• Advances in materials Research
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• 제9권3호
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• pp.219-231
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• 2020

The aim of this study is to investigate the durability of fly ash based geopolymer mortar with and without protective coatings in aggressive chemical environments. The source materials for geopolymer are Fly ash and Ground Granulated Blast furnace Slag (GGBS) and they are considered in the combination of 80% & 20% respectively. Two Molarities of NaOH solution were considered such as 8M and 10M. The ratio of binder to sand and Sodium silicate to Sodium hydroxide solution (Na₂SiO₃/NaOH) are taken as 1:2 and 2 respectively. The alkaline liquid to binder ratio is 0.4. Compressive strength tests were conducted at various ages of the mortar specimens. In order to evaluate the performance of coatings on geopolymer mortar under aggressive chemical environment, the mortar specimens were coated with two different types of coatings such as epoxy and Acrylic. They were then subjected to different chemical environments by immersing them in 10% standard solutions of each ammonium nitrate, sodium chloride and sulphuric acid. Drop in compressive strength as a result of chemical exposure was considered as a measure of chemical attack and the drop in compressive strength was measured after 30 and 60 days of chemical exposure. The compressive strength results following chemical exposure indicated that the specimens containing the acrylic coating proved to be more resistant to chemical attacks. The control specimen without coating showed a much greater degree of deterioration. Therefore, the application of acrylic coating was invariably much more effective in improving the compressive strength as well as the resistance of mortar against chemical attacks. The results also indicated that among all the aggressive attacks, the sulphate environment has the most adverse effect in terms of lowering the strength.

• 한국지하수토양환경학회지:지하수토양환경
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• 제14권3호
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• pp.47-56
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• 2009

본 연구는 해안점토 또는 육상의 사질토에 지반개량재를 혼합하였을 때 어떤 강도변화를 보이는지에 관한 것이다. 철광석을 제련할 때 부산물인 슬래그와 제지류 소각할 때 생기는 paper fly ash를 일정한 비율로 혼합하여 지반개량재를 만들었다. 이러한 지반개량재를 해안점토와 육상의 사질토에 혼합한 후 함수비, 양생일, 혼합비 등으로 구분하여 일축압축강도 시험용 공시체를 제작하였다. 공시체가 28일간 양생되는 동안 일축압축강도의 변화와 생성물질의 변화를 분석하였다. 강도분석 결과 육상의 사질토보다 해안점토에서 최대 11배 정도의 강도증가의 효과가 나타났는데, 이는 지반개량재로 인한 ettringite 반응이 사질토보다 해안점토에서 명확하게 보여주는 것을 의미한다.

• 한국건축시공학회지
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• 제11권6호
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• pp.547-556
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• 2011

경화 콘크리트의 물성에 있어서 황산염 저항에 가장 큰 영향을 미치는 두 요소로서 포틀랜드 시멘트의 화학적 성분과 그 양을 들 수 있다. 본 연구에서는 황산염 침투에 대한 영향을 고찰하기 위하여 ASTM C1012의 규정을 바탕으로 여러 종류의 모르타르를 제작하여 실험을 수행하였다. 본 연구에서 황산염 침투에 대한 영향을 평가하기 위해 TYPE I, 두 가지의 TYPE I-II 시멘트와 TYPE V의 시멘트 등 네 가지 모르타르를 사용하여 실험을 수행하였다. 또한 각각의 모르타르 혼합물들에 사용된 무기혼합물의 경우에도 세 가지 종류를 사용하였다. F타입 플라이애시와 C타입 플라이애시, 고로슬래그를 부피비를 기준으로 대체하여 사용하였으며, 실험을 통한 콘크리트의 팽창률을 ASTM 규정의 권장 팽창 기준을 바탕으로 비교 분석하였다.

• 한국건설순환자원학회논문집
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• 제5권1호
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• pp.117-124
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• 2010

순환골재는 KS F 2573에 만족하지 않는 골재를 사용하였다. 포졸란재료를 혼합하지 않은 순환골재 콘크리트의 재령 28일 압축강도는 21.7MPa 정도로 부순굵은골재을 사용한 콘크리트보다 강도발현이 작게 나타났다. 반면에 조강포틀랜드시멘트를 시멘트 중량에 2.5% 혼합하므로써 재령 28일 압축강도가 향상되었으며, 플라이애시와 고로슬래그 미분말 및 규조분말의 영향으로 재령 91일 및 180일 압축강도 증진효과가 크게 나타났다. 포졸란재료를 혼합한 순환골재 콘크리트의 인장강도도 보통콘크리트에 비하여 약 40% 정도의 강도증진 효과가 있었다. 아울러 플라이애시와 고로슬래그 미분말을 혼합한 순환골재 콘크리트의 건조수축 및 크리프는 플라이애시와 규조분말을 사용한 순환골재 콘크리트에 비하여 약간 감소하였다. 순환골재 콘크리트의 압축강도와 크리프계수와의 관계는 ${\sigma}_c=-30CF+404$와 같은 선형성이 나타났다.

• 한국재난정보학회 논문집
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• 제10권2호
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• pp.238-243
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• 2014

최근 세계적으로 환경오염이 심각해짐에 따라 환경보호의 일환으로 자원 재활용과 연관하여 시멘트의 대체 재료로서 산업부산물에 대한 관심이 높아졌으며, 특히 최근 경제성, 치수안정성 및 신뢰성이 우수한 고품질의 콘크리트 개발이 크게 요구되고 있는데 이를 증명하기 위한 실험을 수행한 결과는 다음과 같다. (1) 고로슬래그 미분말과 플라이애쉬 같은 혼화재를 혼합하여 사용할 경우 유동성이 개선되고 수화열 감소하는 효과가 있다. (2) 고로슬래그 미분말과 플라이애쉬 같은 혼화재의 량을 증가하면 장기강도 증진되고 건조수축이 감소한다, (3) 고로슬래그 미분말과 플라이애쉬 같은 혼화재의 혼입량을 증가시키면 수밀성 및 내구성 향상 등에 효과가 있는 것으로 나타나고 있다. 본 연구에서는 고로슬래그 미분말 및 플라이애쉬의 각각의 치환율과 혼입에 따른 콘크리트의 공학적 특성 및 혼입량의 임계치를 추정하고 현장 적용가능성을 검증하는데 목적이 있다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.369-374
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• 2002

In this paper, setting and hydration heat development characteristics with three binder types, type IV cement＋fly ash, type IV cement＋slag powder and type IV cement ＋ limestone powder. were investigate. As results, it was shown that the limestone powder decreased the initial setting time regardless of replacement ratio, especially the range of 20~50% replacement ratio, and the 2nd peak was shifted ahead when the limestone powder replacement ratio increased. But for the f1y ash and the limestone powder, contrary results were obtained compared with the limestone powder.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1996년도 가을 학술발표회 논문집
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• pp.140-147
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• 1996

This study was performed to investigate the characteristics of workability and strength of the concrete containing admixtures such as silica fume, fly ash, blast furnace slag, and rice husk ash. For this purpose, the workability and the strength of the concrete containing each admixture were tested and analyzed according to the unit weight of binder and the replacement ratio of each admixture.

• 한국건축시공학회지
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• 제4권4호
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• pp.79-86
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• 2004

The purpose of this study was the development of a recycling process to recover the hydraulic properties of hydration products which account for a large proportion of cementitious powder from concrete waste. This process was performed to recycle cementitious powder as recycle cement. Therefore, after the theoretical consideration of the properties of recycle process of recycled aggregates and cementitious powder, we investigated the hydraulic properties of cementitious powder under various temperature conditions in hardened mortar which was modeled on concrete waste. And we analyzed properties of chemical reactions of recycled cement with admixture materials such as Fly-Ash, Blast Furnace Slag As a result of the experiment, the most effective method to recover hydraulic properties of the cementitious powder from concrete waste was condition of burning at 700℃ for 120 minute. And it is shown that the fluidity of mortar was decreased rapidly when the burning temperature of recycle cement was increased. However, the compressive strength and fluidity were improved significantly when admixture materials such as Fly-Ash or Blast Furnace Slag was added.

• International Journal of Concrete Structures and Materials
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• 제18권2E호
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• pp.125-132
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• 2006

Waste glass has been increasingly used in industrial applications. One shortcoming in the utilization of waste glass for concrete production is that it can cause the concrete to be weakened and cracked due to its expansion by alkali-silica reaction(ASR). This study analyzed the ASR expansion and strength properties of concrete in terms of waste glass color(amber and emerald-green), and industrial by-products(ground granulated blast-furnace slag, fly ash). Specifically, the role of industrial by-products content in reducing the ASR expansion caused by waste glass was analyzed in detail. In addition, the feasibility of using ground glass for its pozzolanic property was also analyzed. The research result revealed that the pessimum size for waste glass was $2.5{\sim}1.2mm$ regardless of the color of waste glass. Moreover, it was found that the smaller the waste glass is than the size of $2.5{\sim}1.2mm$, the less expansion of ASR was. Additionally, the use of waste glass in combination with industrial by-products had an effect of reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass. Finally, ground glass less than 0.075 mm was deemed to be applicable as a pozzolanic material.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.643-646
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• 2005

This paper reports the influence of super retarding agent(SRA) on the setting time of concrete incorporating mineral admixture including fly ash(FA), expansive additive(EA), silica fume(SF), blast furnace slag(BS) and blast furnace slag along with fly ash(BS+FA). An increase in SRA resulted in retarding the setting time of control concrete, while the use of mineral admixture led to a delay of setting time markedly, compared with that of control concrete under no SRA content. Meanwhile, An increase in SRA in concrete with mineral admixture exhibited comparable setting delay with control concrete. Furthermore, in case of the use of BS and SF, acceleration of setting time was observed with increase of SRA content. It is considered that proper dosage of SRA of concrete with SF and BS to secure similar setting delay with control concrete require rather larger than that of control concrete. Accordingly, For concrete with mineral admixture, in order to decide the proper dosage of SRA, application of correction factors is needed.