• Title/Summary/Keyword: fly ash

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Effects of Gwaruhaengryeon-hwan on COPD and Particulate Matter Induced Lung Injury on a Mouse Model (만성폐쇄성폐질환 및 미세먼지 유발 폐손상 동물모델에서 과루행련환의 효과)

  • Lee, Chul-wha;Yang, Won-kyung;Lyu, Yee-ran;Kim, Seung-hyeong;Park, Yang-chun
    • The Journal of Internal Korean Medicine
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    • v.38 no.3
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    • pp.353-366
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    • 2017
  • Objective: This study aimed to use a mouse model to evaluate the effects of Gwaruhaengryeon-hwan (GHH) on chronic obstructive pulmonary disease (COPD) and particulate matter induced lung injury. Materials and Methods: The study was carried out in two ways (in vitro, in vivo). In vitro RAW 264.7 cells (mouse macrophage) were used and analyzed by flow cytometry, ELISA. In vivo lipopolysaccharide (LPS) and cigarette smoke solution (CSS), or coal, fly ash, diesel exhaust particle (CFD) challenged mice were used and its BALF was analyzed by ELISA, lung tissue by real-time PCR. Results: In vitro, GHH maintained an 80-100% rate of viability. So cytotoxicity was not shown. In the ELISA analysis with RAW 264.7 cells, GHH significantly decreased NO over $30{\mu}g/ml$. In the ELISA analysis, GHH significantly decreased $TNF-{\alpha}$, IL-6 over $300{\mu}g/ml$. In the COPD model, the GHH 200 mg/kg dosage group, the application of GHH significantly decreased the increasing of neutrophils, $TNF-{\alpha}$, IL-17A, MIP2, CXCL-1 in BALF, $TNF-{\alpha}$, $IL-1{\beta}$ mRNA expression in lung tissue and histological lung injury. In the CFD induced lung injury model, the GHH 200 mg/kg dosage group, the application of GHH significantly decreased the increase of neutrophils, $TNF-{\alpha}$, IL-17A, MIP2, CXCL-1 in BALF, MUC5AC, $TGF-{\beta}$ mRNA expression in lung tissue and histological lung injury. Conclusion: This study suggests the usability of GHH for COPD patients by controlling lung tissue injury.

Strength Characteristics of Recycled Concrete by Recycled Aggregate in Incheon Area Waste Concrete (인천지역의 콘크리트 폐기물을 재생골재로 활용한 재생콘크리트의 강도특성)

  • Jang, Jea-Young;Jin, Jung-Hoon;Cho, Gyu-Tae;Nam, Young-Kug;Jeon, Chan-Ki
    • Journal of the Korea Concrete Institute
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    • v.15 no.2
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    • pp.197-208
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    • 2003
  • This paper is to determine the possibility of re-using waste concrete from Incheon city area. The strength test was conducted with five aggregate compounds which was replaced a natural aggregate with recycled aggregate. After checking the physical characteristics of recycled aggregate compounds, the mix design of recycled concrete was conducted. For the relatively comparison between natural and recycled compounds, while the unit aggregate weight was changed, other conditions were fixed. The freezing and thawing test which included fly-ash and super-plastezer were performed to check the durability and workability when recycling waste concrete. In the physical characteristics of recycled aggregate, it was found that the specific gravity of recycled coarse aggregate and recycled fine aggregate satisfied the first grade of recycle specification(KS), and all compounds of recycled aggregate also satisfied the second grade of absorption specification, Especially up to the 50% substitution of recycled aggregate is equal to or a bit lower than that of convention aggregate. In comparison with conventional concrete, the recycled concrete is lower than maximum by 7% in compressive strength decreasing rate after freezing-thawing test. From now, although most of recycled concrete was used to the building lot, subgrade, asphalt admixture, through the result. It was proved that possibility of re-using recycled aggregate as the substructure of bridge, retaining wall, tunnel lining and concrete structure which is not attacked the drying shrinkage severely.

The Fundamental Study on Properties of Concrete Using the Garnet with Industrial Wastes (산업부산물인 가네트를 이용한 콘크리트의 성질개선에 관한 기초적 연구)

  • Lim, Byoung-Ho;Park, Jung-Min;Kim, Tae-Gon;Kim, Wha-Jung
    • Magazine of the Korea Concrete Institute
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    • v.11 no.1
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    • pp.183-190
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    • 1999
  • This paper investigated the possibility of appling to concrete through fundamental experiment for garnet, which was industrial wastes generated in kyung pook region, in aspects of development of new materials and recycling of industrial wastes due to shortage of natural resources. Consequently, garnet powder showed the possibility of admixture as showed in the chemical composition because the content of silica and alumina in relation to pozzolanic activity was about 50%. The time of setting was more or less diminished as the increasing of replacement ratio of garnet. In flow test, flow values tended to increase to some degree as the increasing of replacement ratio of garnet. Therefore, application of garnet was expected to improve the workability of concrete. The compressive strength of mortar replaced by garnet was respectively increased as compared with plain mortar and the maximum strength was showed in replaced by 10%, however a little different to the change of W/B ratio. Also, the possibility of admixture to reduce the amount of cement and to improve the property of concrete was showed as the strength of mortar replaced by garnet was comparable to that by existing admixture(silica fume, fly-ash).

Characteristics of Shear Waves in Controlled Low Strength Material with Curing Time (양생시간에 따른 유동성 채움재의 전단파 특성)

  • Han, Woojin;Lee, Jong-Sub;Byun, Yong-Hoon;Cho, Samdeok;Kim, Juhyong
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.3
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    • pp.13-19
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    • 2016
  • The ultrasonic waves for monitoring concrete materials have been used to investigate the setting and hardening process of concrete. This paper presents the application of bender elements for monitoring the hardening properties of Controlled Low Strength Material (CLSM) and the characterization of shear waves in CLSM according to curing time. To ensure the early age properties and flow, the CLSM consists of CSA cement, sand, silt, water, fly ash, and accelerator. In addition, three different type specimens according to fine contents are mixed. A couple of bender elements are installed at the wall of measurement cell and the CLSM specimen are prepared at the measurement cell for 28 days. Experimental results show that the resonant frequency and shear wave velocities increase with an increase in the curing time, regardless of the fine contents. Up to ten hours, the amplitudes of shear waves also increase, and the resonant frequency and shear wave velocities at the same time increase as the fine contents increase. The shear wave measurement technique using the bender elements may be effectively used to evaluate the hardening properties of CLSM along the curing time.

Ultrafine Particle Events in the Ambient Atmosphere in Korea

  • Maskey, Shila;Kim, Jae-Seok;Cho, Hee-Joo;Park, Kihong
    • Asian Journal of Atmospheric Environment
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    • v.6 no.4
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    • pp.288-303
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    • 2012
  • In this study, real time measurements of particle number size distribution in urban Gwangju, coastal Taean, and industrial Yeosu in Korea were conducted in 2008 to understand the occurrence of ultrafine particle (UFP) (<100 nm) events, the variation of its concentration among different sampling sites, and UFP formation pathways. Also, to investigate seasonal and long-term variation of the UFP number concentration, data were collected for the period of 5 years (2007, 2008, 2010, 2011, and 2012) in urban Gwangju. Photochemical and combustion events were found to be responsible for the formation of UFP in the urban Gwangju site, whereas only photochemical event led to the formation of UFP in the coastal Taean site. The highest UFP concentration was found in industrial Yeosu (the average UFP number fractions were 79, 59 and 58% in Yeosu, Gwangju, and Taean, respectively), suggesting that high amount of gas pollutants (e.g., $NO_2$, $SO_2$, and volatile organic carbon (VOC)) emitted from industries and their photochemical reaction contributed for the elevated UFP concentration in the industrial Yeosu site. The UFP fraction also showed a seasonal variation with the peak value in spring (61.5, 54.5, 50.5, and 40.7% in spring, fall, summer, and winter, respectively) at urban Gwangju. Annual average UFP number concentrations in urban Gwangju were $5.53{\times}10^3\;cm^{-3}$, $4.68{\times}10^3\;cm^{-3}$, $5.32{\times}10^3\;cm^{-3}$, $3.99{\times}10^3\;cm^{-3}$, and $2.16{\times}10^3\;cm^{-3}$ in the year 2007, 2008, 2010, 2011, and 2012, respectively. Comparison of the annual average UFP number concentration with urban sites in other countries showed that the UFP concentrations of the Korean sites were lower than those in other urban cities, probably due to lower source strength in the current site. TEM/EDS analysis for the size-selected UFPs showed that the UFPs were classified into various types having different chemical species. Carbonaceous particles were observed in both combustion (soot and organics) and photochemical events (sulfate and organics). In the photochemical event, an internal mixture of organic species and ammonium sulfate/bisulfate was identified. Also, internal mixtures of aged Na-rich and organic species, aged Ca-rich particles, and doughnut shaped K-containing particles with elemental composition of a strong C with minor O, S, and K-likely to be originated from biomass burning nearby agricultural area, were observed. In addition, fly ash particles were also observed in the combustion event, not in the photochemical event.

Evaluation on Reactivity of By-Product Pozzolanic Materials Using Electrical Conductivity Measurement (전기전도도 시험방법을 활용한 산업부산물 포졸란재료의 반응성 평가)

  • Choi, Ik-Je;Kim, Ji-Hyun;Lee, Soo-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.5
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    • pp.421-428
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    • 2016
  • In this work, pozzolanic activities of various waste materials were compared with those of well-known by-product pozzolanic materials. Undensified and densified silica fume, ASTM class F and class C fly ash, and metakaolin were chosen as well-known pozzolanic materials, and bentonite powder, ceramic powder obtained from wash basin, and waste glass wool, which can possibly possess pozzolanic property, were chosen for comparison. Drop in electrical conductivity at $40^{\circ}C$ saturated lime solution was measured for each materials. The amount of Ca(OH)2 decomposed from cement paste at $450{\sim}500^{\circ}C$ was also measured to evaluate pozzolanic activity. The 28 day compressive strength were used to observe the mechanical property enhanced by incorporation of various waste materials. According to the experimental results, using "difference between maximum conductivity value and conductivity value at 4 hour" was found to be a reasonable approach to determine pozzolanic activity of a material. Pozzolanic activity measured using electrical conductivity correlates very well with that measured using the amount of Ca(OH)2 remained in the cement paste. Relatively good agreement was also found with electrical conductivity and 28 day compressive strength. It was found that electrical conductivity measurement can be used to evaluate pozzolanic activity of unknown materials.

Properties of Hydration Heat of High-Strength Concrete and Reduction Strategy for Heat Production (고강도 콘크리트의 수화열 특성 및 발열 저감대책에 관한 연구)

  • Jaung, Jae-Dong;Cho, Hyun-Dae;Park, Seung-Wan
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.2
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    • pp.203-210
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    • 2012
  • Recently, the interest and demand for large-scale buildings and skyscrapers have been on the rise, and the performance of concrete is an area of high priority. Securing 'mass concrete and high strength concrete' is very important as a key construction technology. For high strength concrete, the high heat of hydration takes place inside the concrete because of the vitality of hydration in cement due to the large amount of powder, and leads to problems such as an increase of thermal stress due to the temperature difference with the outside, which results in cracks and slump loss. For this reason, measures to solve these problems are needed. This study aims to reduce the hydration heat of high strength concrete to control the hydration heat of mass concrete and high strength concrete, by replacing the type of admixture, The purpose of this study is to control the hydration heat of high strength concrete and mass concrete. Our idea for this purpose is to apply not only the types and contents of admixture but also incorporation mixing water to ice-flake. As a result of the test, the use of blast furnace slag and fly ash as admixture, and the use of ice-flake as mixing water can improve the liquidity of concrete and reduce slump loss. Significantly dropping the maximum temperature will contribute greatly to reducing cracks due to hydration heat in mass concrete and high strength concrete, and improve quality.

Engineering Characteristics of Ultra High Strength Concrete with 100 MPa depending on Fine Aggregate Kinds and Mixing Methods (잔골재 종류 및 혼합방법 변화에 따른 100 MPa 급 초고강도 콘크리트의 공학적 특성)

  • Han, Min-Cheol;Lee, Hong-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.2
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    • pp.536-544
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    • 2016
  • Recently, with the increase in the number of high rise and huge scaled buildings, ultra-high strength concrete with 80~100 MPa has been used increasingly to withstand excessive loads. Among the components of concrete, the effects of the kinds and properties of fine aggregates on the performance and economic advantages of ultra-high strength concrete need to be evaluated carefully. Therefore, this study examined the effects of the type of fine aggregates and mixing methods on the engineering properties of ultra-high strength concrete by varying the fine aggregates including limestone fine aggregate (LFA), electrical arc slag fine aggregate (EFA), washed sea sand (SFA), and granite fine aggregate (GFA) and their mixtures. Ultra-high strength concrete was fabricated with a 20 % water to binder ratio (W/B) and incorporated with 70 % of Ordinary Portland cement: 20 % of fly ash:10 % silica fume. The test results indicate that for a given superplasticizer dose, the use of LFA resulted in increases in slump flow and L-flow compared to the mixtures using other aggregates due to the improved particle shape and grading of LFA. In addition, the use of LFA and EFA led to enhanced compressive strength and a decrease in autogenous shrinkage due to the improved elastic properties of LFA and the presence of free-CaO in EFA, which resulted in the formation of C-S-H.

The Fundamental Characteristics for Mix Proportion of Multi-Component Cement (배합비에 따른 다성분계 시멘트의 기초특성)

  • Kim, Tae-Wan;Jeon, Jae-Woo;Seo, Min-A;Jo, Hyeon-Hyeong;Bae, Su-Yeon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.3
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    • pp.66-74
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    • 2016
  • The aim of this research work is to investigate the mix proportion of multi-component cement incorporating ground granulated blast furnace(GGBFS), fly ash(FA) and silica fume(SF) as an addition to cement in ternary and quaternary combinations. The water-binder ratio was 0.45. In this study, 50% and 60% replacement ratios of mineral admixture to OPC was used, while series of combination of 20~40% GGBFS, 5~35% FA and 0~15% SF binder were used for fundamental characteristics tests. This study concern the GGBFS/FA ratio and SF contents of multi-component cement including the compressive strength, water absorptions, ultrasonic pulse velocity(UPV), drying shrinkage and X-ray diffraction(XRD) analysises. The results show that the addition of SF can reduce the water absorption and increase the compressive strength, UPV and drying shrinkage. These developments in the compressive strength, UPV and water absorption can be attributed to the fact that increase in the SF content tends basically to consume the calcium hydroxide crystals released from the hydration process leading to the formation of further CSH(calcium silicate hydrate). The strength, water absorption and UPV increases with an increase in GGBFS/FA ratios for a each SF contents. The relationship between GGBFS/FA ratios and compressive strength, water absorption, UPV is close to linear. It was found that the GGBFS/FA ratio and SF contents is the key factor governing the fundamental properties of multi-component cement.

Compressive strength prediction of concrete using ground granulated blast furnace slag by accelerated testing (촉진양생법에 의한 고로슬래그 미분말 혼합 콘크리트의 압축강도 예측)

  • Kim, Yong Jic;Kim, Young Jin;Choi, Yun Wang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.91-98
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    • 2009
  • Recently, production cost of ready mixed concrete has been increased due to the rising cost of raw materials such as cement and aggregate etc. cause by the upturn of oil price and increase of shipping charge. The delivery cost of ready mixed concrete companies, however, has been decreased owing to their excessive competition in sale. Consequently, ready mixed concrete companies began to manufacture the concrete by mixing ground granulated blast furnace slag(GGBF) and fly-ash in order to lower the production cost. Therefore, the objective of this study was to predict 28 days strength of GGBF slag concrete by early strength(warm and hot water curing method) for the sake of managing with ease the quality of ready mixed concrete. In experimental results, the prediction equation for 28 days compressive strength of GGBF slag concrete could be produced through the linear regression analysis of early strength and 28 days strength. In order to acquire the reliability, all mixture were repeated as 3 times and each mixture order was carried out by random sampling. The prediction equation for 28 days strength of GGBF slag concrete by 1 day compressive strength(accelerated testing) according to warm and hot water curing method won the good reliability.

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