• Title/Summary/Keyword: foam process

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Foaming Characteristics and Physical Properties of Ethylene Vinyl Acetate Copolymer Foams (Ethylene Vinyl Acetate Copolymer 발포체의 발포특성 및 물리적 특성)

  • Kim, Jin-Tae;Son, Woo-Jung;Ahn, Byung-Hyun;Kim, Won-Ho
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.52-60
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    • 2001
  • Physical properties of foams depend on the density of foams, Physical properties of base polymers, open ceil contents, and cell structures including the size, size distribution, shape of ceil and the thickness of membrane and strut. The density of foam is affected by raw materials, concentration oi crosslinking agent and blowing agent and process parameters such as processing technique and condition. Ethylene vinyl acetate copolymer(EVA) foam is a crosslinked cellular material. The foaming characteristics and physical properties of EVA foam are affected by decomposition rate of blowing agent. In this study, the decomposition rate of blowing agent and crosslinking rate, foaming characteristics and physical properties of foams were evaluated. The slow decomposition rate of blowing agent results in low density foam, good shock absorption property and uniform cell size distribution compared to the high decomposition rate of blowing agent.

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Fabrication and Characterization of Porous TCP coated Al2O3 Scaffold by Polymeric Sponge Method

  • Sarkar, Swapan Kumar;Kim, Young-Hee;Kim, Min-Sung;Min, Young-Ki;Yang, Hun-Mo;Song, Ho-Yeon;Lee, Byong-Taek
    • Journal of the Korean Ceramic Society
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    • v.45 no.10
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    • pp.579-583
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    • 2008
  • A porous $Al_2O_3$, scaffold coated with tricalcium phosphate(TCP) was fabricated by replica method using polyurethane(PU) foam as a fugitive material. Successive coatings of $Al_2O_3$ and hydroxyapatite(HAp) were applied via dip coating onto polyurethane foam, which has a slender and well interconnected network. A porous structure was obtained after sequentially burning out the foam and then sintering at $1500^{\circ}C$. The HAp phase was changed to TCP phase at high temperature. The scaffold showed excellent interconnected porosity with pore sizes ranging from $300{\sim}700{\mu}m$ in diameter. The inherent well interconnected structural feature of PU foam remained intact in the fabricated porous scaffold, where the PU foam material was entirely replaced by $Al_2O_3$ and TCP through a consecutive layering process. Thickness of the $Al_2O_3$ base and the TCP coating was about $7{\sim}10{\mu}m$ each. The TCP coating was homogeneously dispersed on the surface of the $Al_2O_3$ scaffold.

Influence of Rheological Properties of Lightweight Foamed Concrete on Preventing Foam Collapse (경량 기포 콘크리트의 레올로지 특성이 소포억제에 미치는 영향)

  • Lee, Hyang-Sun;Jeon, Jong-Woon;Jo, Mujin;Kee, Seong-Hoon;Han, Dongyeop
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.304-310
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    • 2018
  • The aim of the research is to provide possibility of quality controlling by rheological properties for lightweight foamed concrete. The lightweight foamed concrete achieves its low density by containing air bubbles (foam) produced during the mixing process. Therefore, containing foamed volume during setting period is critical for the securing the performance as an insulating material. In this research, regarding foam collapse during the setting period, rheolgocial properties of fresh state lightweight foamed concrete were assessed to get its relationship with volume stability, or foam stability. For the experiment regarding foaming factors including mixing time, mix design of contents for materials, rheological properties of fresh state lightweight foamed concrete were tested with its density and settling depth. Based on the settling depth with various factors, relationship with rheological properties was analyzed, and especially, close relationship of plastic viscosity and settling depth was found. Therefore, from the results of this research, it is considered to contribute on suggesting a new approach of quality controlling for lightweight foamed concrete using rheological test method.

Materal properties of Porous BCP Scaffolds depending on the process conditions

  • Park, Lee-Ho;Kim, Min-Seong;Min, Yeong-Gi;Song, Ho-Yeon;Lee, Byeong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.44.2-44.2
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    • 2009
  • BCP powder was synthesized using microwave hydrothermal process with mixed calcium hydroxide and phosphoric acid. After using replica method, porous BCP scaffold was fabricated. PU (Poly Urethane) was used as the fugitive skeleton to fabricate the porous scaffold. BCP powder was mixed in PVB (Polyvinyl butyral) and ethanol solution and then applied to the PU foam by dip coating. After several times of coating and the subsequent oven drying the coated PU foam was burnt out at $750^{\circ}C$ at air to remove the PU. The resulting networked porous composites were sintered at $1250^{\circ}C$, $1300^{\circ}C$ and $1350^{\circ}C$ in microwave furnace for 30 minutes. Material properties of the porous bodies like compressive strength and porosity were investigated. Detailed microstructure of the BCP porous body was characterized by SEM and XRD and TEM techniques. In our experiments, the relationship between mechanical property and viscosity of powder, sintering temperature was investigated.

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3D Casing-Distributor Analysis for Hydraulic Design Application

  • Devals, Christophe;Zhang, Ying;Dompierre, Julien;Vu, Thi C.;Mangani, Luca;Guibault, Francois
    • International Journal of Fluid Machinery and Systems
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    • v.8 no.3
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    • pp.142-154
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    • 2015
  • Nowadays, computational fluid dynamics is commonly used by design engineers to evaluate and compare losses in hydraulic components as it is less expensive and less time consuming than model tests. For that purpose, an automatic tool for casing and distributor analysis will be presented in this paper. An in-house mesh generator and a Reynolds Averaged Navier-Stokes equation solver using the standard $k-{\omega}$ shear stress transport (SST) turbulence model will be used to perform all computations. Two solvers based on the C++ OpenFOAM library will be used and compared to a commercial solver. The performance of the new fully coupled block solver developed by the University of Lucerne and Andritz will be compared to the standard 1.6ext segregated simpleFoam solver and to a commercial solver. In this study, relative comparisons of different geometries of casing and distributor will be performed. The present study is thus aimed at validating the block solver and the tool chain and providing design engineers with a faster and more reliable analysis tool that can be integrated into their design process.

Effect of pH on Successive Foam and Sonic Droplet Fractionation of a Bromelain-invertase Mixture

  • Ko Samuel;Prokop Ales;Tanner Robert D.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.26-30
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    • 2002
  • A droplet fractionation method was previously developed to concentrate a dilute nonfoaming protein solution. In that earlier study with invertase, it was demonstrated that droplets created by ultrasonic energy waves could be enriched up to 8 times that of the initial dilute invertase solution. In this study, a mixture of bromelain (a foaming protein) and invertase (a nonfoaming protein) is investigated as a preliminary step to determine if droplet fractionation can also be used to separate a non-foaming protein from foaming proteins. The foaming mixture containing bromelain is first removed by bubbling the binary mixture with air. After the foam is removed, the protein rich air-water interfacial layer is skimmed off (prior to droplet fractionation) so as not to interfere with the subsequent droplet production from the remaining bulk liquid, rich in non-foaming protein. Finally, sonic energy waves are then applied to this residual bulk liquid to recover droplets containing the non-foaming protein, presumed to be invertase. The primary control variable used in this droplet fractionation process is the pH, which ranged for separate experiments between 2 and 9. It was observed that the maximum overall protein partition coefficients of 5 and 4 were achieved at pH 2 and 4, respectively, for the initial foaming experiment followed by the post foaming droplet fractionation experiment.

Effects of Irradiation Crosslinking and Molecular Weight Properties on Crosslinked PP Foaming Process (전자선 조사량과 분자량 특성이 전자선 가교 PP 발포 가공에 미치는 영향)

  • 홍다윗;윤광중;백운선;정영헌;이준길
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.508-515
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    • 2002
  • The effects of the crosslinking caused by irradiation dose, molecular weights of the foaming materials, and various foaming processes on the foam structure of the polypropylene (PP) were investigated. The maximum gel content of the PP was 48% when the sheet was irradiated with 3.2 Mrad. This high gel content improved the cell structures by providing high thermal stability. The increase of both the gel content and structural development were stopped at the irradiation dose exceeding 3.2 Mrad. The increase of the molecular weights served to help produce a foam with particularly fine and even cell structures, along with improved thermal stability as well.

Nanowire-Like Copper Oxide Grown on Porous Copper, a Promising Anode Material for Lithium-Ion Battery

  • Park, Hyeji;Lee, Sukyung;Jo, Minsang;Park, Sanghyuk;Kwon, Kyungjung;Shobana, M.K.;Choe, Heeman
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.438-442
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    • 2017
  • This paper reports the facile synthesis of microlamella-structured porous copper (Cu)-oxide-based electrode and its potential application as an advanced anode material for lithium-ion batteries (LIBs). Nanowire-like Cu oxide, which is created by a simple thermal oxidation process, is radially and uniformly formed on the entire surface of Cu foam that has been fabricated using a combination of water-based slurry freezing and sintering (freeze casting). Compared to the Cu foil with a Cu oxide layer grown under the same processing conditions, the Cu foam anode with 63% porosity exhibits over twice as much capacity as the Cu foil (264.2 vs. 131.1 mAh/g at 0.2 C), confirming its potential for use as an anode electrode for LIBs.

Effect of core shape on debonding failure of composite sandwich panels with foam-filled corrugated core

  • Malekinejadbahabadi, Hossein;Farrokhabadi, Amin;Rahimi, Gholam H;Nazerigivi, Amin
    • Steel and Composite Structures
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    • v.45 no.3
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    • pp.467-482
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    • 2022
  • One of the major failure modes in composite sandwich structures is the separation between skins and core. In this study, the effect of employing foam filled composite corrugated core on the skin/core debonding (resistance to separation between skin and core) is investigated both experimentally and numerically. To this aim, triangular corrugated core specimens are manufactured and compared with reference specimens only made of PVC foam core in terms of skin/core debonding under bending loading. The corrugated composite laminates are fabricated using the hand layup method. Also, the Vacuumed Infusion Process (VIP) is employed to join the skins to the core with greater quality. Utilizing an End Notched Shear (ENS) fixture, three point bending tests are performed on the manufactured sandwich composite panels. The results reveal that the resistance to separation capacity and flexural stiffness of sandwich composite has been increased about 170% and 76%, respectively by using a triangular corrugated core. The Cohesive Zone Model (CZM) with appropriate cohesive law in ABAQUS finite element software is used to model the progressive face/core interfaces debonding the difference between experimental and numerical results in predicting the maximum born load before the skin/core separation is about 6 % in simple core specimens and 3% in triangular corrugated core specimens.

A Case of Workers' Exposure Reductions for Chemicals in a Polyurethane Pad Process through the Substitution of Raw Materials (폴리우레탄 패드 공정에서의 원료물질 대체에 따른 근로자 노출저감 사례)

  • Jang, Jae-Kil;Park, Hyunhee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.3
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    • pp.281-292
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    • 2014
  • Objectives: The aim of this case study is to verify the chemical exposure reductions for various chemicals by substituting the ingredients of raw materials in a polyurethane(PU) foaming industry. The PU foaming process was making various passenger car seats from chemicals such as toluene diisocinate(TDI), methylene bisphenyl isocyanate(MDI) and polyols. Methods: Basic process data and workers' health effects could be gathered by interviewing managers and reviewing previous exposure monitoring data. Amine, aldehyde and isocyanate chemicals were analyzed following the NIOSH-NMAM. Area sampling methods rather than personal sampling were introduced for this field investigation. Results: Two amines, triethylene diamine(TEDA) and N,N,N',N'-Tetramethyl-1,6- hexanediamine(TMHDA) were identified in raw polyol, cured PU foam and air. The average concentrations of TEDA and TMHDA showd less than 1 ppm by area sampling; however, that caused halovision among workers in PU-PAD process. Aldehydes and isocyanates were detected in the air while the concentrations were relatively low compare to occupational exposure limits. Successful raw material substitution from nonreactive amine to reactive amine could reduces air-borne amine and aldehyde levels by about 70%. Halovision had been disappeared successfully in the process. Conclusions: Several amines caused halovision among workers in PU-PAD process, especially during summer season in spite of relatively low levels. Combination of reactive amines into urethane foam could reduced vapor generation into air, which resulted in the elimination of eye troubles in the process.