• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.5
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• pp.205-211
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• 2015

Most of the sulfur is obtained from desulfurization of natural gas and crude oil. In Korea, more than 120 tons of sulfur are produced by refinery, and about 50 % of the produced sulfur is used as a raw material for the production of fertilizer and sulfuric acid. Modified sulfur is manufactured from excessive sulfur that could be used to improve concrete properties, and this study evaluated concrete strength and durability that contains modified sulfur. Flexural and compressive strengths of concrete with sulfur modified polymer were comparable to those of OPC concrete with mixing water at similar temperatures, while the strengths increased a little as mixing water temperature increased. It was also confirmed that the resistance to freeze-thaw damage was more dependent on entrained air characteristics obtained by a proper use of air entraining agent than on the use of sulfur modified polymer. When concrete was immersed in 5 % sulfuric acid, the rate of reduction in compressive strength of OPC concrete was less than 1/4 of the strength reduction of concrete with sulfur modified polymer. Also, the resistance of concrete with sulfur modified polymer to scaling due to the use of de-icing salt was evaluated as Class 1, while that of OPC concrete was evaluated as Class 4, as aggregates were exposed. Accordingly, it is believed that sulfur modified polymer could be effectively used for bridge deck concrete since sulfur modified polymer improves the durability of concrete.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.2
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• pp.190-197
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• 2020

This paper evaluates the mechanical properties and durability of cement matrix blended with mineral admixtures and ferronickel slag(FNS) powder which is an industrial b y-product during ferronickel smelting process. The hydration heat, pore structure, compressive strength, length change, rapid chloride penetration test(RCPT), and freezing and thawing resistance of ternary blended cement matrix were investigated and compared with ordinary portland cement matrix. The result showed that the compressive strength of ternary blended cement matrix using ferronickel slag powder and mineral mixture was low in strength compared to the reference concrete, but recovered to a certain extent by using alkali activator. Length change of cement mortar using FNS powder have shown less shrinkage occurs than the reference specimen. In addition, irrespective of using the alkali-activators, all ternary mix are indicative of the 'very low' range for chloride ion penetrability according to the ASTM C 1202, and the freeze-thaw resistance also showed excellent results.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.482-488
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• 2022

In this study, the durability of ultra rapid hardening mortar for sewage pipe was evaluated by type of mortar binder. As a result of analyzing the internal structure for each type of mortar, it was confirmed that Al₂(OH)₃ was generated in the internal structure of the CAC-based mortar, and its corrosion resistance was superior to that of other types of mortar. As a result of the compressive strength test, OPC had the tsmallest strength, followed by CAC100 > CAC100P > CAC80. This trend was similar to the previous study results. Chloride ion penetration resistance and freeze-thaw test showed similar trends. That is, CAC and C12A7 were better than OPC, and CSA was worse than OPC. This is mostly beacuse of cracks caused by expansion of CSA-based mortar. CAC100P mix showed the best chemical resistance. It is thought that this is because the alumina gel formed inside the mortar and the polymer combine to make the internal structure more dense.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.3-23
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• 1997

The growth in fast-track construction and repair has prompted major efforts to develop high-early-strength concrete mix compositions. Such mixtures rely on the use of relatively high cement contents and accelerator dosages to increase the rate of strength development. The measures, however, seem to compromise the long-term performance of concrete in applications such as full-depth patches as evidenced by occasional premature deterioration of such patches. The hypothesis successfully validated in this research was that traditional methods of increasing the early-age strength of concrete, involving the use of high cement and accelerator contents, increase the moisture and thermal movements of concrete. Restraint of such movements in actual field conditions, by external or internal restraining factors, generates tensile stresses which introduced microcracks and thus increase the permeability of concrete. This increase in permeability accelerates various processes of concrete deterioration, including freeze-thaw attack. Fiver reinforcement of concrete is an effective approach to the control of microcrack and crack development under tensile stresses. Fibers, however, have not been known of accelerating the process of strength gain in concrete. The recently developed specialty cellulose fibers, however, were found in this research to be highly effective in increasing the early-age strength of concrete. This provides a unique opportunity to increase the rate of strength gain in concrete without increasing moisture an thermal movements, which actually controlling the processes of microcracking and racking in concrete. Laboratory test results confirmed the desirable resistance of specialty cellulose fiber reinforced High-early-strength concrete to restrained shrinkage microcracking an cracking, and to different processes of deterioration under weathering effects.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.116-121
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• 2016

The amount of carbon dioxide ($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical methods of reducing $CO_2$ in building materials is the addition of slag and fly ash, like pozzolan material another method is to reduce $CO_2$ production by developing carbon negative cement. MgO-based cement from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, basic research on magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as the main starting materials, as well as blast furnace slag for the mineral admixture, was carried out for industrial waste material recycling. In order to increase the overall hydration activity, $MgCl_2$ was also added. In the case of the addition of $MgCl_2$as accelerating admixture, there was a promoting effect on the compressive strength. This was found to be due to the production of needle-like dense Mg-Cl hydrates. Mgnesia cement has a high viscosity due to its high specific surface area therefore, when the PC-based dispersing agent was added at a level of more than 1.0%, it had the effect of improving fluidity. In particular, the addition of $MgCl_2$ in magnesia cement using $MgCO_3$and magnesium silicate ore (serpentine) as main starting materials led to a lower expansion ratio and an increase in the freeze-thaw resistance finally, the addition of $MgCl_2$ as accelerating admixture led to good overall durability.

• International Journal of Highway Engineering
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• v.12 no.3
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• pp.103-111
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• 2010

Recently, usage bicycle has been encouraged to reduce energy consumption and $CO_2$. For this purpose, lots of bike road construction are planned. Typical type of pavement used in bikeroad such as asphalt concrete pavement, portland cement concrete pavement, colored pavement, soil pavement. However, these pavement types may need high construction cost comparing the required capacity of bike road. In this study, roller compacted concrete pavement which are economical and durable, are investigated to use as bike road pavement. The optimum compaction level and mix design of roller compacted concrete pavement are suggested by exploring strength test with various mixture ratio and compaction level, Also durability was examined based on freeze-thaw and scaling test. In addition, the cost and amount of carbon emission during in the construction of roller compacted concrete were evaluated and compare with the cost and carbon emission of typical portland cement concrete.

• Journal of the Korea Concrete Institute
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• v.14 no.1
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• pp.16-23
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• 2002

In construction field, million tons of demolished concrete are produced in korea. It is urgently needed that they are used as recycled materials in order to prevent environment pollution and gain economic profits. However, existing recycling methods of demolished concrete have their limits for wide application. They have been only focused on the burying and banking. Therefore, in this paper, physical and mechanical properties of planting concrete using construction wastes for aggregates are described in order to investigate the validities of demolished concrete as recycled aggregates. The Properties of strength and durability are tested. According to the experimental results, compressive strength and freeze-thaw resistance of planting concrete using recycled aggregates shows worse performance than those using crushed stone concrete. But, it shows positive performance on the absorption ratio and thermal conductivity. Especially, considering the side of recycling of concrete wastes, it is recommended that recycled aggregates made with construction wastes is applied to planting concrete.

• Journal of the Korea Institute of Building Construction
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• v.21 no.4
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• pp.281-291
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• 2021

To reduce the environmental load of the construction industry, there is a need to minimize construction and demolition by strengthening the eco-friendliness of building materials and extending the durable lifespan. Therefore, while many Hanok roof finishing methods have been proposed to address these problems, the current trend is to use the existing method due to issues such as economic feasibility, weight, and durability. The manufacturing method of clay roof tiles used as roofing materials for Hanok buildings is optimized by using a mixture of 64.5% Gyeongju clay, 15.0% kaolin, 15.0% FNS(Ferro Nickel Slag), and 5.5% MAS(Magnesia Aluminum Silicate) under optimal conditions. The results of the experiment involving firing at 1,125℃ showed that flexural strength of 12,102N, which is higher than the standard of KS F 3510, an absorption rate of 6.08%, a volume specific gravity of 2.15g/cm³, and the freeze-thaw properties were satisfied. A method for securing stable quality was studied.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.6A
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• pp.449-456
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• 2011

Spacing factor proposed by Power is a concept of averaging air void spacing composed of geometric models. Thus, there's a limitation on simulating actual air void characteristics in concrete. This study presents SDI(spacing distribution index) to overcome the limitation of spacing factor. SDI is also evaluated through comparing SDI with SF(spacing factor). In this study, it was confirmed that SF decreased due to increasing air-entrainer content but SDI increased. This occurs because SDI is the area of spacing distribution curve and SDI increases with increasing the frequency of spacing. SDI is evaluated to have better coverage below $300{\mu}m$ of SF so that determination of critical point of SDI above 80% of durability index can be easily obtained with more reliability. SDI is the area of spacing distribution curve and reflects actual air void characteristics in concrete. A comparative study of SDI and results of freeze-thaw test will be performed later.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.2
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• pp.105-115
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• 2010

In this study, as one of solutions associated with the shortage of treatment area of industrial waste and the containment of its harmful components, the bottom ash which is known to be by-products of thermoelectric power plant was selected and its applicability for aggregate of concrete mixture was measured. Hardness test, sieve analysis, water-absorption test and SEM analysis were carried out to investigate the possibility of using bottom ash as a replacement of coarse and fine aggregate. Chemical analyses such as ignition loss test and X-ray incidence were carried out also. In addition, values for slump, strength, permeability, freeze and thaw, and carbonation were evaluated in terms of effects of replacement ratio of bottom ash. As the results, it was found that, though bottom ash is in short supply of fine particles and is in lack of cohesion, these problems can be solved by partially mixing with natural aggregates or improving in a process of production. In addition, bottom ash has not only advantage of durability but also acquirement of general compressive strengths in case that a certain proportion of natural aggregate is applied to mixture, in spite that unit water or chemical admixture should be increased to acquire good workability due to plenty of porosity.