• Title/Summary/Keyword: formation composition

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Formation Behaviour Al-Ti Intermetallic Compounds by Ball milling methods (볼 밀링에 의한 Al-Ti 계 금속간화합물 생성 거동)

  • 안인섭
    • Journal of Powder Materials
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    • v.6 no.1
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    • pp.42-48
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    • 1999
  • Three mixtures of elemental powders of Al-25at.%Ti, 48at.%Ti and 70at.%Ti were offered to ball milling process for the formation of intermetallic compounds of $Al_3Ti$, AlTi and $Ti_3Al$. Ballmilling or attrition process were carried out at the condition of rotaing speed of 110 or 350 rpm at $10^{-3}$ torr vacuum or argon atmospheres. $Al_3Ti$phases were fully obtained by heat treatment for 1 hors at $600^{\circ}C$ with Al-25at.%Ti composition mixtures milled by 100 hours. The amorphous phase was completely formed at the composition of Al-48at.%Ti mixed powders by milling 100hours at the 50 to 1 weight ratio of ball to powder, and AlTi compounds were obtained by heat treament. In the case of Al-70at%Ti mixed powders milled for 100 hours, $Ti_3Al$ and $Al_3Ti$intermetallic compounds were formed by heat treatment for 1 hour at $600^{\circ}C$. By attrition milling of 350rpm for 10 hours, $Ti_3Al$ phase was formed completley after heat treatment for 1 hour at $600^{\circ}C$.

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Chemical Mass Composition of Ambient Aerosol over Jeju City (제주시 지역 미세먼지의 변동과 화학적 구성 특성)

  • Lee, Ki-Ho;Kim, Su-Mi;Kim, Kil-Seong;Hu, Chul-Goo
    • Journal of Environmental Science International
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    • v.29 no.5
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    • pp.495-506
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    • 2020
  • This study investigated the nitrate formation process, and mass closure of Particulate Matter (PM) were calculated over the urbanized area of Jeju Island. The data for eight water-soluble inorganic ions and nineteen elements in PM2.5 and PM10 were used. The results show that the nitrate concentration increased as excess ammonium increased in ammonium-rich samples. Furthermore, nitrate formation was not as important in ammonium-poor samples as it was in previous studies. According to the sum of the measured species, approximately 45~53% of gravimetric mass of PM remained unidentified. To calculate the mass closure for both PM2.5 and PM10, PM chemical components were categorized into secondary inorganic aerosol, crustal matter, sea salt, trace matter and unidentified matter. The results by the mass reconstruction of PM components show that the portion of unidentified matter was decreased from 52.7% to 44.0% in PM2.5 and from 45.1% to 29.1% in PM10, despite the exclusion of organic matter and elemental carbon.

Synthesis of $SrTiO_3$ from the Mixtures of $SrCO_3$ and $TiO_2$ ($SrCO_3$$TiO_2$를 사용한 $SrTiO_3$의 합성반응에 관한 연구)

  • 이종권;이병하
    • Journal of the Korean Ceramic Society
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    • v.20 no.1
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    • pp.43-48
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    • 1983
  • The formation of strontium titanate from several molar $SrCO_3$ and $TiO_2$ mixtures was studied in air and $CO_2$ gas Mixtures of $SrCO_3$ and $TiO_2$ were heated in air at 400-$600^{\circ}C$ DTA-TG was used to obtain thermal histories of simples heated in air and $CO_2$ gas. X-ray diffraction analysis was used to determine both the phase composition and the amounts of each phase present. The phase relationship of various compounds $SrTiO_3$, $Sr_2TiO_4$, $Sr_2Ti_3O_7$ and $Sr_4Ti_3O_{10}$ formed by the sintering in each composition was shown by the calibration curves. High temperature X-ray analysis was used to determine both the formation process and deformation process of each products. Small amount of SrTiO3 is formed first at the surface af contact SrTiO3 reacts with $SrCO_3$ to form Sr2TiO4 this is affected on the $CO_2$ pressure.

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A Study on the Direct Synthesis of TaC by Cast-bonding (주조접합법에 의한 TaC 직접합성에 관한 연구)

  • Park, Heung-Il;Lee, Sung-Youl
    • Journal of Korea Foundry Society
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    • v.17 no.4
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    • pp.371-378
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    • 1997
  • The study for direct synthesis of TaC carbide which was a reaction product of tantalum and carbon in the cast iron was performed. Cast iron which has hypo-eutectic composition was cast bonded in the metal mold with tantalum thin sheet of thickness of $100{\mu}m$. The contents of carbon and silicon of cast iron matrix was controlled to have constant carbon equivalent of 3.6. The chracteristics of microstructure and the formation mechanism of TaC carbide in the interfacial reaction layer in the cast iron/tantalum thin sheet heat treated isothermally at $950^{\circ}C$ for various time were examined. TaC carbide reaction layer was grown to the dendritic morphology in the cast iron/tantalum thin sheet interface by the isothermal heat treatment. The composition of TaC carbide was 48.5 at.% $Ti{\sim}48.6$ at.% C-2.8 at.% Fe. The hardness of reaction layer was MHV $1100{\sim}1200$. The thickness of reaction layer linearly increased with increasing the total content of carbon in the cast iron matrix and isothermal heat treating time. The growth constant for TaC reaction layer was proportional to the log[C] of the matrix. The formation mechanism of TaC reaction layer at the interface of cast iron/tantalum thin sheet was proved to be the interfacial reaction.

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A Study on the Deformation of Folk Village (전통민속마을의 주거변형실태에 관한 연구 - 낙안민속마을을 중심으로 -)

  • Park, Ik-Soo
    • Journal of the Korean Institute of Rural Architecture
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    • v.6 no.3
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    • pp.63-74
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    • 2004
  • This study is focusing on the Nagan Folk Village, primarily because of its historical and cultural values. The purpose of this study, accordingly, analysis the fact of the dwelling change through spot-survey and case-investigation, and is to find a way to improve for the rational preservation of the traditional dwelling analyzing on the actual condition and the reason for such changes in the Nakan Folk Village. The dwelling change is stemmed from the physical factors, and some modifications of internal composition, exterior formation, building equipment. As a result, The changes of internal composition are included in the reduction of garnering room, the enlargement of bed/service room, the establishment of mechanical room. The changes of exterior formation with structural material are included in the glass door for the internalization of 'TOEMARU', the extra glass door for the brightening of room, the cement plastering for the endurance of wall. The changes of building equipment are included in the establishment of oil-boiler, wash closet, sink for convenient life All houses should be graded on their qualitative value, managed in a cycle. And its own criterion for acceptable deformations should be established.

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A Study on Ag-doping in Chalocogenide Thin Films Application for Programmable Metallization Cell (PMC(Programmable Metallization Cell) 응용을 위한 칼코게나이드 박막에서의 Ag-doping에 관한 연구)

  • Choi, Hyuk;Nam, Ki-Hyun;Ju, Yong-Woon;Lee, Yung-Hie;Chung, Hong-Bay
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1325-1326
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    • 2007
  • We have demonstrated new functionalities of Ag doped chalcogenide glasses based on their capabilities as solid electrolytes. Formation of such amorphous systems by the introduction of silver via photo-induced diffusion in thin chalcogenide films is considered. The influence of silver on the properties of the newly formed materials is regarded in terms of diffusion kinetics and Ag saturation is related to the composition of the hosting material. Silver saturated is related to the composition of the hosting material. Silver saturated Ge-Ch glasses have been used in the formation of solid electrolyte which is the active medium in programmable metallization cell (PMC) devices. This paper concerns our more recent work on silver-doped germanium selenide electrolytes and describes the electrical characteristics of PMC devices made from these materials following annealing at $300^{\circ}C$.

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Effect of the Cu Composition Ratio on the Phase Transformation in Low Ni Austenite Cast Iron, Fe-3%C-16%(Ni+Mn+Cu) (Fe-3%C-16%(Ni+Mn+Cu) 주철에서 상변태에 미치는 Cu 조성비의 영향)

  • Park, Gi-Deok;Heo, Hoe-Jun;Na, He-Sung;Kang, Chung-Yun
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.419-425
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    • 2012
  • The purpose of this research was to develop a low Ni austenitic cast iron through replacing Ni by Cu and Mn because they are cheaper than Ni. The effect of the Cu content (6-12 wt%) on the microstructure characteristics was investigated in Fe-3%C-16%(Ni+Cu+Mn) cast iron. Contrary to general effect of the Cu on cast iron, the result of the microstructure analysis indicated that bainite and cementite were formed in high Cu content (>8 wt%Cu). A crystallized Cu-solution (Cu-Mn) phase and MnS in the Cu-solution were formed. The quantity of those phases increased as the Cu content increased. Consequently, the high Cu content in the composition ratio (Ni+Cu+Mn=16%) caused the formation of Cu-Mn/MnS and those phases decreased the effect of Cu and Mn on austenite formation. For this reason, bainite and cementite were formed in high Cu content.

Formation Behavior of Passive State Film on Stainless Steel for Metallic Ion Concentration in Electropolishing Solution (전해 연마액 금속 이온 농도에 따른 스테인리스 스틸의 부동태 피막 형성 거동)

  • Oh, Jong Su;Kang, Eun-Young;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.230-236
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    • 2022
  • The formation behavior of a passive state film on the surface of STS304 in electrolytic solution was analyzed to determine its metallic ion composition. The properties of passive state films vary depending on the Fe and Cr ions in the electrolytic solution. It was observed that the passive state film surface became flat and glossy as the concentration of Fe and Cr ions in the electrolytic solution increased. The corrosion resistance property of the passive state film was proportional to the amount of Fe and Cr in the electrolytic solution. An initial passive state film with high Fe concentration was formed on the surface of STS304 during early electrolytic polishing. Osmotic pressure of Fe ions occurs between the passive state film and electrolytic solution due to the Fe ion concentration gradient. The Fe in the passive state film is dissolved into the electrolyte, and Cr fills up the Fe ion vacancies. As a result, a good corrosion-resistant floating film was formed. The more Fe ions in the electrolytic solution, the faster the film is formed, and as a result, a flat passive state film containing a large amount of Cr can be formed.

Microstructural Properties of the Insoluble Residue in a Simulated Spent Fuel

  • Kim, J.S.;Song, B.C.;Jee, K.Y.;Kim, J.G.;Chun, K.S.
    • Nuclear Engineering and Technology
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    • v.30 no.2
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    • pp.99-111
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    • 1998
  • Chemical composition of the insoluble residue in a simulated spent PWR fuel(SIMRJEL) were studied. SIMFUELS were prepared by adding calculated amount of FP(fission product) elements with a burnup of 3.6% FIMA(fission per initial metal atom) to uranium in nitrate solution, evaporating the mixed solution to dryness, calcining at 90$0^{\circ}C$ in a stream of 4% H$_2$ + 96% He, and heating the pellet at 140$0^{\circ}C$ under high and low oxygen potentials. Insoluble residue was obtained from the dissolution of the SIMFUEL with HNO$_3$(1 : 1). The chemical composition of the SIMFUELs and the insoluble residues was determined by EPMA(electron probe microanalysis), XPS(X-ray photoelectron spectroscopy) and by XRD (X-ray diffraction) measurements. All of the insoluble residues suspended and precipitated were composed mainly of Mo, Ru with a small amount of Zr, Rh, Pd and Cd. The amount of insoluble residue(<1 wt.%) and a Mo/Ru ratio decreased with increasing oxygen potential. Formation of the zirconium molybdate precipitate, ZrMo$_2$O$_{7}$(OH)$_2$($H_2O$)$_2$, was observed in the residues. The possible role of Mo on the phase formation was discussed in regard to oxygen potential.l.

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Orientation toward Teaching of Science Teachers Showed in Lesson on Law of Definite Composition in Middle School and the Factors Which Influenced Its Formation (중학교 일정성분비의 법칙 수업에서 나타난 과학교사의 교수지향과 그의 형성에 영향을 준 요인)

  • Kim, Jin-Hee;Choi, Byung-Soon
    • Journal of Science Education
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    • v.38 no.1
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    • pp.103-119
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    • 2014
  • The purpose of this study was to investigate orientation toward teaching of science teachers had shown in lesson on Law of Definite Composition for middle school students and the factors which influenced its formation. To achieve this, we collected survey materials by recording and analyzing lessons of 8 teachers, interviewing them, and using CoRe questionnaire. From teachers' activities in lessons, we found their orientation toward science teaching, and through analyzing collected materials, drew the factors which influenced the formation of orientation toward science teaching. The result identified two types of orientation toward science teaching: activity-directional and lecture-directional. The former, activity-directional was categorized further as exploration and non-exploration; the latter as interaction-centered and content delivery. The main factors which affected the formation of orientation toward science teaching were reflective thinking through teaching experiences, interaction with colleagues, consideration on education environment, training as a learner, and their own interest and curiosity. Among them, the reflective thinking through teaching experiences was strongest cause, and teacher's interest and curiosity was even limited, also influenced positively. On the other hand, unlikely other factors, consideration on education setting affected negatively to build teacher's teaching orientation. Interaction with colleagues, training for teachers by universities and graduated schools acted on a bit, but had a limit just for mainly developing science content knowledge.

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