• Title/Summary/Keyword: formaldehyde emissions

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Effect of Temperature and Bake-out on Formaldehyde Emission from UF Bonded Wood Composites

  • Lee, Young-Kyu;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.2
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    • pp.91-100
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    • 2012
  • This study analysis the effect of various temperatures (20, 35 and $50^{\circ}C$) on the formaldehyde emission from wood composites, which were particleboard (PB), medium density fiberboard (MDF), high density fiberboard (HDF) and laminated HDF (L-HDF) by Japanese desiccator method. Also, to reduce formaldehyde emission by wood composites, it has been suggested that undergo a bake-out conditions. On average, the level of formaldehyde emission increased many times with a $15^{\circ}C$ increase in temperature from 20 to $35^{\circ}C$ for PB, MDF, HDF and L-HDF, respectively. Formaldehyde emissions from wood composites could be expected to increase with increasing ambient temperature. At $35$ for 28 days bake-out treatment of boards, the free formaldehyde emission reduced 67.8% (PB), 40.1% (MDF), 37.8% (HDF), and 35.2% (L-HDF). On the other hand, after the bake-out at $50^{\circ}C$ for 28 days, the formaldehyde concentration decreased by 88.2, 66.9, 62.2 and 59.3% of the concentration before the bake-out for PB, MDF, HDF and L-HDF, respectively. An interesting of the bake-out treatment at $50^{\circ}C$ after 14 days, formaldehyde emission grade of PB & MDF down $E_2$ to $E_1$, and HDF & L-HDF down $E_1$ to $E_0$.

The Effect of Olefin Contents on Exhaust Emissions from Gasoline Vehicles (휘발유 차량에서 배출가스에 미치는 올레핀의 영향)

  • Park, Cheonkyu;Jung, Choongsub;Na, Byungki
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.2
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    • pp.37-43
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    • 2014
  • Exhaust emissions were studied as a function of gasoline olefin composition in two vehicles-MPI and GDi engine equipped vehicles. Three different gasolines were tested which varied in olefin contents-12, 16 and 20 vol%. Exhaust emissions in two vehicles were affected by changes in gasoline olefin composition. Responses to changes in olefins were similar in both vehicles : reducing olefins lowered emissions of NOx and CO. Measured exhaust emissions included total hydrocarbons (THC), oxides of nitrogen (NOx), carbon monooxide(CO), carbon dioxide($CO_2$), formaldehyde, benzene, toluene, xylene, 1,3-butadiene and acetylene.

Mock-up Model of the Environment Assessment Study on Red-clay and Cement (Mock-up모델을 이용한 황토 및 시멘트의 환경요소 평가 연구)

  • Choi, Yool;Song, Hyeun-Guen
    • KIEAE Journal
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    • v.11 no.2
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    • pp.91-96
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    • 2011
  • The purpose of this study is to measure the environmental effects of different alternative building materials. The following building materials were tested: clay bricks, cement wall, and red-clay plaster. Four mock-up models were constructed using clay bricks, cement wall, red-clay plaster and the last model as the control model. The effects of the above four building materials on temperature, humidity, the emissions of formaldehyde, and V.O.C were measured. This experiment was conducted during September. The conclusions are as follows. Clay bricks were able to control temperature, humidity and filter formaldehyde by itself. The environment within the cement wall was not affected by the humidity changes outside. Red-clay plaster walls had little impact on the environment because it is very thin.!

Formaldehyde Emission of Building Materials and Effect of Carbonized Board on Their Reduction (건축재료의 폼알데하이드 방출 특성 및 탄화보드에 의한 저감 효과)

  • Jang, Jae-Hyuk;Lee, Min;Lee, Sang-Min;Park, Sang-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.3
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    • pp.327-334
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    • 2017
  • This study was carried out to investigate the formaldehyde emission of building materials and effect of carbonized-board (c-board) on formaldehyde reduction using a chamber method. As a result, reduction performance of formaldehyde was in the order of c-board (90%), c-bamboo board (84%), diatomite-based panel (82%), allophane-based tile (78%), Pinus densiflora timber (58%), MDF (54%) and gypsum-based board (46%) for approximately 12 days. In $1.9m^3$ chamber filled with particleboard (PB), the formaldehyde reduction performance of c-board was significantly increased with increasing input amount of c-board for 68 days. In particular, the formaldehyde emissions can be reduced above 40% and 75% by input rate of 10% and 30% c-board, respectively, in given ratio of chamber volume and PB area.

Korea Emissions Inventory Processing Using the US EPA's SMOKE System

  • Kim, Soon-Tae;Moon, Nan-Kyoung;Byun, Dae-Won W.
    • Asian Journal of Atmospheric Environment
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    • v.2 no.1
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    • pp.34-46
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    • 2008
  • Emissions inputs for use in air quality modeling of Korea were generated with the emissions inventory data from the National Institute of Environmental Research (NIER), maintained under the Clean Air Policy Support System (CAPSS) database. Source Classification Codes (SCC) in the Korea emissions inventory were adapted to use with the U.S. EPA's Sparse Matrix Operator Kernel Emissions (SMOKE) by finding the best-matching SMOKE default SCCs for the chemical speciation and temporal allocation. A set of 19 surrogate spatial allocation factors for South Korea were developed utilizing the Multi-scale Integrated Modeling System (MIMS) Spatial Allocator and Korean GIS databases. The mobile and area source emissions data, after temporal allocation, show typical sinusoidal diurnal variations with high peaks during daytime, while point source emissions show weak diurnal variations. The model-ready emissions are speciated for the carbon bond version 4 (CB-4) chemical mechanism. Volatile organic carbon (VOC) emissions from painting related industries in area source category significantly contribute to TOL (Toluene) and XYL (Xylene) emissions. ETH (Ethylene) emissions are largely contributed from point industrial incineration facilities and various mobile sources. On the other hand, a large portion of OLE (Olefin) emissions are speciated from mobile sources in addition to those contributed by the polypropylene industry in point source. It was found that FORM (Formaldehyde) is mostly emitted from petroleum industry and heavy duty diesel vehicles. Chemical speciation of PM2.5 emissions shows that PEC (primary fine elemental carbon) and POA (primary fine organic aerosol) are the most abundant species from diesel and gasoline vehicles. To reduce uncertainties in processing the Korea emission inventory due to the mapping of Korean SCCs to those of U.S., it would be practical to develop and use domestic source profiles for the top 10 SCCs for area and point sources and top 5 SCCs for on-road mobile sources when VOC emissions from the sources are more than 90% of the total.

Physico-mechanical Properties and Formaldehyde/TVOC Emission of Particleboards with Volcanic Pozzolan

  • Kim, Sumin;An, Jae-Yoon;Kim, Jin-A;Kim, Hee-Soo;Kim, Hyun-Joong;Kim, Hak-Gyeom
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.2
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    • pp.39-50
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    • 2007
  • The purpose of this study was to investigate the physico-mechanical properties and characteristics on reduction of formaldehyde and total volatile organic compound (TVOC) emission from particleboard (PB) with added volcanic pozzolan. Pozzolan was added as a scavenger at the level of 1, 3, 5, and 10 wt.% of urea formaldehyde (UF) resin for PB manufacture. The moisture content, density, thickness swelling, water absorption and physical properties of PBs were examined. Three-point bending strength and internal bond strength were determined using a universal testing machine. Formaldehyde and TVOC were determined by desiccator and 20L small chamber methods. With increasing pozzolan content the physical and mechanical properties of the PBs were not significantly changed, but formaldehyde and TVOC emissions were decreased. Because pozzolan has a rough and irregular surface with porous form, it can be used as a scavenger for PBs at a content up to 10 wt.% without any detrimental effect on the physical and mechanical properties.

Measurement of Formaldehyde in the Atmosphere using a Dual-channel Glass Coil Sampler (이중 채널 유리코일 샘플러를 이용한 대기 중 포름알데하이드 측정)

  • Park Seung-Shik;Hong Sang-Bum;Lee Jai-Hoon;Cho Sung-Yong;Kim Seung-Jai
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.2
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    • pp.259-266
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    • 2006
  • A dual-channel glass coil sampling technique was used to measure hourly formaldehyde concentration in the ambient air. The dual-channel coil sampling assembly consists of three parts; an all-pyrex 28-turn coil made of 0.2-cm internal diameter glass tubing for gas-liquid contact and scrubbing of soluble gases, an inlet section upstream of the coil for introducing sample air and scrubbing solution, and a widened glass section downstream of the coil for gas-liquid separation. The scrubbing solution used was a dilute aqueous DNPH (dinitrophenylhydrazine) solution. Hourly concentration of formaldehyde was determined at a Gwangju semi-urban site during two intensive studies between September and October using the dual channel glass-coil/DNPH sampling technique and HPLC (High Performance Liquid Chromatography) analysis. The mean concentration was 1.7($0.4{\sim}4.7$) and 3.0($0.5{\sim}19.1$) ppbv for the September and October intensives, respectively, which are considerably low, compared to those measured in polluted urban areas around the world including several urban areas of Korea. The diurnal variation showed significant increase of formaldehyde in the daytime suggesting the dominance of formation of formaldehyde due to photochemical oxidation of methane and other hydrocarbons. An increase in the formaldehyde sometimes in the night might be due to an increase in primary source, i.e. traffic emissions. It was also found that rapid increase in formaldehyde levels from 3.0 to 19.1 ppbv in the afternoon on October 20 was due to plumes from burning of agricultural wastes such as rice straw and stubble. It is expected from the measurement data that the constructed dual-channel glass coil sampling system can be utilized for measuring atmospheric concentration of the formaldehyde with high time resolution.

Analysis of Catalytic Reaction Characteristics of NGV Exhaust Gas by FTIR Spectroscopy (FTIR법에 의한 천연가스자동차 배기의 촉매반응특성 분석)

  • Choi, B.C.;Kim, Y.K.;Lim, M.T.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.6
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    • pp.218-225
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    • 1998
  • FTIR spectroscopy, useful technology for simultaneous and continuous measurement of the various components of the automotive exhaust gas, is utilized to investigate catalytic reaction charactristics of methane and a few unregulated exhaust emissions of NGV. Major findings are (1) catalytic reaction characteristics of methane measured in unsteady states of varying temperature are similar to those measured in steady states, (2) about 24 % of NO was oxidized to $NO_2$ as soon as they encounter catalysts, (3) study of formaldehyde suffers from difficulties in measurement due to the proximity in wavenumber of formaldehyde and methane, and requires an analyzer of higher resolution and accuracy than used in this study.

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Monitoring of Formaldehyde Concentration in Exhibition Hall Using Passive Sampler (Passive Sampler를 이용한 유물 전시관내 폼알데하이드 농도 모니터링)

  • Lee, Sun Myung;Lim, Bo A;Kim, Seojin
    • Journal of Conservation Science
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    • v.33 no.5
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    • pp.319-329
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    • 2017
  • In this study, formaldehyde concentrations in two exhibition halls were monitored using a passive sampler from May 2012 to April 2013. Formaldehyde concentrations in the exhibition halls were 5 to 36 times higher than concentrations outdoors. Concentrations inside the exhibition room and showcase varied according to pollutant source, HVAC(heating, ventilation, air conditioning)system and environment management. The formaldehyde concentration levels were corrected according to a standard method prescribed by Indoor Air Quality Management Law of the Ministry of Environment, Korea. As a result, Most concentration levels exceeded the exhibition standard of the Ministry of Environment($100{\mu}g/m^3$) and artifacts conservation standard of Tokyo National Museum($50{\mu}g/m^3$). Seasonal concentrations in the exhibition room and showcase were in the order summer>fall>spring>winter. Formaldehyde emissions increased in summer when air temperature and relative humidity are both high. Formaldehyde concentration distribution according to the temperature and relative humidity showed positive correlation. Air temperature showed good correlation because $R^2$ was in the range of 0.8~0.9. Analysis of formaldehyde emission characteristics in the exhibition hall would be helpful in efforts to improve indoor air quality.