• 한국지하수토양환경학회지:지하수토양환경
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• 제25권1호
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• pp.74-83
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• 2020

In this study, the effect of hydrochloric acid (HCl) concentrations on removal efficiency and chemical forms of heavy metals in dredged sediment during acid washing was investigated. The removal efficiencies of Zn, Cu, Pb, Ni and Cd by acid washing were 18.4-92.4%, 7.2-83.7%, 9.4-75%, 8.1-53.4% and 34.4-70.8%, respectively. Overall, the removal efficiencies of heavy metals were remarkably enhanced with the increase of the acid strength. However, the removal efficiencies for 0.5 and 1.0 M HCl were comparable, and both cases met the Korean soil contamination standard. Based on the sequential extraction results, concentration of the exchangeable fraction (F1), the most labile fraction, increased whereas concentrations of the other fractions decreased with increasing acid strength. Particularly, the carbonate (F2) and Fe/Mn oxides (F3) fractions drastically decreased by using 0.5 M or 1.0 M HCl. The current study results verified that acid washing could effectively reduce heavy metal concentrations and its potential mobility in dredged sediments. However, the study also found that acid washing may cause significant increase in bioavailable fraction of heavy metals, suggesting the need to evaluate the changes in chemical forms of heavy metals by acid washing when determining the acid strength to be applied.

• 한국수산과학회지
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• 제32권2호
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• pp.165-169
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• 1999

포말분리 장치를 이용한 해수 중의 단백질 제거 특성을 조사한 결과, 단백질 농도가 높을 수록 또한 폭기량이 높을수록 단백질의 제거속도는 증가하는 것으로 나타났다. 이러한 각각의 제거특성을 통계학적으로 비선형 회귀분석하여 각각의 인자의 변화에 따른 단백질 농도의 변화를 다음의 식으로 나타낼 수 있었다. $$f\;(Co,\;u)=1.5712\times10^{-7}\timesCo^{3.061}\timesu^{1.258}$$ 위 식을 이용하여 유한차분법으로 시뮬레이션을 수행한 결과 실제 포말분리 운전에서 나타난 결과와 상관성이 아주 높은 결과를 얻을 수 있었다.

• 한국산학기술학회논문지
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• 제8권1호
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• pp.136-142
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• 2007

최근 부영양화를 야기시키는 물질인 $PO_4^{3-}$ 이온을 제거하기 위해 고형반응물을 이용하는 것이 주목을 받고있다. 철광석의 정련 과정에서 생기는 슬래그는 용해된 무기 인산염을 폐수로부터 유리시켜 흡착 제거하는 것에 대한 근본적인 연구가 이루어져 왔다. 본 연구는 물 속의 인산염을 제거하기 위해 전로슬래그를 이용하였을 때 오랜 시간동안 hydroxyapatite 형태로 변화시켜 제거하고 인산염 제거를 향상시키기 위한 가능성을 찾기 위하여 여러 가지 조건을 변화시켜서 수행하였다. 본 연구 결과 전로슬래그를 이용한 등온흡착식을 적용했을 때 Freundlich 식을 적용할 수 있었으며, 인을 제거하는데 사용된 전로 슬래그의 크기는 $2{\sim}0.425mm$가 가장 적당한 것으로 나타났다. 특히, 연속반응탑을 이용할 경우, 유입수 농도가 1 mg/L일 때 80%까지 제거되는 것으로 나타났다.

• Membrane and Water Treatment
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• 제1권4호
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• pp.283-296
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• 2010

During the disinfection of potable water, humic substances present in the solution react with chlorine to form potential carcinogenic compounds. This study evaluates the feasibility of using a submerged membrane photocatalysis reactor (SMPR) process for treatment of humic substances through the characterization of both organic removal efficiency and membrane hydraulic performance. A simple SMPR was operated and led to the removal of up to 83% of the polluting humic matters. Temporal rates of organic removal and membrane fouling were found to decrease with filtration time. Using tighter membrane in the hybrid process resulted in not only higher organic removal, but also more significant membrane fouling. Under the experimental conditions tested, optimum $TiO_2$ concentration for humic removal was found to be 0.6 g/L, and increasing initial pollutant concentration expectedly resulted in a more substantial membrane fouling. The importance of the influent nature and pollutant characteristics in this type of treatment was also assessed as various water sources were tested (model humic acid solution vs. local water containing natural organic matters). Results from this study revealed the promising nature of the SMPR process as an alternative technique for organic removal in the existing water treatment system.

• Environmental Engineering Research
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• 제14권3호
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• pp.164-169
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• 2009

A powder form of aluminum (hydr)oxides is not suitable in wastewater treatment/filtration systems because of low hydraulic conductivity and large sludge production. In this study, aluminum (hydr)oxide-coated sand (AOCS) was used to remove phosphate from aqueous solution. The properties of AOCS were analyzed using a scanning electron microscopy (SEM) combined with an energy dispersive X-ray spectrometer (EDS) and an X-ray diffractometer (XRD). Kinetic batch, equilibrium batch, and closed-loop column experiments were performed to examine the adsorption of phosphate to AOCS. The XRD pattern indicated that the powder form of aluminum (hydr)oxides coated on AOCS was similar to a low crystalline boehmite. Kinetic batch experiments demonstrated that P adsorption to AOCS reached equilibrium after 24 h of reaction time. The kinetic sorption data were described well by the pseudo second-order kinetic sorption model, which determined the amount of P adsorbed at equilibrium ($q_e$ = 0.118 mg/g) and the pseudo second-order velocity constant (k = 0.0036 g/mg/h) at initial P concentration of 25 mg/L. The equilibrium batch data were fitted well to the Freundlich isotherm model, which quantified the distribution coefficient ($K_F$ = 0.083 L/g), and the Freundlich constant (1/n = 0.339). The closed-loop column experiments showed that the phosphate removal percent decreased from 89.1 to 41.9% with increasing initial pH from 4.82 to 9.53. The adsorption capacity determined from the closed-loop experiment was 0.239 mg/g at initial pH 7.0, which is about two times greater than that ($q_e$ = 0.118 mg/g) from the kinetic batch experiment at the same condition.

• 반도체디스플레이기술학회지
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• 제16권1호
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• pp.22-28
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• 2017

The result of stripping process for the removal of the post etch/ash Photoresist (PR) residue on an aluminum patterned wafer by using supercritical $CO_2$ ($sc-CO_2$) mixture, was investigated by scanning of electron microscope (SEM) inspection of wafer, measuring the cloud points and visual observation of the state of $sc-CO_2$ mixtures. It was found that $sc-CO_2$ mixtures were made by mixing additives and $sc-CO_2$ should form homogeneous and transparent phase (HTP) in order to effectively and uniformly remove the post etch/ash PR residue on the aluminum patterned wafer using them. The additives were formulated by mixing and co-solvents like an amine compound and fluorosurfactants used as HTP agents, and the PR residue on the wafer were able to be rapidly and effectively removed using the $sc-CO_2$ mixture of HTP. The five kinds of additives were formulated by the recipe of mixing co-solvents and surfactants, which were able to remove PR residue on the wafer by mixing with $sc-CO_2$ at the stripping temperature range from 40 to $80^{\circ}C$. The five kinds of $sc-CO_2$ mixtures which were named as PR removers were made, which were able to form HTP within the above described stripping temperature. The cloud points of $sc-CO_2$ mixtures were measured to find correlation between them and HTP.

• 산업기술연구
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• 제18권
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• pp.249-258
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• 1998

In this paper, we investigated the post-combustion removal of nitrogen oxide($NO_x$) and sulfur oxide($SO_x$) which is based on the gas to particle conversion process by the pulsed corona discharge. Under normal pressure, the pulsed corona discharge produces the energetic free electrons which dissociate gas molecules to form the active radicals. These radicals cause the chemical reactions that convert $SO_x$ and $NO_x$ into acid mists and these mists react with $NH_3$ to form solid particles. Those particles can be removed from the gas stream by conventional devices such as electrostatic precipitator or bag filter. The reactor geometry was coaxial with an inner wire discharge electrode and an outer ground electrode wrapped on a glass tube. The simulated flue gas with $SO_x$ and $NO_x$ was used in the experiment. The corona discharge reactor was more efficient in removing $SO_x$ and $NO_x$ by adding $NH_3$ and $H_2O$ in the gas stream. We also measured the removal efficiency of $SO_x$ and $NO_x$ in a cylinder type corona discharge reactor and obtained more than 90 % of removal efficiency in these experimental conditions. The effects of process variables such as the inlet concentrations of $SO_x$, $NH_3$ and $H_2O$, residence time, pulse frequencies and applied voltages were investigated.

• 한국미생물·생명공학회지
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• 제47권1호
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• pp.116-124
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• 2019

The rapid development of the poultry industry has led to the production of large amounts of manure, which produce substances like hydrogen sulfide ($H_2S$) that contribute to odor pollution. $H_2S$ is a highly undesirable gas component and its removal from the environment is therefore necessary. Sulfur-oxidizing bacteria (SOB) are widely known to remove contaminating $H_2S$ due to their ability to oxidize reduced sulfur compounds. In this study, three potential SOB (designated AH18, AH25, and AH28) that were previously isolated from a hot spring in Malaysia were identified by 16S rRNA gene analysis. Laboratory-scale biological deodorization experiments were conducted to test the performance of the three isolates-in the form of pure or mixed cultures, with the cells immobilized onto alginate as a carrier-in reducing the $H_2S$ from chicken manure. On the basis of 16S rRNA phylogenetic analysis, isolate AH18 was identified as Pseudomonas sp., whereas isolates AH25 and AH28 were identified as Achromobacter sp. The most active deodorizing isolate was AH18, with an $H_2S$ reduction rate of 74.7% (p < 0.05). Meanwhile, the reduction rates for isolates AH25 and AH28 were 54.2% and 60.8% (p > 0.05), respectively. However, the $H_2S$ removal performance was enhanced in the mixed culture, with a reduction rate of 81.9% (p < 0.05). In conclusion, the three potential SOB isolates were capable of reducing the $H_2S$ from chicken manure in the form of a pure culture immobilized on alginate, and the reduction performance was enhanced in the mixed culture.

• 한국농촌건축학회논문집
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• 제14권4호
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• pp.97-105
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• 2012

Winsborough Hall built by Martin L. Winehart who was the missionary of the Presbyterian Church of America in 1927 was built by Mrs. Winsborough's birthday contribution. Winsborough Hall was clearly divided into the original form built in 1927 and remodelled form by extension. Most of walls were constructed with several kinds of bricks for both sides and opening in the original form and remodelled form. Each room divided by inner wall was kept with original form because it is difficult to remodel it on the characteristics of building. But, it was confirmed through the related literatures that security of opening at some rooms and annexation of rooms through removal of the wall on the 2nd floor which was relatively easy to transform wall compared to the first floor were made. Variability of the wall affected the truss structure of roof and it created rare double truss structure. Architectural value of Winsborough Hall was in its first architectural trial using red brick in Gwangju region since 1920s. It suggested that it was differential architectural trial from Korean-Western mixed building constructed by the missionaries from 1940 to 1910 and buildings made of gray bricks prevailed from 1911 to 1920 and it showed the advancement in the architectural structure and materials.

• 콘크리트학회논문집
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• 제13권6호
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• pp.629-636
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• 2001

최근 철근콘크리트 골조 구조물에 대한 장기변형 특성을 고려하여 고층건물의 설계 및 시공에 적용하려는 연구가 활발하게 진행되고 있다. 그러나 기존의 연구에서 고려하고 있는 시공단계는 reshoring을 고려하지 못하고 거푸집제거 및 shoring을 한 단계로 고려하기 때문에 동바리를 제거하기전의 초기재령에서 발생하는 변형을 고려하지 못한다. 본 연구에서는 동바리의 설치/제거를 포함한 실제적인 시공과정을 고려하여 거푸집의 강성, 동바리의 강성 그리고 시간에 따른 콘크리트의 강성의 변화에 따른 축력변화를 예측할 수 있는 2차원 골조해석 프로그램을 개발하였다. 예제해석결과 동바리의 축력이 시간에 따라서 감소한다. 또한, 동바리의 개수와 상관없이 기둥과 동바리와의 축력 재분배에 의해서 외측기둥에는 실제 설계 값보다 비탄성 하중이 작게 작용하고 내측 기둥에서는 크게 나타난다. 한편, 프로그램의 타당성을 검증하기 위하여 실제 철근콘크리트 골조 구조물을 타설-거푸집 제거-reshoring-동바리 제거-부가하중작용과 같은 일반적인 시공순서에 따라서 제작하였다. 실험결과 동바리를 제거하기 전에 기둥에 변형이 발생하며 동바리의 축력이 기둥에 분배되었다. 따라서 개발된 해석프로그램은 실험결과를 비교적 잘 예측하였다.