• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2006년도 춘계학술대회 논문집
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• pp.141-144
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• 2006

In this study, we developed a decladding device which separates 250 mm length of simulated nuclear spent fuel rod into the pallets and the pieces of the hulls after inserting the rod cut into the module with several pairs of blades. To improve the performance of the equipment, we considered some mechanisms to prevent the rod cut from being exposed or bounced into the hot-cell, to reduce the operation time, and to insert the rods automatically. It is expected that the newly developed system will contribute to prevent radioactive pollution in the hot-cell, reduce the operation time, and to increase the safety of the operators. As a result of the performance test for some mockup fuel rod cuts in the ACP(Advanced Spent Fuel Control Process) facility, it was verified that the decladding device could be applied to the actual fuel rod cut. And it will be able to use for a scale-up facility in the future.

• 한국수소및신에너지학회논문집
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• 제32권5호
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• pp.308-314
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• 2021

Chemical durability issue in polymer electrolyte membranes has been a challenge for the commercialization of polymer electrolyte membrane fuel cells (PEMFCs). In this study, we proposed a manufacturing method of Nafion composite membrane containing a stable polyimide antioxidant to improve the chemical durability of the membrane. The thermal casting of the Nafion solution with poly (amic acid) induced polyimide reaction. We evaluated proton conductivity, oxidative stability with ex-situ Fenton's test, and fluoride ion emission to analyze the effect of polyimide antioxidants. We confirmed that incorporating the polyimide antioxidant improves the chemical durability of the Nafion membrane while maintaining inherent proton conductivity.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1994년도 하계학술대회 논문집 C
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• pp.1373-1375
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• 1994

We now expect the various dispersed generation system installation to the power distribution system in a unexpected manner. If so, the power utility may experience the several unexpected problems such as voltage variation, harmonic distortion etc. In order to test the various phenomena related to the fault, we developed the fuel cell simulator and fault simulator. Several kinds of fault cases are tried. Test results and analysis are shown in this paper.

• E2M - 전기 전자와 첨단 소재
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• 제8권5호
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• pp.544-550
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• 1995

In this paper, the anode for molten carbonate fuel cell have been prepared by doctor blade method and microstructure, pore distribution, sintering test of the electrode were investigated. Component analysis were done by Scanning Electron Micrograph, porosimeter and sintering test apparatus. As a result, median pore size was 11.mu.m order at the major specimen and porosity was about 70%. And thickness loss of the electrode was 1.5% at Ni-10Co anode after sintering test.

• 한국수소및신에너지학회논문집
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• 제30권6호
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• pp.531-539
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• 2019

The development of cost-effective electrocatalysts with high durability is one of the most important challenges for the commercialization of polymer electrolyte fuel cells (PEFCs). The durability of the electrocatalyst has been studied in terms of structural change in the active metal and the support. In particular, in fuel cell vehicles, degradation of the carbon-based support is known to have a significant effect on the electrocatalyst deterioration since the start-up/shut-down cycle is frequently repeated. The requirements for the support of the electrocatalyst include high surface area, electrical conductivity, chemical stability, and so on. In this study, we propose the evaluation methods for choosing better support materials and present the physicochemical properties that promising carbon supports should have. Three kinds of carbon materials with different crystallinity are compared. From in-depth study using X-ray diffraction, Raman spectroscopy, thermogravimetric analysis, and accelerated stress test, it is clearly confirmed that the durability of carbon-supported electrocatalysts is closely related to the physicochemical properties of the carbon supports.

• 한국유체기계학회 논문집
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• 제9권6호
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• pp.45-53
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• 2006

Turbo-blower as an air supply system is one of the most important BOP (Balance of Plant) systems for FCV(Fuel Cell Vehicle). For generating and blowing compressed air, the motor of air blower consumes maximum 25% of net power, and fuel cell demands a clean air. In this study, turbo-blower supported by air foil bearings is introduced as the air supply system used by 80kW proton exchange membrane fuel systems. The turbo-blower is a turbo machine which operates at high speed, so air foil bearings suit their purpose as bearing elements. Analysis for confirming the stability and endurance is conducted. The rotordynamic stability was predicted using the numerical analysis of air foil bearings and it is verified through experimental works. In spite of various transient dynamic situation, the turbo-blower had stable performances. After the performance test, results are presented. The normal power of driving motor has about 1.6 kW with the 30,000 rpm operating range and the flow rate of air has maximum 160 SCFM. The test results show that the aerodymic performance and stability of turbo-blower are satisfied to the primary goals.

• 한국수소및신에너지학회논문집
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• 제16권2호
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• pp.170-179
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• 2005

Electrolyte loss is considered as one of the major obstacles limiting the life time of molten carbonate fuel cells (MCFCs). Unit cells with an effective area of 100 $cm^2$ were prepared and were operated to determine the optimum matrix thickness which contains the maximum amount of electrolyte without serious preformance loss caused by high resistance. Matrices with different thickness, 1.45, 1.8, and 2.3 mm, were used in unit cells and those cells were operared about 5000, 10000, and 4000 hrs. The unit cell used 1.8 mm thick matrix showed 0.85 V (at 150 mA/$cm^2$) as the intial performance and this cell voltage is not lower than the cell voltage obtained in the cell with 1 mm thick matrix. This cell was operated for 10000 hrs. The cell used 1.45 mm thick matrices showed 16.6 % in the electrolyte loss after 5000 hr operation. In the case of the cell with 2.3 mm thick matrix, the initial cell voltage was below 0.80 V (at 150 mA/$cm^2$). For thermal cycle test, the gas crossover amount of unit cell used 1.8 mm thick matrix was much less than that of the cell with 1.0 mm thick matrix.

• 한국수소및신에너지학회논문집
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• 제28권4호
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• pp.377-383
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• 2017

This paper presents the performance characteristics of a 1 kW solid oxide fuel cell (SOFC) stack under various internal reforming and fuel utilization conditions. The Research Institute of Industrial Science & Technology (RIST) developed the 9-cell stack using a $20{\times}20cm^2$ anode supported planar cell with an active area of $324cm^2$. In this work, current-voltage characteristic test, fuel utilization test, continuous operation, and internal reforming test were carried out sequentially for 765 hours at a furnace temperature of $700^{\circ}C$. The influence of fuel utilization and internal reforming on the stack performance was analyzed. When the 1 kW stack was tested at a current of 145.8 A with a corresponding fuel utilization of 50-70% (internal reforming of 50%) and air utilization of 27%, the stack power was approximately 1.062-1.079 kW. Under continuous operation conditions, performance degradation rate was 2.16%/kh for 664 hours. The internal reforming characteristics of the stack were measured at a current of 145.8. A with a corresponding fuel utilization of 60-75%(internal reforming of 50-80%) and air utilization of 27%. As fuel utilization and internal reforming ratio increased, the stack power was decreased. The stack power change due to the internal reforming ratio difference was decreased with increasing fuel utilization.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.123.2-123.2
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• 2010

Fuel Cell cogeneration system is a promising technology for generating electricity and heat with high efficiency of low pollutant emission. We have been developed 5kW class fuel cell cogeneration system for commercial and residential application. The fuel processor is a crucial part of producing hydrogen from the fossil fuels such as LNG and LPG. The 5kW class high efficiency fuel processor consists of steam reformer, CO shift converter, CO preferential oxidation(PrOx) reactor, burner and heat exchanger. The one-stage CO shift converter process using a metal oxide catalyst was adopted. The efficiency of 5 kW class fuel processor shows 75% based on LHV. In addition, for the purpose of continuous operation with load fluctuations in the commercial system for residential use, load change of fuel processor was tested. Efficiency of 30%, 50%, 70% and 100% load shows 75%, 75%, 73% and 72%(LHV), respectively. Also, during the load change conditions, the product gas composition was stable and the outlet CO concentration was below 5 ppm. The Fuel processor operation was carried out in residential fuel cell cogeneration system with fuel cell stack under dynamic conditions. The 5kW class fuel processor have been evaluated for long-term durability and reliability test including with improvement in optimal operation logic.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.91-91
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• 2011

This paper describes development procedure of the four types of fuel cell's blowers: pressurized fuel blower, selective oxidation air blower, cathode air blower, and burner air blower. Diaphragm blowers having two heads are selected to maintain force balance when the rotating arms are moving by the driving motor. Dimensions of a diaphragm cavity is designed according to the optimal design procedure using numerical simulation and experimental measurement. Experimental apparatus is designed by considering the bower characteristics having low flow rate and high pressure. Test blower is operated by a diaphragm, which has suction and discharge port on the top of the blower. For analyzing the internal flow of the blower, three-dimensional Navier-Stokes analysis is introduced in the present study. Throughout the optimal design of the blowers, blower performance is enhanced by reducing the unbalance motion of the rotating arm and loss region in the diaphragm cavity.