• Title/Summary/Keyword: formation composition

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Counterion Specific Conformational Transition and ion Selective Transport of a Poly(L-glutamic acid)/PVA Blend Membrane (Poly(L-glutamic acid)/PVA 블렌드막의 대이온 선택적인 구조전이와 이온투과 특성)

  • 허양일
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.802-809
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    • 2000
  • Counterion-specific helix formation and ion-selective transport of alkali metal chlorides (LiCl, NaCl, KCl, CsCl) were investigated for a poly(L-glutamic acid)(PLGA)/poly (vinyl alcohol)(PVA) blend membrane immersed in aqueous ethanol. The counterion specificity for helix formation of PLG alkali metal salts in the membrane was Li>Na>K>Cs. This specificity is ascribed to a contact ion-pair formation between the PLG carboxyl anion and the bound counterion, which depends on the energy balance between the electrostatic interaction and the desolvation. In aqueous ethanol, an appreciable ion-selectivity was observed for the permeability coefficient, i.e. Li$^{+}{\cdot}$Cl$^{-}$) formation between counterion and coion, and the latter to a specific interaction of diffusing counterions with polymer charges.

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Formation of Liquid Crystal Gel with Hydrogenated Lecithin and Its Effectiveness

  • Kim In-Young;Lee Joo-Dong;Ryoo Hee-Chang;Zhoh Choon-Koo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.29 no.2 s.43
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    • pp.181-191
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    • 2003
  • This study described about method that form liquid crystal gel (LCG) by main ingredient with hydrogenated lechin (HL) in OW emulsion system. Result of stability test is as following with most suitable LCG's composition. Composition of LCG is as following. To form liquid crystal, an emulsifier used $4.0\;wt\%$ of cetostearyl alcohol (CA) by $4.0\;wt\%$ of HL as a booster, Moisturizers contained $2\;wt\%$ of glycerin and $3.0\;wt\%$ of 1.3-butylene glycol (1,3-BG). Suitable emollients used $3.0\;wt\%$ of cyclomethicone, $3.0\;wt\%$ of isononyl isononanoate (ININ), $3.0\;wt\%$ of cerpric/carprylic triglycerides (CCTG), $3.0\;wt\%$ of macademia nut oil (MNO) in liquid crystal gel formation. On optimum conditions of LCG formation, the pHs were formed all well under acidity or alkalinity conditions. Considering safety of skin, PH was the most suitable $\pm61.0$ ranges. The stable hardness of LCG formation appeared best in $32\;dyne/cm^2.$ Particle of LCG is forming size of $1{\~}20\;{\mu}m$ um range, and confirmed that the most excellent LCG is formed in $1{\~}6\;{\mu}m$ range. According to result that observe shape of LCG with optical or polarization microscope, LCG could was formed, and confirmed that is forming multi-layer lamellar type structure around the LCG. Moisturizing effect measured clinical test about 20 volunteers. As a result, moisturizing effect of LCG compares to placebo cream was increased $30.6\%$. This could predicted that polyol group is appeared the actual state because is adsorbed much to round liquid crystal droplets to multi-lamellar layer's hydrophilic group. It could predicted that polyol group is vast quantity present phase that appear mixed because is adsorbed to round liquid crystal to multi-lamellar layer's hydrophilic group. This LCG formation theory may contribute greatly in cosmetics and pharmacy industry development.

Effects of Rapid Weight Loss on Body Composition and Heinz Body Formation in Middle-School Wrestlers (중학교 레슬링 선수의 단기간 체중 감량이 신체 구성과 적혈구 Heinz body 형성에 미치는 영향)

  • Kim, Jong-Oh;Kim, Young-Uk;Yoon, Jin-Hwan
    • Journal of Life Science
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    • v.16 no.6
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    • pp.884-889
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    • 2006
  • The purpose of this study was to examine the changes of body composition and heinz body blood component after 3 days rapid weight loss(5.16% of total body weight) through combined method with total food restriction and dehydration. The result were as follows: The average weight showed a significant difference between before and after rapid weight loss(p < .05). The percentage of body fat showed some decrease in average with $12.14{\pm}1.80\;(%)$ after weight decrement in an average of $12.68{\pm}1.69\;(%)$ before rapid weight loss, but the difference that noted did not show. The body fluid showed a significant difference between before and after rapid weight loss(p < .05). RDW, ESR, and Heinz body formation showed a significant increase after rapid weight loss. It was concluded that rapid weight loss techniques result in deleterious effects on body composition and red blood cell in middle school wrestler.

Formation and Deformation of the Fluid Mud Layer on Riverbeds under the Influence of the Hydrological Property and Organic Matter Composition (하천 수문 특성과 유기물 성상 변화에 따른 하상 유동상 퇴적물 거동 연구)

  • Trung Tin Huynh;Jin Hur;Byung Joon Lee
    • Journal of Korean Society on Water Environment
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    • v.40 no.2
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    • pp.79-88
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    • 2024
  • This study employed field measurements and biogeochemical analysis to examine the effects of seasonal conditions (e.g., temperature and precipitation) and human intervention (e.g., dam or weir construction) on the chemical composition of dissolved organic matter, flocculation kinetics of suspended particulate matter, and formation of the fluid mud layer on riverbeds. The results indicated that a water environment with a substantial amount of biopolymers offered favorable conditions for flocculation kinetics during an algal bloom period in summer; a thick fluid mud layer was found to be predominated with cohesive materials during this period. However, after high rainfall, a substantial influx of terrigenous humic substances led to enhanced stabilization of the particulate matter, thereby decreasing flocculation and deposition, and the reduced biopolymer composition served to weaken the erosion resistance of the fluid mud on the riverbed. Moreover, a high-turbulence condition disaggregated the flocs and the fluid mud layer and resuspended the suspended particulate matter in the water column. This study demonstrates the mutual relationship that exists between biogeochemistry, flocculation kinetics, and the formation of the fluid mud layer on the riverine area during different seasons and under varying hydrological conditions. These findings are expected to eventually help inform the more optimal management of water resources, which is an urgent task in the face of anthropogenic stressors and climate change.

Microstructure and Hot Corrosion Resistance of Aluminide and Chromium-Aluminide Coatings for Inconel 600 (Inconel 600에 있어서 Al 및 Al-Cr擴酸浸透 被覆處理에 따른 被覆層의 特性과 耐蝕性)

  • Chung In-Sang;Park, Kyeung-Chae;Park, Soo-Ho
    • Journal of the Korean institute of surface engineering
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    • v.20 no.3
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    • pp.95-105
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    • 1987
  • For the purpose of improving the hot corrosion resistance of Ni-base superalloy, Inconel 600, aluminide and chromium-aluminide coatings by pack cementation process were studied. The morphology of these coatings is dependent on the type of process employed. And their overall composition depends on the composition of the base alloy and on the nature of the cement. Therefore the different aluminide and chromium-aluminide coatings obtained on a superalloy do not possess the same resistance to oxidation and hot corrosion. The mechanisms governing the formation of the coatings and the composition of the coating were varied by pack composition and temperature, and cyclic hot corrosion resistance of the auluminide coating formed by one-step process was inferior to that of the coating formed by two-step process. and Cr-Al composite coating showed good resistance for cyclic hot corrosion.

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Studies on the Formation of Copper Complexes of Sulfa-Drug II.Study on Chemical Constisuent of Copper Sulfa-Drug Complex by Continuous Variation Method. (Sulfa제-Cu착화합물의 형성에 관하여 II Spectrophotometry 에 의한 Copper Sulfa-Drug Complex 의 화학조성결정)

  • 이왕규
    • YAKHAK HOEJI
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    • v.8 no.4
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    • pp.96-99
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    • 1964
  • In the previous study, the composition ratios of the Cu-sulfa drugs complexes determined by gravimetric and solvent extraction method reported. In this paper, the continuous variations method has been used to know whether the complexes are simple complexes or chelates, and to recertify the composition ratios of the complexes at pH 7-8. It has been certified that the ratio of $Cu^{+2}$ ion to sulfa drugs in 1:2 from the result of this experiment.

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The Study on Foam Formation in Waterslag-Bentonite System (수광재와 백토조합물에서의 기포형성에 관한 연구)

  • 김종희;송한식
    • Journal of the Korean Ceramic Society
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    • v.14 no.4
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    • pp.248-255
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    • 1977
  • The effect of firing temperature, soaking time and batch composition upon the glass phase and pore formation as well as their distribution in slag foamed glass was investigated. Sulfur dioxide gas produced by the oxidation and reduction of metal sulfide in waterslag was attributed to foam forming agent. Slag foamed glass matrix was mainly composed of 35~60% glas phase and melilite crystalline phase. The increment of bentonite addition in batch lowered the foam forming temperature in studied system. The result showed also that the foam size distribution was broadened as th firing temperature wa inbereased.

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Fabrication and Characterization of Sol-Gel Ternary Titanium Silicate Waveguides

  • Junmo Koo;Han, Sang-Soo;Bae, Byeong-Soo
    • The Korean Journal of Ceramics
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    • v.2 no.2
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    • pp.89-94
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    • 1996
  • Aluminum and zinc titanium silicate sol-gel films were fabricated for application of waveguide and the effect of additions of ZnO and $Al_2O_3$ to binary titanium silicate films was investigated. During firing, the films are densified as they shrunk and their refractive index increases in the range of 1.58-1.83 depending on the film composition. The attenuation of the waveguides is not sensitive to changes in composition except for zinc titanium silicate waveguides which have substantially higher attenuation. However, the increase in the attenuation with aging of the waveguides depend upon the composition of waveuides. The addition $Al_2O_3$ or the reduced $SiO_2$ content in the composition appears to slow the deterioration of the waveguides due to the formation of more stable bonds and increased acidity on the film surface. Also, the wavelength dependence of the attenuation of the waveguides varies with composition. The attenuation of the waveguides except for the $65SiO_2{\cdot}35TiO_2$ composition are not Rayleigh scatter limited, suggesting the absorption loss of the waveguides due to the effects of residual carbon and structural defects in the films.

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The Type of Composition and Classification of Tension Structure Systems in Architecture (건축 인장구조시스템의 분류와 구성유형)

  • Lee, Ju-Na;Park, Sun-Woo;Park, Chan-Soo
    • Journal of Korean Association for Spatial Structures
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    • v.3 no.3 s.9
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    • pp.111-120
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    • 2003
  • Tension members is a type of effective structural member, which is often used in large span structures. The structure systems composed with tension members are combined in various way and specific formations. So, there are need to research into the formations of tension structure and the type of adaptation in tension structure architectures. The structure systems with tension members were considered as tension main system, vector system and tension supported bending system, comprehensively. And tension structures were classified into the formation of tension structure with uniaxial or multiaxial line tension member, with surface member, with hybrid member of line and surface, concerning the flow of tension force. In each the formation of tension structure, the typical adaptations to architecture were also investigated through architecture examples. The type of the formation can be used to plan an architecture with respect to the flow of tension force and structural feature.

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