• Title/Summary/Keyword: foaming properties.

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Preparation and Antifoaming Properties of Long Chain Fatty Acid Methyl Esters (고급지방산 메틸 에스테르류의 합성 및 소포특성)

  • Park, Jong-Kwon;Kim, A-Ram;Hwang, Jun-Bae;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.72-77
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    • 2015
  • In this study, anti-foaming agents of a fatty acid methyl esters was synthesized and confirmed by FT-IR and $^1H-NMR$ spectroscopy. Synthesized material of characteristic of -C=O group having a $1740cm^{-1}$ and -C-O group $1175cm^{-1}$ peak by using FT-IR, and it was confirmed that k. Surface tensions were measured by surface tensiometer CBVP-43. Their surface tension values was 17.7 to 21 dyne/cm. Anti-foaming abilities in the SLS solution was measured through the Ross-Miles method. Performance of the 4 type of anti-foaming agent was determined and the best anti-foaming agent was prepared using stearic acid methyl.

A Foaming Ceramics for Insulation of Building Equipment (건축설비의 단열 보온을 위한 발포세라믹 개발)

  • Lee, Ju-Young;Song, Young-Hwan;Shin, Hae-Jong;Choi, Jae-Ho;Jang, Sung-Cheol;Yun, Kang-Ro;Lee, Yong-Hee
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.369-374
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    • 2008
  • This study is an inorganic foaming ceramic by sol-gel reaction in order to overcome weak point of insulator using in construction equipment. We shall be able to confirm as the existing product substitute is possible result of this study. The solution where the silicate, the ceramic powder and the additive are included which makes foaming ceramic slurry, then the insulator made by used $CO_2$ Sol-Gel reaction. There being will be able to manufacture the insulator where the economical efficiency is excellent confirmed at the start product which is completed. The recording gel time decreases when the silicate will increase. Uses the hydrogen peroxide and fe make foam, when additionally surface preparation the fluorine resin, the water tolerance increases and will be able to complement the weak point of the silicate which omits in the water. The case which will use the loess powder with the research method which sees specially was environment-friendly product and according to appearing, the physical properties of nonflammability.

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Effect of Surfactant and Anti-foaming Agent on the Properties of Silicone Rubber Impression Material (계면활성제와 소포제가 실리콘 고무인상재의 물성에 미치는 영향)

  • Kim, Kyoung-Nam;Cho, Lee-Ra;Oh, Young-Il;Kang, Seung-Kyung;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.102-110
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    • 2001
  • The three types of surfactants such as nonylphenoxy poly(ethylene) ethanol homologues, caster oil poly(ethylene) ethanol homologues, and sodium perfluoroalkyl carboxylates are used to improve the wettability of rubber impression material. Among the surfactants, the usage of sodium perfluoroalkyl carboxylates containing fluoro group resulted in the lowest surface energy of impression material and the result gave the positive effect on the wettability of rubber impression material to teeth. Also, the anti-foaming agents were used to reduce or remove the hydrogen gas generating on the impression material by reaction. In the case of rubber impression material containing sodium perfluoroalkyl carboxylate as a surfactant, it was found that the tear strength of rubber impression material increased over 3 N/mm with the addition of anti-forming agent. Therefore, the anti-foaming agent could contribute to the mechanical property of rubber impression material without the change of surface property.

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An Experimental Study on the Development of Lightweight Foamed Concrete as Sandwich Panel Core (샌드위치 패널 심재용 경량기포콘크리트 개발에 관한 실험적 연구)

  • Lee, Sang-An;Chun, Woo-Young;Ko, Kwan-Ho;Kim, Wha-Jung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.557-560
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    • 2008
  • This was done by analyzing the sandwich panels that are now widely used in construction work. Sandwich panels are used for diverse purposes in construction work worldwide. In Korea, polystyrene panels that have organic materials as their core material are used. These panels are thus very vulnerable to fire, with risks of core melting, sheet deformation, and hazardous gases. Accordingly, sandwich panels' fire-resistant or non-flammable properties must be secured. To solve these problems, the optimal mixing proportion of lightweight foamed concrete for the sandwich panel core was determined. A new method of doing this was introduced that is completely different from the existing method, wherein a foaming agent is added to realize lightweight concrete. For lightweight concrete, the foaming mechanisms via diverse chemical reactions were identified, H$_2$O$_2$ was added for heating in the reaction, and the concrete foaming was maximized. Through diverse experiments to determine the optimal mixing proportion of lightweight foamed concrete and to examine the filling characteristic of lightweight foamed concrete for sandwich panel cores using waste materials, the physical and mechanical properties of lightweight foamed concrete were examined.

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A Comparison Study on Functional Properties of Mungbean Protein and Chemically Modified Mungbean Protein (분리 녹두 단백질과 이를 화학적으로 수식화한 단백질간의 식품학적 기능성 비교)

  • Sohn, Kyung-Hee;Min, Sung-Hee;Park, Hyun-Kyung;Park, Jin
    • Korean journal of food and cookery science
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    • v.7 no.3
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    • pp.53-59
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    • 1991
  • This study was carried out in order to investigate the change of protein functionalities such as foaming and emulsifying properties by succinylation of protein isolates. Succinylated and unsuccinylated munghean protein isolates were tested for finding out the effects of pH, heat treatment and sodium chloride concentration on the solubility, emulsion capacity, emulsion stability, foaming capacity, and foam stability. The results are summarized as follows: 1. Succinylation enhanced the solubility of MPI except at pH 4.5. When heated, succinylation greatly increased the solubility of succinylated MPI above $60^{\circ}C$. With the addition of NaCl, succinylation increased the solubility of MPI at acidic condition. 2. Emulsion capacity of succinylated MPI showed the lowest value at pH 7 and higher values at acidic and alkaine condition. when succinylated MPI was heated, emulsion capacity showed the highest at $80^{\circ}C$. With NaCl was added, emulsion capacity of succinylated MPI lincreased at pH 7, 9 or 11 decreased at pH 3 except addition of 1.0M NaCl. 3. Emulsion stability of MPI and succinylated MPI showed the highest at pH 4.5. Succinylation enhanced the emulsion stability of MPI at acidic condition. 4. The foaming capacity of MPI was increased at pH 3, 7 or 9 by succinylation. 5. When heated, foam stability of MPI and succinylated MPI showed the highest at pH 4.5 and at pH 11, respectively. When heated, both proteins showed the highest stability at $100^{\circ}C$.

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Effect of Waste Ground Tire Rubber on Flame Retardancy and Foaming Properties of the NBR foams (폐타이어 고무분말(GTR)이 니트릴고무(NBR) 발포체의 난연 및 발포 특성에 미치는 영향)

  • Moon, Sung-Chul;Lee, Jae-Chul;Choi, Jae-Kon;Jo, Byung-Wook
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.251-261
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    • 2003
  • The flame retardancy and foaming properties of NBR foams containing waste ground tire rubber (GTR) were studied. When the composition ratios of NBR/GTR were ranged in $100/0{\sim}80/20$ (w/w) and rubbers/flame retardants were in the range of $1/1.95{\sim}3.70 wt%$, the considerably optimized foam for flame retardancy was obtained with high limiting oxygen indices (LOI, $29.4{\sim}40.0$), low heat release rate(HRR), closed/semi-closed cell of uniformity, and reasonable expandability ($215{\sim}300 %$). The LOI was increased and the heat release rate was decreased with increasing the amount of GTR content.

Synthesis and Properties of Anionic Surfactants Using Sarcosine and Taurine (사코진과 타우린을 이용한 음이온 계면활성제의 합성 및 물성)

  • Cho, Jung-Eun;Shin, Hye-Rin;Jeong, Noh-Hee
    • Applied Chemistry for Engineering
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    • v.30 no.1
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    • pp.102-107
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    • 2019
  • Anionic surfactants were synthesized by using an sarcosine, taurine and fatty alcohol with varying the carbon chain length. The structure of synthesized surfactants was confirmed by $^1H$ NMR analysis. The critical micelle concentration of the synthetic anionic surfactant was $10^{-2}{\sim}10^{-4}mol/L$ and the surface tension value at the critical micelle concentration was between 21 and 39 mN/m. It was confirmed by the Ross-Miles method that the synthetic surfactant with the carbon chain of 12 showed a good foaming power and stability. In addition, the surfactant using the sacosine was found to have a good affinity in soybean oil while that using taurine in benzene. The physical properties of synthesized surfactants were determined by measuring the critical micelle concentration, foaming power and emulsifying stability.

Engineering Properties of Lightweight Foaming Grouting Materials for Underground Cavities (지반 공동의 충진을 위한 발포성 경량그라우트재의 공학적 특성)

  • Han, WooJin;Lee, Jong-Sub;Byun, Yong-Hoon
    • Journal of the Korean GEO-environmental Society
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    • v.19 no.2
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    • pp.5-12
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    • 2018
  • Underground cavities could induce road subsidence, which have been frequently observed in urban areas. Therefore, adequate backfilling materials and the restoring methods of the cavities are required to prevent the road subsidence. The objective of this paper is to evaluate the suitability of backfilling methods using foaming lightweight grouting materials considering the flow values, unit weights, and air contents at slurry and expanded states, and unconfined compressive strengths. The grouting materials consist of water, cement, and foaming agent whose proportions of water, cement, and foaming agent are 25: 25: 1.0 and 25: 25: 1.2. The flow values of the two materials are greater than 200 mm, and their unconfined compressive strengths at 28 days age are smaller than 1.3 MPa. From the results, the two proportions of materials are expected to be effectively used as a backfilling material. However, the material components should be carefully mixed because poor mix of these materials could induce non-homogeneous distribution of air bubbles. The unexpectedly non-homogeneous distribution of air bubbles may induce significant cracks or additional cavities.

Mechanical Performance Evaluation of Cement Paste with Foaming Agent using FEM Analysis Based on Picture Image (화상 이미지 기반 FEM 해석을 이용한 기포제 혼입 시멘트 페이스트의 역학 성능 평가)

  • Kim, Bo-Seok;Shin, Jun-Ho;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.35-43
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    • 2016
  • Concrete is a representative heterogeneous material and mechanical properties of concrete are influenced by various factors. Due to the fact that pores in concrete affect determining compressive strength of concrete, studies which deal with distribution and magnitudes of pores are very important. That way, studies using picture imaging have been emerged. Studies on mechanical performance evaluation of structural lightweight foamed concrete and FEM analysis based on picture image are inadequate because lightweight foamed concrete has been researched for only non-structural. Therefore, in this study, cement paste with foaming agent to evaluate mechanical performance is made, FEM analysis with picture image is conducted and young's modulus of experiment and analysis are compared. In this study, dosage of foaming agent is determined 7 level to check pore distribution and water-binder ratio is determined 20% to progress research about structural light weight foamed concrete. Weight of unit volume is minimum at 0.8% of foaming agent dosage. However, weight of unit volume is increased over 0.8% of foaming agent dosage because of interconnection with independent pores. For FEM analysis, cement paste is photographed to use image analyzer(HF-MA C01). Consequently, the fact that Young's Modulus of experiment and FEM analysis are same is drawn by using OOF(Object Oriented Finite elements).

Synthesis and Properties of Glycidyl Succinate Type Cationic Gemini Surfactant (2-메틸숙신산을 이용한 에스테르계 제미니 양이온 계면활성제의 합성 및 물성)

  • Park, Jong-Kwon;Kim, Won-Kyun;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.312-319
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    • 2013
  • This study is to do with the synthesis of glycidyl succinate cationic gemini surfactant. The gemini surfactant was synthesized with using 2-methyl disodium succinate, epichlorohydrine and N,N-dimethyl dodecyl amine. The target material was confirmed by FT-IR, $^1H$-NMR and was tested their properties. Surface active properties such as surface tension, evaluated cmc, emulsing properties, foaming properties were measured respectively at given conditions. The surface tensions for the aqueous solution of gemini surfactant were 33~34 dyne/cm and their cmc values evaluated by surface tension method were $10^{-4}{\sim}10^{-3}mol/L$. Emulsing properties of gemini surfactant was better in organic solvent and foaming power was confirmed good stability.