• Journal of the Korean Wood Science and Technology
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• v.39 no.2
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• pp.179-186
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• 2011

In an effort to understand the hydrolytic degradation process of cured urea-formaldehyde (UF) resins responsible for the formaldehyde emission of wood-based composite panels, this study analyzed the influence of acid hydrolysis on the morphology of cured UF resins with different formaldehyde/urea (F/U) mole ratios such as 1.6, 1.4, 1.2 and 1.0. Field emission-scanning electron microscopy (FE-SEM) was employed to observe both exterior and fracture surfaces on thin films of cured UF resins before and after the etching with hydrochloric acid as a simulation of the hydrolytic degradation process. FE-SEM images showed that the exterior surface of cured UF resin with the F/U mole ratio of 1.0 had spherical structures after the acid hydrolysis while the other cured UF resins were not the case. However, the fracture surface observation showed that all the samples possessed spherical structures in the cured state of UF resins although their occurrence and size decreased as the F/U mole ratio increased. For the first time, we found the spherical structures in cured UF resins of higher F/U mole ratio of 1.4. After the acid hydrolysis, the spherical structures became a much predominant at the fracture surface. These results indicated that the spherical structures in cured UF resinswere much more resistant to the hydrolytic degradation by the acid than amorphous region.

• International Journal of Concrete Structures and Materials
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• v.4 no.1
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• pp.37-43
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• 2010

Theoretical models based on modern interpretations of the morphology and interactions of cement hydration products are developed for prediction of the mechanical properties of hydrated cement paste (hcp). The models are based on the emerging nanostructural vision of calcium silicate hydrate (C-S-H) morphology, and account for the intermolecular interactions between nano-scale calcium C-S-H particles. The models also incorporate the effects of capillary porosity and microcracking within hydrated cement paste. The intrinsic modulus of elasticity and tensile strength of hydrated cement paste are determined based on intermolecular interactions between C-S-H nano-particles. Modeling of fracture toughness indicates that frictional pull-out of the micro-scale calcium hydroxide (CH) platelets makes major contributions to the fracture energy of hcp. A tensile strength model was developed for hcp based on the linear elastic fracture mechanics theories. The predicted theoretical models are in reasonable agreements with empirical models developed based on the experimental performance of hcp.

• Journal of Mechanical Science and Technology
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• v.18 no.6
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• pp.915-923
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• 2004

This study investigated the fatigue lives and mechanical properties of the carbon black filled natural rubber for the vibration-proof parts of the railway vehicle and automobile. The carbon blacks were one of the sources of crack nucleation and crack propagation in the rubber matrix, like the cementite and the maganese sulfide in iron matrix. Different kinds of carbon blacks resulted in different fatigue lives, critical J-values, and fracture morphologies. It was noticed that the critical J-value remained almost the same regardless of the length of a pre-crack. In addition, different kinds of carbon blacks generated different fracture morphologies, and microscopic and macroscopic roughnesses. The critical J-value has linear relations to the roughness, and it seemed related to the size distribution of carbon black particles. By reviewing all the experi-mental data, we found the factors that were related to the fatigue lives, and the logarithmic value of the fatigue life could be linearly expressed by the combination of the critical J-value and the macroscopic roughness. We also proposed a new estimative equation of fatigue life.

• Journal of Mechanical Science and Technology
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• v.15 no.10
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• pp.1417-1422
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• 2001

Since fracture surface presents clear evidence to describe the circumstances of material failure event, analysis of fracture surface should provide plenty of useful information for failure prevention. Thus if we extract proper information from the fracture surface, the safety evaluation, for plant component could be more accurate. In general, the chaotic morphology of fracture surface is determined by the degree of material degradation as well as by other factors such as type of load, geometry of specimen, notch condition, microstructure of material and environment. In this research, we developed a fractal analysis technology for the fracture surface of aged turbine rotor steel based on the slit-island technique using an image analyzer. Moreover the correlation between the fractal dimension and the aging time was studied.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.7 s.262
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• pp.732-738
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• 2007

Effects of melt-mixing conditions on fracture properties of hydroxyapatite filled bioabsorbable poly(L-lactic acid)(HA/PLLA) composites was investigated by measuring the firacture toughness value of HA/PLLA composites prepared under different mixing time and rotor speed. The fracture surface morphology was also examined by profile measurement and scanning electron microscopies. It was found that the fracture toughness of HA/PLLA composites decreases due to decrease of ductile deformation of PLLA matrix and debonding of interfaces with increase of the rotor speed and mixing time. Effect of mixing process on neat PLLA was also assessed, and it was found that the fracture toughness of PLLA decreases due to disappearance of multiple craze formation and increase of defects. Such thermal and shear-stress degradation were found to be the primary mechanisms of the degradation of HA/PLLA composites during melt-mixing process.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.19 no.5
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• pp.653-659
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• 2010

Friction stir welding results in low distortion and high joint strength compared with other welding procedures, and is able to join all aluminium alloys that are not considered as virtually weldable with classical liquid state techniques. The comparative study on high cycle fatigue properties between A16005-T6 friction stir welds and MIG weld joints have been performed and fracture mechanisms for the fatigue specimens were investigated. Although mechanical properties are lower than the corresponding base material, FSW joints of A16005-T6 become higher at tensile and fatigue strength in comparison with the traditional fusion weld(MIG). The fracture surfaces of FSW and MIG fatigue specimens cleary show different aspects of the fracture morphology. MIG weldments were characterized by voids and cleavage(brittle fracture) but FSW specimens showed the presence of ductile fracture surface.

• Journal of the Korean institute of surface engineering
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• v.48 no.6
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• pp.283-291
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• 2015

The purpose of this study was to investigate effects of TiN coating on the fatigue fracture of dental implant system with various cyclic loads. TiN coated abutment screw, the fixture, and abutment of internal hex type were prepared for fatigue test. The fatigue test was carried out according to ISO 14801:2003(E) using tensile and compression tester with repeated load from 30% to 80% of static fracture force. Morphology and fractured surface was observed by field emission scanning electron microscope(FE-SEM) and energy dispersive X-ray spectroscope(EDS). The fracture cycle drastically decreased as repeated load increased. Especially, in the case of TiN-coated abutment screw, fracture cycle increased compared to non-coated abutment screw. The fatigue crack was propagated fast as repeated load increased. The plastic deformation region decreased, whereas, cleavage fracture region increased as repeated load increased.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.10a
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• pp.49-52
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• 2001

The investigation of cure kinetics, morphology, and fracture toughness studies on epoxy resin/amine terminated PEI/Anhydride system were performed by differential scanning calorimetry and scanning electron microscopy. Modified autocatalystic kinetics model was applied by isothermal scan test. The fracture toughness for the neat epoxy resin was 2.15 MPa m0.5 and the fracture toughness was improved 45% as neat epoxy resin system. The generation of secondary phase of AT-PEI was observed and its size was grown up by increasing contents of PEI.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.12
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• pp.2055-2060
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• 2003

Striation is a typical pattern observed on the fatigue fracture surface and the spacing is known to correspond to a macroscopic fatigue crack growth rate, and many models for the predict in the formation of such striation have been proposed. However, these theories and methods can't be applied under random loading spectrum. In this study, the fatigue tests were carried out on aluminum alloy under random loading spectrum. The fatigue fracture surfaces were observed in the scanning electron microscope (SEM) and great quantities of SEM micrographs were synthesized and saved in computer system. The space and morphology of several large-scale striations, which are expected to from at the relatively greater load range in loading block, were observed. The crack length for each loading blocks was decided in consideration of regularity and repetition of those striations. It is shown that the applicability of fractographic methods on the fatigue fracture surface under random loading spectrum.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.573-578
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• 2001

For the corrosion protect ion of the natural gas transmission pipelines, two methods are used, cathodic protection and coating technique. In the case of cathodic protection, defects are embrittled by occurring hydrogen at the crack tip or material surface. It is however very important to evaluate whether cracks in the embrittled area can grow or not, especially in weld metal. In this work, on the basis of elastic plastic fracture mechanics, we performed CTOD test ing with varying test conditions, such as the potential and current density. The CTOD of the base steel and weld metal showed a strong dependence of the test conditions. The CTOD decreased with increasing cathodic potential and current density. The morphology of the fracture surface showed quasi-cleavage. Hydrogen introduced fractures, caused by cathodic overprotection.