• Korean Chemical Engineering Research
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• v.54 no.3
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• pp.404-409
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• 2016

Thermal Characteristics and kinetic parameters of $LaMnO_3$ synthesis reaction were investigated by means of TGA (Thermogravimetric analysis) at non-isothermal heating conditions (5.0, 10.0, 15.0 and 20.0 K/min). The reaction was occurred rapidly at 450~600K (X=0.4~0.7) depending on the heating rate. Activation energy for the synthesis of $LaMnO_3$ from the precursor, which was determined by different method such as Friedman, Ozawa-Flynn-Wall and Vyazovkin methods, was in the range of 23~243 kJ/g-mol depending on the fractional conversion level and estimation method. The reaction order decreased with increasing heating rate and fractional conversional level. The average reaction order was 4.50 in case of X=0.1~0.3, while it was 1.87 in case of X=0.7~0.9, respectively. The value of frequency factor of reaction rate increased with inceasing heating rate and fractional conversion level. The aveage value of frequency factor was 205.6 ($min^{-1}$) when X=0.1~0.3, while it was 475.2 ($min^{-1}$) when X=0.7~0.9, respectively.

• Journal of the Korean Institute of Intelligent Systems
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• v.8 no.2
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• pp.60-69
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• 1998

This paper proposes a speech synthesis method using Fuzzy VQ, and then study how to make choice of fuzziness value which optimizes (controls) the performance of FVQ in order to obtain the synthesized speech which is closer to the original speech. When FVQ is used to synthesize a speech, analysis stage generates membership function values which represents the degree to which an input speech pattern matches each speech patterns in codebook, and synthesis stage reproduces a synthesized speech, using membership function values which is obtained in analysis stage, fuzziness value, and fuzzy-c-means operation. By comparsion of the performance of the FVQ and VQ synthesizer with simmulation, we show that, although the FVQ codebook size is half of a VQ codebook size, the performance of FVQ is almost equal to that of VQ. This results imply that, when Fuzzy VQ is used to obtain the same performance with that of VQ in speech synthesis, we can reduce by half of memory size at a codebook storage. And then we have found that, for the optimized FVQ with maximum SQNR in synthesized speech, the fuzziness value should be small when the variance of analysis frame is relatively large, while fuzziness value should be large, when it is small. As a results of comparsion of the speeches synthesized by VQ and FVQ in their spectrogram of frequency domain, we have found that spectrum bands(formant frequency and pitch frequency) of FVQ synthesized speech are closer to the original speech than those using VQ.

• The Journal of the Acoustical Society of Korea
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• v.16 no.4
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• pp.106-109
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• 1997

In the area of the speech synthesis techniques, the waveform coding methods maintain the intelligibility and naturalness of synthetic speech. In order to apply the waveform coding techniques to synthesis by rule, however, we must be able to alter the pitches for prosody control of synthetic speech. In this paper, we propose a new pitch alteration technique in time-frequency hybrid domain, that compensates phase distortion of the cepstral pitch alteration method with time scaling method in the time domain. This method can remove some phase spectrum distortion which is occurred in conjunction point between the waveforms in continued frames. Also, we can obtain little magnitude spectrum distortion below 1.18% for pitch alteration of 200%.

• Journal of Radiation Protection and Research
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• v.10 no.1
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• pp.29-40
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• 1985

The objectives of present study is to investigate genetic damage of radiation in mammalian male germ cell and. to establish available screening method for determining genetic hazard by radiation. Several methods were employed to measure the genetic damage of radiation as follows: Sperm head counts, frequency occurrence of sperm with abnormal head shape, fertility, activity of LDH-X, and the induction of unscheduled DNA synthesis (U.D.S.) in male mouse were performed with the passing of time after irradiation by making use of the sequence of event that occurs during spermatogenesis. Sperm head counts and activity of LDH-X in testes were gradually reduced by increased radiation dose and with the passing of the time after irradiation. Frequency occurrence of sperm with abnormal head shape, sterile period, and the induction of unscheduled DNA synthesis were increased by increased radiation dose. It is suggested that since germ cell is a direct reflection of genetic complement, the use of male germ cell is rapid and convenient method for measuring genetic damage by radiation.

• Journal of Powder Materials
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• v.16 no.2
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• pp.91-97
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• 2009

Nanopowders of $Co_3O_4$ and FeAl were fabricated by high energy ball milling. Dense 4.25 $Co_{0.53}Fe_{0.47}-Al_2O_3$ composite was simultaneously synthesized and consolidated by high frequency induction heated combustion method within 2 min from mechanically activated powders. Consolidation was accomplished under the combined effects of a induced current and mechanical pressure of 80 MPa.

• Journal of Korea Multimedia Society
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• v.14 no.11
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• pp.1507-1515
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• 2011

As the first step in research for sound synthesis of Pyungjong, timbre was analyzed by FFT analysis. There was no significant difference in the pitch of scale between modern Pyungjong and western twelve-tone equal temperament scale. The timbre of Pyunjong chagnes over time. When striking Pyunjong, the noises to be generated across all frequencies will disappear in a short period of time, and a unique partial only is left. Then it disappear from the partial of high frequency components in order, and two partials remain at release time. At this time, the beating is occurring by the frequency of the remaining partial. Pyungjong used in this study is relatively a recently manufactured Pyungjong, and for original sound synthesis of Pyungjong, a study of ancient Pyungjong's timbre should be additionally conducted later.

• Advances in nano research
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• v.2 no.2
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• pp.121-133
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• 2014

Polymer nanocomposites are advanced nanomaterials which exhibit dramatic improvements in various mechanical, thermal and barrier properties as compared with the neat polymer. Polystyrene/ alumina nanocomposites were prepared by an ultrasound-assisted solution casting method at filler loadings ranging from 0.2 to 2% and also at different ultrasonic frequencies, viz. 58 kHz, 192/58 kHz, 430 kHz, 470 kHz and 1 MHz. The composites were subjected to mechanical property tests (tensile and impact tests) and cavitation erosion tests to study the enhancement in functional properties. Filler dispersion in the polymer matrix was observed by SEM analysis. The effect of frequency on filler dispersion in the matrix was studied by SEM analysis and functional property enhancement of the composite material. The composites prepared at dual (high/ low) frequency (192/58 kHz) were found to show better property enhancement at low filler loadings as compared with neat polymer and also with composites prepared without ultrasound, thus reinforcing the finding that ultrasound-assisted synthesis is a promising method for the synthesis of nanocomposites.

• MALSORI
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• no.25_26
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• pp.3-26
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• 1993

The goals of the present study were (3) to collect and analyze sets of fundamental frequency (F0) and formant frequency (F1, F2, F3) data of Korean diphthongs from ten linguistically homogeneous speakers of Korean males, and (2) to make a comparative study of Korean monophthongs and diphthongs. Various definitions, kinds, and previous studies of diphthongs were examined in the introduction. Procedures for screening subjects to form a linguistically homogeneous group, time point selection and formant determination were explained in the following section. The principal findings were as follows: 1. Much variation was observed in the ongliding part of diphthongs. 2. F2 values of (j) group descended while those of [w] group ascended, 3. The average duration of diphthongs were about 110 msec, and there was not much variation between speakers and diphthongs. 4. In a comparative study of monophthongs and diphthongs, Fl and F2 values of the same offgliding part at the third time point almost converged. 5. The gliding of diphthongs was very short beginning from the h-noise. Perceptual studies using speech synthesis are desirable to find major parameters for diphthongs. The results of the present study wi11 be useful in the area of automated speech recognition and computer synthesis of speech.

• Korean Journal of Materials Research
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• v.24 no.2
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• pp.67-72
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• 2014

Nanocrystalline materials have received much attention as advanced engineering materials with improved physical and mechanical properties, including high strength, high hardness, excellent ductility and toughness. In this study, nanopowders of $Al_2O_3$, MgO and $TiO_2$ were prepared as starting materials by high energy ball milling for the simultaneous synthesis and sintering of the nanostructured compound $Mg_4Al_2Ti_9O_{25}$ by high-frequency induction heating process. The highly dense nanostructured $Mg_4Al_2Ti_9O_{25}$ compound was produced within one minute by the simultaneous application of 80MPa pressure and induced current. The sintering behavior, grain size and mechanical properties of the $Mg_4Al_2Ti_9O_{25}$ compound were evaluated.

• Journal of the Korea Institute of Military Science and Technology
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• v.17 no.1
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• pp.57-63
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• 2014

In this paper, we have proposed a wide band antenna for manpack SDR(Software Defined Radio). The proposed antenna consists of feeding post, flexible gooseneck and two radiating elements composed of a upper and lower radiators. The upper radiator has a longer electrical length than the lower radiator in order to operate in the lower frequency. Also, the resonant frequency and impedance characteristics of the antenna can be adjusted independently for two radiators. Therefore, the proposed antenna can be achieved wide impedance bandwidth by the combination of two independent resonance modes. To analyze the characteristics of the antenna in the design process is employed the equivalent circuit theory and EM(Electro-Magnetic) simulation. The measurement results show that the proposed antenna have the sufficient wide bandwidth, above -3.4dBi of the gain and fairly good radiation pattern over the wide bandwidth.