• Title/Summary/Keyword: formaldehyde emission.

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Formaldehyde Emission of Wood-Based Composite Panels with Different Surface Lamination Materials Using Desiccator Method

  • Park, Byung-Dae;Kang, Eun Chang;Lee, Sang-Min;Park, Jong Young
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.4
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    • pp.600-606
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    • 2016
  • Wood-based composite panels such as plywood, particleboard (PB), or medium density fiberboard (MDF) are mostly used in the lamination on their surface for the manufacturing of furniture, or interior building products, the concern on the formaldehyde emission (FE) from the surface laminated wood panels is increasingly attracting attentions from the public. Thus, this study was conducted to understand influence of surface laminating materials to the FE from PB and MDF with or without edge sealing, using 24-hour desiccator method. Both PB samples that had been laminated on their surface with low-pressure laminate (LPL) or polypropylene (PP) film and MDF that had been treated with poly(vinyl chloride) (PVC) or coating were tested for the FE with or without edge sealing. As expected, the FE of PB with the sealed edges decreased to 37.4% and 80.7% with the LPL and PP lamination, respectively. The surface laminated MDF with the sealed edges also showed a decrease in the emission up to 57.8% and 54.3%, with the PVC lamination and coating, respectively. However, the coated MDF samples showed 5.3% increase in the emission when their edges were not sealed, indicating a FE form the solvent used for coating. These results showed that the type of surface lamination materials on wood-based composite panels has a great impact on their resultant FE, indicating that the influence of surface laminating materials should be taken into consideration for the formaldehyde mission measurement.

Influence of Hydrolytic Degradation on the Morphology of Cured Urea-Formaldehyde Resins of Different Formaldehyde/Urea Mole Ratios

  • Park, Byung-Dae;Jeong, Ho-Won
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.2
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    • pp.179-186
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    • 2011
  • In an effort to understand the hydrolytic degradation process of cured urea-formaldehyde (UF) resins responsible for the formaldehyde emission of wood-based composite panels, this study analyzed the influence of acid hydrolysis on the morphology of cured UF resins with different formaldehyde/urea (F/U) mole ratios such as 1.6, 1.4, 1.2 and 1.0. Field emission-scanning electron microscopy (FE-SEM) was employed to observe both exterior and fracture surfaces on thin films of cured UF resins before and after the etching with hydrochloric acid as a simulation of the hydrolytic degradation process. FE-SEM images showed that the exterior surface of cured UF resin with the F/U mole ratio of 1.0 had spherical structures after the acid hydrolysis while the other cured UF resins were not the case. However, the fracture surface observation showed that all the samples possessed spherical structures in the cured state of UF resins although their occurrence and size decreased as the F/U mole ratio increased. For the first time, we found the spherical structures in cured UF resins of higher F/U mole ratio of 1.4. After the acid hydrolysis, the spherical structures became a much predominant at the fracture surface. These results indicated that the spherical structures in cured UF resinswere much more resistant to the hydrolytic degradation by the acid than amorphous region.

Characteristics of Volatile Organic Compounds and Aldehydes Emission from Yellow poplar (Liriodendron tulipifera L.) (백합나무 판재의 VOCs 및 Aldehydes 방출특성)

  • Lee, Min;Park, Sang-Bum;Lee, Sang-Min;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.357-366
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    • 2014
  • Based on fundamental properties and machining characteristics of Yellow poplar (Liriodendron tulipifera L.), it has well performance on machinability or workability, drying, and fine surface. Additionally, yellow poplar is light weight and has bright color with high performance of bending processing, so it could be used for furniture or artworks materials and wood-based panel materials. Recently, public attention has been focused on indoor air quality, and Ministry of environment drift more tight regulation on indoor air quality for an apartment house and public facility with the times. Construction materials has been assessed emission of volatile organic compounds (VOCs) and formaldehyde according to law (No.10789), so yellow poplar is also needed to assess these emission characteristics. Emission of VOC and aldehyde compounds from dry and green wood condition of yellow poplar were investigated with KS M 1998:2009. Based on results, more than 30 compounds were detected from yellow poplar, and lower NVOC (natural VOC) were emitted than AVOC (Anthropogenic VOC) and OVOC (other VOC). Formaldehyde emission was lower than $5{\mu}g/m^3$ and acetaldehyde, ketone, and propionaldehyde were detected from yellow poplar. From dry yellow poplar, m-Tolualdehyde ($33.6{\mu}g/m^3$) was additionally detected while no detection of propionaldehyde. After drying process, amount of ketone emission increased significantly. The unique smell of yellow poplar may not only come from emission of acetaldehyde and propionaldehyde.

Long Term Formaldehyde Emission Trend of Wood Panels Manufactured by F/U Molar Ratios in Urea Resin Adhesive (요소수지의 F/U 몰비별로 제조된 목질패널의 포름알데히드 장기 방출 경향)

  • Park, Heon
    • Journal of the Korea Furniture Society
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    • v.11 no.2
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    • pp.73-78
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    • 2000
  • This study was carried out to measure formaldehyde emission with the passing of two years from plywood, sliver-board and strand-board bonded with urea resins which were made of 6 f/U molar ratios. The urea resins were manufactured by six kinds of formaldehyde/urea molar ratio of 1.0, 1.2, 1.4, 1.6, 1.8 and 2.0. 1. The plywood with molar ratio of 1.0 satisfied the KS F3101 $F_2$ directly after manufacture. The plywood with molar ratio of 1.2 satisfied m 3 days. The plywood with molar ratio of 1.4 satisfied the $F_3$ in 3 days and the $F_2$ in 600 days. And the plywood with molar ratio of 1.8 and 2.0 satisfied the $F_3$ in 365 days, but didn't satisfy the $F_2$ in 730 days. 2. Sliver-board with molar ratio of 1.0 and 1.2 satisfied the KS F3104 $E_2$ right after manufacture. Sliver-board with molar ratio of 1.4 and 1.6 satisfied in 150 and 360 days, respectively. Sliver-board with molar ratio of 1.8 and 2.0 satisfied in 730 days. 3. Strand-board with molar ratio of 1.0 and 1.2 satisfied the KS F3104$ E_2$ directly after manufacture. Strand-board with molar ratio of 1.4 and 1.6 satisfied in 150 days. But Strand-board with molar ratio of 1.8 and 2.0 didn't satisfied in 730 days.

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Preparation of Blood Glue from Porcine Plasma Protein and Cross-linking Reaction of Plasma Protein with Formaldehyde

  • Cho, Yongsik;Lee, Hwahyoung;Song, Kyung Bin
    • Journal of Applied Biological Chemistry
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    • v.42 no.2
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    • pp.81-84
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    • 1999
  • Blood glue was prepared to reutilize porcine blood. Plasma proteins after lyophilization were treated by addition of wood flour, sodium hydroxide, sodium silicate, and hydrated lime to make blood glue with a suitable adhesivity. Characteristics of the prepared blood glue was monitored by measuring the viscosity with time, and the relationship between degree of hydrolysis of plasma proteins by addition of various amounts of sodium hydroxide and adhesivity was studied. To prevent the emission of formaldehyde during manufacturing of plywood by blood glue, the cross-linking reaction of plasma protein with formaldehyde was also examined. Fourier transform infrared, circular dichroism, and fluorescence spectroscopy study showed that blood plasma proteins react with formaldehyde, resulting in removal of formaldehyde by cross-linking reaction.

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Formaldehyde Deodorization Effect and Far-Infrared Emission Characteristics of Ceramics Prepared with Sawdust, Risk Husk, and Charcoal: Effect of Material Mixing Ratio

  • HWANG, Jung-Woo;OH, Seung-Won
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.2
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    • pp.104-112
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    • 2022
  • Indoor air quality is a very important environmental factor in modern society. However, air pollutants generated from various interior construction materials significantly affect the human body, including formaldehyde (HCHO) and volatile organic compounds that threaten public health by deteriorating indoor air quality. Effective in removing these harmful substances are porous materials, such as woodceramics. In this study, charcoal, a porous material, was added to rice husk, an agricultural by-product, and sawdust generated during the sawing process to prepare boards and ceramics at different mixing ratios, and the HCHO deodorization performance and far-infrared emission characteristics were measured. As the mixing ratio of charcoal increased, the deodorization rate of the boards and ceramics tended to increase. Overall, the deodorization rate was measured to be 80% to 90%, indicating that the boards and ceramics prepared with charcoal are suitable to be used for the purpose of deodorization. The effect of the material mixing ratio on far-infrared emissivity and emission power was insignificant.

Formaldehyde Emission of Building Materials and Effect of Carbonized Board on Their Reduction (건축재료의 폼알데하이드 방출 특성 및 탄화보드에 의한 저감 효과)

  • Jang, Jae-Hyuk;Lee, Min;Lee, Sang-Min;Park, Sang-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.3
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    • pp.327-334
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    • 2017
  • This study was carried out to investigate the formaldehyde emission of building materials and effect of carbonized-board (c-board) on formaldehyde reduction using a chamber method. As a result, reduction performance of formaldehyde was in the order of c-board (90%), c-bamboo board (84%), diatomite-based panel (82%), allophane-based tile (78%), Pinus densiflora timber (58%), MDF (54%) and gypsum-based board (46%) for approximately 12 days. In $1.9m^3$ chamber filled with particleboard (PB), the formaldehyde reduction performance of c-board was significantly increased with increasing input amount of c-board for 68 days. In particular, the formaldehyde emissions can be reduced above 40% and 75% by input rate of 10% and 30% c-board, respectively, in given ratio of chamber volume and PB area.

A Study on the Indoor Air Pollutants Emission Characteristics by Composed Building Materials (건축자재 마감구성에 따른 실내공기오염물질 방출특성에 관한 연구)

  • Park, Jin-Chul;Rhee, Eon-Ku;Yu, Hyung-Ku
    • Proceedings of the SAREK Conference
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    • 2005.11a
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    • pp.3-8
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    • 2005
  • Building parts of Multi-Family Houses are consisted of several building material assembly. Therefore, after selecting building materials with test result of emission intensity and their feature, composed building materials are made equally with actual construction methods, and experimented emission intensity. 7 days after experiment, formaldehyde emission intensity appeared low in an order of Tile Wall, Wood Flooring, Wallpaper, Reum Flooring, Silk Wallpaper, and 20 days after experiment, TVOC emission intensity appeared low in an order of Tile Wall, Reum Flooring, Silk Wallpaper, Wood Flooring, Wallpaper. There was a clear difference in TVOC emission intensity according to kind of building materials. Composed building materials that weight per unit area is big and omission intensity is high, they effect continuously to indoor air because decrement is small.

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A Study on the Emission Characteristics of Aldehydes from Various Industries (대기 배출 사업장의 알데하이드류 배출특성)

  • Hwang, Cheol-Won;Kim, In-Goo;Kim, Se-Kwang;Oh, Cheon-Hwan;Kim, Tae-Hyun;Jeong, Byeong-Hwan;Im, Ju-Hyeok;Moon, Hye-Ran;Kim, Jong-Soo
    • Journal of Environmental Health Sciences
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    • v.44 no.2
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    • pp.169-177
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    • 2018
  • Objectives: The emission characteristics of aldehydes were investigated in five industries for the efficient management of aldehydes. Methods: Aldehydes and THC were measured from the stack and boundary of facilities. The relative concentrations and odor contribution of aldehydes were evaluated. Results: The concentrations of aldehydes in the asphalt manufacturing and printing industries were relatively high. Formaldehyde met emission limits for all facilities. According to the odor contribution analysis of aldehydes, i-valeraldehyde and butyraldehyde, which have a relatively low odor threshold value, were found to be the major odor-causing substances in the painting and textile processing industries. Conclusions: Among the aldehydes, the major emission compounds were formaldehyde in asphalt manufacturing, acetaldehyde in the paper manufacturing and textile processing industries, and butyraldehyde in the printing and painting industries. Therefore, to increase the effectiveness of aldehyde reduction, proper control devices need to be installed and operated according to the emission characteristics of aldehydes.

Estimation of Source Emission Rate on Volatile Organic Compounds and Formaldehyde Using Indoor Air Quality Modeling in New Apartment (실내공기질 모델을 이용한 신축공동주택의 VOCs 및 HCHO 배출량 추정)

  • Sim, Sang-Hyo;Kim, Yoon-Shin;Yang, Won-Ho
    • Journal of Environmental Science International
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    • v.15 no.10
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    • pp.929-933
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    • 2006
  • Indoor air quality is the dominant contributor to total personal exposure because most people spend a majority of their time Indoors. Especially when indoor environments have sources of contaminants, exposure to in-door air can potentially pose a greater threat than exposure to ambient air. In this study, estimations of volatile organic compounds and formaldehyde omission rate in indoor environments of new apartments were carried out using mass balance model in indoor environment, because indoor air quality can be affected by source generation, outdoor air level, ventilation, decay by reaction, temperature, humidity, mixing condition and so on. Considering the estimated emission rate of volatile organic compounds and formaldehyde, it Is suggested that new apartment should be designed and constructed in the aspect of using construction materials to emit low hazardous air pollutants.