• Journal of Powder Materials
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• v.22 no.4
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• pp.283-288
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• 2015

Two sintering methods of a pressureless sintering and a spark-plasma sintering are tested to densify the Fe-TiC composite powders which are fabricated by high-energy ball-milling. A powder mixture of Fe and TiC is prepared in a planetary ball mill at a rotation speed of 500 rpm for 1h. Pressureless sintering is performed at 1100, 1200 and $1300^{\circ}C$ for 1-3 hours in a tube furnace under flowing argon gas atmosphere. Spark-plasma sintering is carried out under the following condition: sintering temperature of $1050^{\circ}C$, soaking time of 10 min, sintering pressure of 50 MPa, heating rate of $50^{\circ}C$, and in a vacuum of 0.1 Pa. The curves of shrinkage and its derivative (shrinkage rate) are obtained from the data stored automatically during sintering process. The densification behaviors are investigated from the observation of fracture surface and cross-section of the sintered compacts. The pressureless-sintered powder compacts show incomplete densification with a relative denstiy of 86.1% after sintering at $1300^{\circ}C$ for 3h. Spark-plasma sintering at $1050^{\circ}C$ for 10 min exhibits nearly complete densification of 98.6% relative density under the sintering pressure of 50 MPa.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.4
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• pp.283-296
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• 2008

The numerical simulations for groundwater flow were carried out to support the input parameters for safety assessment in LILW repository site. As the input parameters for safety assessment, the groundwater flux into the underground facilities during construction, flow rate through the disposal silo after closure of disposal silo and flow pathway from the disposal silo to discharge area were analyzed using the 10 cases groundwater flow simulations. From the total 10 numerical simulation results, the statistics of estimated output were similar to among 10 cases. In some cases, the analyzed input parameters were strongly governed by locally existed high permeable fracture zone at radioactive waste disposed depth. Indeed, numerical simulation for well scenario as a human intrusion scenario was carried out using the hydraulically severe case model. Using the results of well scenario, the input parameters for safety assessment were also obtained through the numerical simulation.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.8 no.2
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• pp.159-166
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• 2010

The block-scale groundwater flow system at Olkiluoto site in Finland was simulated. The heterogeneous and anisotropic hydraulic conductivity field for the domain was constructed from the discrete fracture network, which considered only the fractured zones identified in the deep boreholes installed in the study site. The groundwater flow model was calibrated by adjusting the recharge rate and the transmissivities of the fractured zones to fit the calculated hydraulic heads and into- and out-flow rates in the observation intervals of the boreholes with the observed ones. In the calibrated model, the calculated flow rates at some intervals were not in accordance with the observed ones although the calculated hydraulic heads fit well with the observed ones, which revealed that the number of the conduits for groundwater flow is insufficient in the conceptual model for groundwater flow modeling. Therefore, it was recommended that the potential local conduits such as background fractures should be added to the present conceptual model.

• Journal of Adhesion and Interface
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• v.4 no.1
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• pp.1-8
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• 2003

In this work, the effect of PMR-15 content on the variation of surface free energy of the DGEBA/PMR-15 blend system was investigated in terms of contact angles and mechanical interfacial tests. Based on FT-IR result of the blend system. C=O (1,772, $1,778cm^{-1}$) and C-N ($1,372cm^{-1}$) peaks appeared with imidization of PMR-15 and -OH ($3,500cm^{-1}$) peak showed broadly at 10 phr of PMR-15 by ring-opening of epoxy. Contact angle measurements were performed by using deionized water and diiodomethane as testing liquids. As a result, the surface free energy of the blends gave a maximum value at 10 phr of PMR-15, due to the significant increasing of specific component. The mechanical interfacial properties measured from the critical stress intensity factor ($K_{IC}$) and the critical strain energy release rate ($G_{IC}$) showed a similar behavior with the results of surface energetics. This behavior was probably attributed to The improving of the interfacial adhesion between intermolecules, resulting from increasing the hydrogen bondings of the blends.

• Nuclear Engineering and Technology
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• v.25 no.4
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• pp.539-547
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• 1993

A stochastic approach using continuous time Markov process is presented to model the one-dimensional nuclide transport in fractured rock media as a further extension for previous works［1-3］. Nuclide transport of decay chain of arbitrary length in the single planar fractured rock media in the vicinity of the radioactive waste repository is modeled using a continuous time Markov process. While most of analytical solutions for nuclide transport of decay chain deal with the limited length of decay chain, do not consider the case of having rock matrix diffusion, and have very complicated solution form, the present model offers rather a simplified solution in the form of expectance and its variance resulted from a stochastic modeling. As another deterministic way, even numerical models of decay chain transport, in most cases, show very complicated procedure to get the solution and large discrepancy for the exact solution as opposed to the stochastic model developed in this study. To demonstrate the use of the present model and to verify the model by comparing with the deterministic model, a specific illustration was made for the transport of a chain of three member in single fractured rock medium with constant groundwater flow rate in the fracture, which ignores the rock matrix diffusion and shows good capability to model the fractured media around the repository.

• Journal of the Korean Society for Precision Engineering
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• v.3 no.1
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• pp.40-49
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• 1986

Crack, craze and void are common defects which may be found in the bulk of polymeric materials such as either themoplastics or thermosets. The healing phenomena, autohesion, of these defects are known to be a intrinsic material property of various polymeric materials. However, only a few experimental and theoretical investigations on crack, void and craze healing phenomena for various polymeric materials have been reported up to date [1, 2, 3]. This may be partly due to the complications of healing processes and lacking of appropriate theoretical developments. Recently, some investigators have been urged to study the healing phenomena of various polymenic materials since the significance of the use of polymer based alloys or composites has been raised in terms of specific strength and energy saving. In the earlier published reports [1, 2, 3, 4], the crack and void healing velocity, healing toughness and some other healing mechanical and physical properties were measured experimentally and compared with predicted values by utilizing a simple model such as the reptation model under some resonable assumptions. It seems, however, that the general acceptance of the proposed modeling analyses is yet open question. The crack healing processes seem to be complicate and highly dependent on the state of virgin material in terms of mechanical and physical properties. Furthermore, it is also strongly dependent on the histories of crack, craze and void development including fracture suface morphology, the shape of void and the degree of disentanglement of fibril in the craze. The rate of crack healing may be a function of environmental factors such as healing temperature, time and pressure which gives different contact configurations between two separated surfaces. It seems to be reasonable to assume that the crack healing processes may be divided in several distinguished steps like stress relaxation with molecular chain arrangement, surface contact (wetting), inter- diffusion process and com;oete healing (to obtain the original strength). In this context, it is likely that we no longer have to accept the limitation of cumulative damage theories and fatigue life if it is probable to remove the defects such as crack, craze and void and to restore the original strength of polymers or polymer based compowites by suitable choice of healing histories and methods. In this paper, we wish to present a very simple and intuitive theoretical model for the prediction of healed fracture toughness of cracked or defective polymeric components. The central idea of this investigation, thus, may be the modeling of behavior of chain molecules under healing conditions including the effects of chain scission on the healing processes. The validity of this proposed model will be studied by making comparisons between theoretically predicted values and experimentally determined results in near future and will be reported elsewhere.

• Economic and Environmental Geology
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• v.53 no.2
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• pp.121-131
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• 2020

In this paper, the transmissivities obtained from the pulse test, the slug test and the constant head test were compared each other to assess an applicability and a reliability of the hydrogeological test method, which are commonly used to derive the hydrogeological properties of a crystalline rock at un underground research facility. When comparing the results of the pulse test and the slug test, the transmissivities were very similar in the entire test section of the medium. However, there was a little discrepancy in the results in the areas where the permeability is relatively high. The results of the constant head test on the same section showed the lower transmissivity than the results of the pulse test and the slug test on the highly permeable section. This difference in permeability was considered to be due to the difference in the radius of the hydraulic effect applied in each hydraulic test. When the heterogenetic distribution of fracture affects the hydrogeological properties on crystalline rock, it is believed that the hydrogeological characteristics can be explained through a constant head test or a constant flow rate test with a large hydraulic effective radius, as well as a pulse and a slug test that can identify hydrogeological properties in a relatively short time.

• Journal of Korea Foundry Society
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• v.34 no.2
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• pp.54-59
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• 2014

In this study, the extruded Al-6.3Zn-2.4Mg alloys were selected among the 7000 series aluminum alloys sensitive to hydrogen environment in order to examine the effects of both the aging conditions and the length of hydrogen charging period on the mechanical properties of the alloy. The specimens were aged for 24hours at $100^{\circ}C$ (under aging (UA)), $120^{\circ}C$ (peak aging (PA)), and $160^{\circ}C$ (over aging (OA)), respectively. Charging tests were performed at RT for 12, 24, 36 hours under potentiostatic conditions (-2000 mV vs (Ag/AgCl)) for 12, 24 and 36 hours in 1M $H_2SO_4$ and 0.1%$NH_4SCN$ solution. The fracture surface was examined by scanning electron microscopy (SEM). X-ray diffraction (XRD) pattern in peak aged sample was obtained before and after hydrogen charging from extruded Al-6.3Zn-2.4Mg alloys. The decreasing rate of tensile strength and elongation is represented in order of over aging < under aging < peak aging, and it is believed that the hydrogen recharge is more sensitive to elongation than tensile strength. The formation of $AlH_3$ in hydrogen charged Al-6.3Zn-2.4Mg alloys has been confirmed by X-ray diffraction studies.

• The Journal of Engineering Geology
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• v.8 no.3
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• pp.207-213
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• 1998

A study was conducted to determine the characteristics of acoustic emission(AE) events generated by the expansive cement induced rock fracturing. The dominant frequency and the maximum amplitude of the AE events are changed in relation to the rate of expansive pressure development in the hole. The dominant frequencies are in the range of 150∼230kHz for the small hole tests and 400∼500kHz for the large hole test. The maximum amplitudes are in the range of 0.015∼0.050cm/sec and 0.025∼0.064cm/sec, respectively. The fact that AE events of higher amplitude with higher frequency on the large hole test and lower amplitude with lower frequency on the small hole tests were detected, may strongly imply that the amount of energy consumed for a macro-crack in both tests may be similar. The expansive cement induced crack propagates stably without any distinguished event having higher amplitude and this implies that a macro-crack is a result of stable growth of micro cracks.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.5
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• pp.297-304
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• 2019

In this research, crack propagation in a silicon anode during two-phase lithiation was evaluated using a cohesive zone model. The phase transition from crystalline silicon to lithiated silicon causes compressive yielding due to the high volume expansion rate. Li-ion diffuses from the surface of the silicon to its core, and the complex deformation mechanisms during lithiation cause tensile hoop stress along the surface. The Park-Paulino-Roesler (PPR) potential-based cohesive zone model that guarantees consistent energy dissipation in mixed-mode fracture was adopted to simulate edge crack propagation. It was confirmed that the edge crack propagation characteristics during lithiation from the FEM simulation results coincided with the real experimental results. Crack turning observed from real experiments could also be predicted by evaluating the angles of maximum tensile stress directions.