spindts formula over wide range of AFR. The objects of investigating fuel are gasoline, methanol, NG and LPG. The result shows that Eltinge and Spindt method is flawlessly compatible and the difference between the two methods is under 0.3% in a λrange from 0.9 to 1.7. The method fur debugging instrumentation error is also presented.

A Study on the Sintering of Simulated DUPIC Fuel (모의 DUPIC 핵연료의 소결 특성 연구)

  • 강권호;배기광;박희성;송기찬;문제선
    • Journal of Powder Materials
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    • v.7 no.3
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    • pp.123-130
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    • 2000
  • The simulated DUPIC fuel provides a convenient way to investigate fuel properties and behaviours such as thermal conductivity, thermal expansion, fission gas release, leaching and so on. Several pellets simulating the composition and microstructure of the DUPIC fuel were fabricated from resintering powder through the OREOX process of the simulated spent fuel pellets, which were prepared from the mixture of stable forms of constituent nuclides. This study describes the powder treatment, OREOX, compaction and sintering to fabricate simulated DUPIC fuel using the simulated spent fuel. The homogeneity of additives in the powder was observed after attrition milling. The microstructure of the simulated spent fuel was in agreement with the previous studies. The densities and the grain size of simulated DUPIC fuel was pellets are higher than those of simulated spent fuel pellets. Small metallic precipitates and oxide precipitates were observed on matrix grain boundaries.

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Pore-filling anion conducting membranes and their cell performance for a solid alkaline fuel cell (세공충진 음이온 전도성막의 제조 및 이를 이용한 고체알칼리 연료전지 성능 평가)

  • Choi, Youngwoo;Lee, Misoon;Park, Gugon;Yim, Sungdae;Yang, Taehyun;Kim, Changsoo
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.129.2-129.2
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    • 2010
  • AEM which were used for solid alkaline fuel cell(SAFC) were prepared by photo polymerization in method pore-filling with various quaternary ammonium cationic monomers and crosslinkers without an amination process. Their specific thermal and chemical properties were characterized through various analyses and the physico-chemical properties of the prepared electrolyte membranes such as swelling behavior, ion exchange capacity and ionic conductivity were also investigated in correlation with the electrolyte composition. The polymer electrolyte membranes prepared in this study have a very wide hydroxyl ion conductivity range of 0.01 - 0.45S/cm depending on the composition ratio of the electrolyte monomer and crosslinking agent used for polymerization. However, the hydroxyl ion conductivity of the membranes was relatively higher at the whole cases than those of commercial products such as A201 membrane of Tokuyama. These pore-filling membranes have also excellent properties such as smaller dimensional affects when swollen in solvents, higher mechanical strength, lowest electrolyte crossover through the membranes, and easier preparation process compared of traditional cast membranes. The prepared membranes were then applied to solid alkaline fuel cell and it was found comparable fuel cell performance to A201 membrane of Tokuyama.

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Self-Cementitious Hydration of Circulating Fluidized Bed Combustion Fly Ash

  • Lee, Seung-Heun;Kim, Guen-Su
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.128-136
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    • 2017
  • Fly ash from a circulating fluidized bed combustion boiler (CFBC fly ash) is very different in mineralogical composition, chemical composition, and morphology from coal ash from traditional pulverized fuel firing because of many differences in their combustion processes. The main minerals of CFBC fly ash are lime and anhydrous gypsum; however, due to the fuel type, the strength development of CFBC fly ash is affected by minor components of active $SiO_2$ and $Al_2O_3$. The initial hydration product of the circulating fluidized bed combustion fly ash (B CFBC ash) using petro coke as a fuel is Portlandite which becomes gypsum after 7 days. Due to the structural features of the portlandite and gypsum, the self-cementitious strength of B CFBC ash was low. While the hydration products of the circulating fluidized bed combustion fly ash (A CFBC ash) using bituminous coal as a fuel were initially portlandite and ettringite, after 7 days the hydration products were gypsum and C-S-H. Due to the structural features of ettringite and C-S-H, A CFBC ash showed a certain degree of self-cementitious strength.