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Characterization of Alumina Doped with Lanthanum and Pluronic P123 via Sol-Gel Process (고분자 P123와 란탄이 도핑된 알루미나의 특성 연구)

  • Jung, Mie-Won;Lee, Mi-Hoe
    • Journal of the Korean Ceramic Society
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    • v.45 no.5
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    • pp.297-302
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    • 2008
  • To direct the evolution of nanostructure and immobilize ${\gamma}-Al_2O_3$ catalyst, nanocrystalline La-doped-$Al_2O_3$ powder were prepared by the sol-gel process with addition of an amphiphilic block copolymer template (pluronic P123: $(poly(ethyleneoxide)_{20}-poly(propyleneoxide)_{70}-poly(ethyleneoxide)_{20})$. The dried gel is amorphous, whereas heating at temperature above $700^{\circ}C$ leads to the formation of nanocrystalline ${\gamma}$ and ${\delta}-Al_2O_3$ and these two phases is kept until $1100^{\circ}C$. ${\alpha}-A1_2O_3 $starts to form at $1200^{\circ}C$ with $LaAl_{11}O_{18}$. The surface morphology and crystal structure has been observed by field emission scanning electron microscope (FE-SEM) and X-ray diffraction (XRD). Solid state $^{27}Al$ MAS NMR indicates two types of local environment, i.e. octahedral and tetrahedral sites. The surface area and pore size was compared among these powders using the BET nitrogen adsorption measurements.

Fuzzy Measures to Control Video Bit-rate in the DCT Domain (동영상 대역폭 조절을 위한 DCT 영역의 퍼지 측정값)

  • Kim Tae-Yong
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.43 no.4 s.310
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    • pp.113-122
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    • 2006
  • In this paper, we propose a fuzzy method to control bit-rate in the DCT Domain. The method consists of a bit-rate allocation with fuzzy measures and a least-distortion bit-rate reduction. Fuzzy measures are calculated by the code length, the discontinuity ambiguity, and the neighborhood momentum in each DCT block. These measures are summed with weights and form a reduction fuzziness to indicate the degree of preferable reduction. Using the reduction fuzziness. each DCT block is filtered by the least-distortion reduction method to adjust the bit-rate for the target bandwidth. In the experiment, we show the results that the transcoded video quality by the method is better and the bandwidth is more regular than those of existing methods in both visually and quantitatively.

The Crystal and Molecular Structure of Sulfapyridine

  • Koo, Chung-Hoe;Lee, Young-Ja
    • Archives of Pharmacal Research
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    • v.2 no.2
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    • pp.99-110
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    • 1979
  • The crystal structure of sulfapyridine, $C_{11}H_{11}N_{3}O_{2}S$, has been determined by X-ray diffraction method. The compound crystallizees in the monoclinic space group C2/c with a = 12, 80(4), b= 11.72(4), $c= 15.36(5){\AA}, {\beta}= 94(3)^{\circ}$and Z = 8. A total of 1133 observed reflections were collected by the Weissenberg method with CuKaradiation. Structure was solved by the heavy atom method and refined by isostropic block-diagonal least-squares method to the R value of 0.14. The nitrogen in the pyridine ring of sulfapyridine is associated with an extra-annular hydrogen. The C (benzene ring) S-N-C (pyridine ring) group adopts the gauche form with a fonformational angle of $71^{\circ}$. The benzene ring are inclined at angle of $84^{\circ}.to the pyridine ring plane. Sulfapyridine shows three different hydrogen bonding in the crystal. They are two N-H...O hydrogen bonds with the distance of 2.90 and 2.98${\AA}$ respectively, and on N-H...N with the distance of 3.06 ${\AA}$.

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A Study on the Production Conditions of Circular Knit of Domestic Women's Apparel Industry (국내 여성복 업체의 환편니트 제품 생산현황 조사)

  • Oh, Ji-Yeong
    • Fashion & Textile Research Journal
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    • v.18 no.5
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    • pp.637-646
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    • 2016
  • The goal of this study is to provide basic data on developing circular knit basic pattern for women in their 20's. Production conditions of circular knit product pattern making among domestic women's apparel industry was researched, and collected data on sizes and ease amounts from woven and circular knit pattern were compared and analyzed. According to the result of the survey, product measurements adjusted to the actual body size fit for the brand's image were used, and the common problem among manufacturers and consumers regarding circular knit products turned out to be change in size and form due to stretching. For the basic pattern of circular knit, stretching quality was reflected in the woven basic pattern based on plain stitch(single knit) and then dart was removed and ease amount was reduced. The result of looking into size and ease amount about woven and circular knit torso & sleeve block shows that there is a significant difference among chest circumference, hip circumference, bi-shoulder length, interscye back, interscye front, scye depth, upper arm circumference and wrist circumference, and it was clear that circumference and width on the areas around the wrist tended to fit around the body more when circular knit was used instead of woven fabric.

Novel Approach for Eliminating BER Irreducible Floor in the Enhanced Blind Cyclic Detection for Space-Time Coding

  • Pham, Van-Su;Le, Minh-Tuan;Mai, Linh;Kabir, S.M.Humayun;Yoon, Gi-Wan
    • Journal of information and communication convergence engineering
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    • v.6 no.2
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    • pp.150-153
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    • 2008
  • In the blind Maximum-likelihood (ML) detection for Orthogonal Space-Time Block Codes (OSTBC), the problem of ambiguity in determining the symbols has been a great concern. A possible solution to this problem is to apply semi-blind ML detection, i.e. the blind ML decoding with pilot symbols or training sequence. In order to increase the performance, the number of pilot symbols or length of training sequence should be increased. Unfortunately, this leads to a significantly decrease in system spectral efficiency. This work presents an approach to resolve the aforementioned issue by introducing a new method for constructing transmitted information symbols, in which transmitting information symbols drawn form different modulation constellations. Therefore, the ambiguity can be easily eliminated. In addition, computer simulation is implemented to verify the performance of the proposed approach.

Effective Vitalization Plan of Electronic Cash using Bitcoin (비트코인을 활용한 효율적 전자화폐 활성화 방안)

  • Lee, Jun Hyung;Lee, Seong Hun;Lee, Do Eun;Kim, Woo Cheol;Kim, Minsu
    • Convergence Security Journal
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    • v.16 no.4
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    • pp.79-90
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    • 2016
  • It is current status that currently-used 'electronic cash' cannot go beyond the physically and commonly-used as it is used by digitalizing the existing commodity money. Especially in case of bitcoin, though it is issued only by the activity called 'mining' without the issuing body and used in some countries in relatively-active way as it is admitted as the currency in the way that proves the transaction through 'BlockChain' in the form of P2P for the transaction among the individuals, it has several issues due to the characteristics it has. So, this research is willing to suggest the alternative plan to matter of policy, managerial and technical problems regarding the vitalization plan of bitcoin.

The crystal and molecular structure of chlorpropamide

  • Koo, Chung-Hoe;Cho, Sung-Il;Yeon, Young-Hee
    • Archives of Pharmacal Research
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    • v.3 no.1
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    • pp.37-49
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    • 1980
  • Chlorpropamide, $C_{10}H_{13}N_{2}O_{3}SCI$, forms orthofombic crystals of space group $P_{2}_{ 1}2_{1}2_{1}$ with a 9.066 $\pm$ 0.004, b = 5.218 $\pm$ 0.003, c = 26, 604 $\pm$, 0.008 $\AA$, and four molecules per cell. Three dimensional photographic data were collected with Mo-K$\alpha$ radiation. The structure was determined using Patterson, Fourier and Difference syntheses methods and refined by the block-diagonal least-squares methods with anisotropic thermal parameters for all nonhydrogen atoms and isotropic thermal parameters for all hydrogen atomes. The final R value was 0.10 for the 1823 observed independent reflections. The dihedral angle between the planes through the benzene ring and the urea goup is 99$^{\circ}$. The conformational angle formed by the projection of the S-C(1) with that of N(1)-C(7) when the projection is taken along the S-N(1) bond is 76$^{\circ}$. The molecule appears to form with neighbouring molecules two hydrogen bonds, N(1)..H...O(3) and N(2)-H...0(2) of lengths 2.774 and 2.954$\AA$ respectively related by screw diads parallel to the a axis. Adjacent molecules parallel to b and c axis are bound together by van der Wasls forces.

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Preparation and Reconstitution of Core-shell Type Nanoparticles of Poly(ε -caprolactone)/Poly(ethyleneglycol)/Poly(ε -caprolactone) Triblock Copolymers

  • Jeong, Young-Il;Ryu, Jae-Gon;Kim, Young-Hoon;Kim, Sung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.872-879
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    • 2002
  • One of the improtant characteristics of core-shell type nanoparticles is the long-term storage and reuse as an aqueous injection solution when required. For this reason, reconstruction of lyophilized core-shell type nanoparticles is considered to be essential . BAB type triblock copolymers differ from AB type diblock copolymers, which contain the A block as a hydrophilic part and the B block as a hydrophobic part. by not being easily redistributed into phosphate-buffered saline (PBS, pH 7.4, 0.1 M). Therefore, lyophilized core-shell type nanoparticles of CEC triblock copolymer were reconstituted using a somication process with a bar-type sonicator in combination with a freezing-thawing process. Soncation for 30s only resuspended CEC nanoparticles in PBS; their particle size distribution showed a monomodal pattern with narrow size distribution. The bimodal size distribution pattern and the aggregates were reduced by further sonication for 120 s but these nanoparticles showed a wide size distribution. The initial burst of drug release was increased by reconstitution process. The reconstitution of CEC core-shell type nanoparticles by freezing-thawing resulted in trimodal distribution pattern and formed aggregates, although freezing-thawing process was easier than sonication . Drug release form CEC nanoparticles prepared by freezing-thawing was slower than from the original dialysis solution. Although core-shell typenanoparticles of CEC triblock copolymers were not easily performed. Cytotoxicity testing of core-shell type nanoparticles of CEC-2 triblock copolymers containing clonazepam (CNZ) was performed using L929 cells. Cytotoxicity of CNZ was decreased by incorporation into nanoparticles.

The Study on Traditional Housing Space in Inchon - focus on traditional housing in Pupyng Area after 1900s - (인천지역(仁川地域) 전통주거(傳統住居)의 공간구조(空間構造)에 관한 조사(調査)·연구(硏究) - 1900년대(年代) 이후에 건축(建築)된 부평지역(富平地域)의 전통가옥(傳統家屋)을 중심(中心)으로 -)

  • Hong, Se Pyo
    • Journal of architectural history
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    • v.4 no.1
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    • pp.71-78
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    • 1995
  • This study aims 1) to estimate the form of living house of pre-urbanization of Inchon, and 2) to ensure originality of to be achieve urban plan and living space plan which is base on local character by 3) arranging changed character of living space through the urbanization sequence by invest of house in natural village at Pupyung. The character of arranging living space of house at Pupyung is placing Sarang-chae(husband's block of house) instead of making another Haenrang-chae (visitor's block of house) and Sarang-chae is attach importance to Man's living space but today, have disappearing the uses of Sarang-bang (husband's living space) because by Man lives An-bang(originally woman's space). The character of plan is arranging room in both side of Maru(wooden living floor) in spite of different structure, and the uses of plan or room is changing to fit to purpose of according to environment of living. Generally, the structure is made by natural stone and cubed column, and used smaller member cause by rare wood material.

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Targeted Drug Delivery Carriers Using Folate Conjugated Poly((R)-3-hydroxy butyrate)-Poly(ethylene glycol) Nanoparticles (Folate가 수식된 Poly((R)-3-hydroxy butyrate)-Poly(ethylene glycol) 나노입자를 이용한 표적지향형 약물전달체)

  • Kwon, Seung-Ho;Kim, Young-Jin
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.515-519
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    • 2009
  • Biodegradable poly((R)-3-hydroxy butyrate) and poly(ethylene glycol) was conjugated to make amphiphilic di-block copolymer. Folate was conjugated at di-block copolymer to target the cancer cells. Copolymer was ready to form the self-assembled micelle whose size was 125~156 nm in aqueous solution. Griseofulvin as a hydrophobic drug was loaded in nanoparticles. Their loading efficiencies were 35~56%. Hydrophobic drug was continuously released for 24 h. Cell viability test showed that folate attached particles were 10% more efficient than the particles without targeting ligands.