• Title/Summary/Keyword: flux concentration

Search Result 920, Processing Time 0.027 seconds

COMPARISON OF FLUX AND RESIDENT CONCENTRATION BREAKTHROUGH CURVES (BTCs) IN STRUCTURED SOIL COLUMNS

  • Kim, Dong-Ju
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 1997.05a
    • /
    • pp.25-29
    • /
    • 1997
  • In many solute transport studies, either flux or resident concentration has been used. Choice of the concentration mode was dependent on the monitoring device in solute displacement experiments. It would be questionable, however. to accept the equivalency in the solute transport parameters between flux and resident concentrations in structured soils exhibiting preferential movement of solute. In this study, we investigate how they differ in the monitored breakthrough curves (BTCs) and transport parameters for a given boundary and flow condition by performing solute displacement experiments on a number of undisturbed soil columns. Both flux and resident concentrations have been simultaneously obtained by monitoring the effluent and resistance of the Horizontally-positioned TDR probes. The study reveals that soil columns having relatively high flux densities exhibited great differences in the degree of peak concentration and travel time of peak between flux and resident concentrations. The peak concentration in flux mode was several times higher than that in resident one. This was mainly due to the bypassing of solute through soil macropores.

  • PDF

Treatment of high-salinity wastewater after the resin regeneration using VMD

  • Gao, Junyu;Wang, Manxiang;Yun, Yanbin
    • Membrane and Water Treatment
    • /
    • v.9 no.1
    • /
    • pp.53-62
    • /
    • 2018
  • In this study, vacuum membrane distillation (VMD) was used to treat high-salinity wastewater (concentration about 17%) discharged by chlor-alkali plant after resin regeneration. The feasibility of VMD for the treatment of real saline wastewater by using Polyvinylidene fluoride (PVDF) microporous plate membrane with a pore diameter of $0.2{\mu}m$ was investigated. The effects of critical operating parameters such as feed temperature, velocity, vacuum degree and concentration on the permeate water flux were analyzed. Numerical simulation was used to predict the flux and the obtained results were in good agreement with the experimental data. The results showed that an increase in the operating conditions could greatly promote the permeate water flux which in turn decreased with an increase in the concentration. When the concentration varied from 17 to 25%, the permeate water flux dropped marginally with time indicating that the concentration was not sensitive to the decrease in permeate water flux. The permeate water flux decreased sharply until zero due to the membrane fouling resistance as the concentration varied from 25 to 26%. However, the conductivity of the produced water was well maintained and the average value was measured to be $4.98{\mu}s/cm$. Furthermore, a salt rejection of more than 99.99% was achieved. Overall, the outcome of this investigation clearly indicates that VMD has the potential for treating high-salinity wastewater.

Sensitivity Study of the Flow-through Dynamic Flux Chamber Technique for the Soil NO Emissions

  • Kim Deug-Soo
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.21 no.E3
    • /
    • pp.75-85
    • /
    • 2005
  • A mathematical sensitivity analysis of the flow-through dynamic flux chamber technique, which has been utilized usually for various trace gas flux measurement from soil and water surface, was performed in an effort to provide physical and mathematical understandings of parameters essential for the NO flux calculation. The mass balance equation including chemical reactions was analytically solved for the soil NO flux under the steady state condition. The equilibrium concentration inside the chamber, $C_{eq}$, was found to be determined mainly by the balance between the soil flux and dilution of the gas concentration inside the chamber by introducing the ambient air. Surface deposition NO occurs inside the chamber when the $C_{eq}$ is greater than the ambient NO concentration ($C_{0}$) introducing to the chamber; NO emission from the soil occurs when the $C_{eq}$ is less than the ambient NO concentration. A sensitivity analysis of the significance of the chemical reactions of NO with the reactive species (i.e. $HO_{2},/CH_{3}O_{2},/O_{3}$) on the NO flux from soils was performed. The result of the analysis suggests that the NO flux calculated in the absence of chemical reactions and wall loss could be in error ranges from 40 to $85\%$ to the total flux.

Effect of Concentration of Solution and Temperature on Water Flux by Semi-Permeability of Hardened Cement Paste (시멘트경화체의 반투과성에 의한 수분이동에 미치는 용액농도와 환경온도의 영향)

  • 배기선;오상근;김무한
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 1997.10a
    • /
    • pp.131-136
    • /
    • 1997
  • It is well known that concrete is typical porous material. We pay attention to Hansen's idea that concrete may be expected to act as semi-permeable membrane, and report the effect of concentration of solution and temperature on water flux in forward osmosis. In order to measuring volume of water flux from distilled water to solution of sodium chloride through hardened cement paste, specially designed apparatus was constructed, and the following result were obtained: (1) hardened cement paste acts as semi-permeable membrane, consequently, water flux in forward osmosis may occur. (2) Rate of water flux is proportion to concentration of dilute solution, and this suggests hardened cement paste is agreeable to the theory of membrane. (3) Effect of temperature on water flux is agreeable to Arrehenius equation and is great.

  • PDF

A study on the Character of Water Quality according to the Flux in Pal-Dang Reservoir (팔당호 유량변동에 따른 수질특성에 관한 연구)

  • 김종민
    • Journal of environmental and Sanitary engineering
    • /
    • v.10 no.1
    • /
    • pp.12-24
    • /
    • 1995
  • I tried to evaluate the reason of the monthly variation of water quality according to the hydrologic character of Pal- dang reservoir inflow variation. The result of this study is as below; 1 ) COD, BOD, Total- nitrogen and Total- phosphate concentration increase generally according to the flux and Total- phosphate concentration is the most affected item by flux. 2) COD, BOD, Total- nitrogen and Total- phosphate concentration increase according the flux, but they begin to decrease at the below point ; COD · 1,154 CMS, BOD : 1,007 (CMS cubicmeter per second ) and Inflow- Concentration interrelation formula is as below; table omitted.

  • PDF

Modeling of flux enhancement in presence of concentration polarization by pressure pulsation during laminar cross flow ultrafiltration

  • Kumar, Kamal;De, Sirshendu
    • Membrane and Water Treatment
    • /
    • v.1 no.4
    • /
    • pp.253-271
    • /
    • 2010
  • A theoretical study for the flux enhancement by pulsation of transmembrane pressure is presented for osmotic pressure controlled ultrafiltration under laminar flow regime. The transient velocity profile is solved analytically using Green's function method. Time dependent convective diffusive equation is solved to quantify the membrane surface concentration and the permeate flux, numerically. The effects of the amplitude and frequency of pulsation on flux, surface concentration and observed retention are studied.

Forward Osmosis Based Seawater Desalination using Liquid Fertilizer as Draw Solution (액상 비료를 유도 용액으로 사용하는 정삼투 기반의 해수 담수화)

  • Park, Seong-Jik;An, Hee-Kyung
    • Journal of The Korean Society of Agricultural Engineers
    • /
    • v.55 no.2
    • /
    • pp.21-27
    • /
    • 2013
  • The present study explored the way to desalinate seawater for agricultural irrigation using forward osmosis (FO) process using liquid fertilizer as draw solution. FO experiments were performed in a cross flow mode using flat sheet FO membrane. The effect of membrane orientation, flow rate, and draw solution concentration on the performance of forward osmosis was investigated by measuring water flux of forward osmosis membrane. The water flux when the draw solution was placed against the membrane active layer was lower than the water flux when the feed solution was placed against the membrane active layer. This results indicated that the decrease of effective osmotic pressure by dilutive internal concentration polarization was less than that by concentrative internal concentration polarization. Increasing flow rate from 66.7 to 133.1 $cm^3$/min resulted in increase of the water flux when the membrane active layer orient to draw solution and feed solution, respectively. The reduction of resistance to water flow increased water flux at higher flow rate. The water flux of FO membrane increased with increasing draw solution concentration from 10000 to 30000 mg/L. The water flux for $KH_2PO_4$ draw solution was similar to that for commercial fertilizer. Optimization of FO process would contribute to economically desalinate brackish water for agricultural use.

A Study on Development of an Automatic Spreading System of High-concentration Flux for a Nocolok Brazing Furnace (NBF 고농도 플럭스 자동 도포 장치 개발에 관한 연구)

  • Lee, Young-Lim;Hwang, Soon-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.11 no.3
    • /
    • pp.1108-1114
    • /
    • 2010
  • Nocolok brazing requires flux at the joining area and low-concentration flux is uniformly spreaded to products to be brazed in a chamber. However high-concentration flux needs to be applied only to a necessary spot. In general, high-concentration flux is manually applied for conventional brazing furnaces, resulting in low production efficiency and harmful environments for workers due to particles and heat etc. Therefore an economical and efficient automatic spreading system needs to be developed. In this study, an efficient automatic spreading system of high-concentration flux was successfully developed and tested with a NBF.

Optimization of chemical cleaning of discarded reverse osmosis membranes for reuse

  • Jung, Minsu;Yaqub, Muhammad;Lee, Wontae
    • Membrane and Water Treatment
    • /
    • v.12 no.1
    • /
    • pp.1-9
    • /
    • 2021
  • This study optimized the chemical cleaning process of discarded RO membranes for reuse in less demanding separation processes. The effect of physicochemical parameters, including the temperature, cleaning time, pH of the cleaning solution, and addition of additives, on the cleaning process was investigated. The membrane performance was evaluated by testing the flux recovery rate and salt rejection before and after the cleaning process. High temperatures (45-50 ℃) resulted in a better flux recovery rate of 71% with more than 80% salt rejection. Equal time for acid and base cleaning 3-3 h presented a 72.43% flux recovery rate with salt rejection above 85%. During acid and base cleaning, the best results were achieved at pH values of 3.0 and 12.0, respectively. Moreover, 0.05% concentration of ethylenediaminetetraacetic acid presented 72.3% flux recovery, while 69.2% flux was achieved using sodium dodecyl sulfate with a concentration of 0.5%; both showed >80% salt rejection, indicating no damage to the active layer of the membrane. Conversely, 0.5% concentration of sodium percarbonate showed 83.1% flux recovery and 0.005% concentration of sodium hypochlorite presented 85.2% flux recovery, while a high concentration of these chemicals resulted in oxidation of the membrane that caused a reduction in salt rejection.

Ultrafiltration and Separation Process Optimization of Hen Egg White Lysozyme as Natural Antimicrobial Enzyme (천연 항균 효소제 난백 lysozyme의 한외여과 조건 최적화)

  • Lee, Eun-Young;Woo, Gun-Jo
    • Korean Journal of Food Science and Technology
    • /
    • v.30 no.2
    • /
    • pp.397-406
    • /
    • 1998
  • Hen egg white lysozyme (HEWL) is very valuable as a natural preservative in food processing due to its selective bactericidal activity. HEWL which traditionally isolated by crystallization or freeze drying was simply separated from 13 different hen egg white (HEW) proteins by a single-step ultrafiltration. Freeze dried HEW (0.25%, w/v) dissolved in a citrate-phosphate buffer (pH 4.6) was ultrafiltered with a PM30 membrane under various operating conditions, by changing concentration, temperature, transmembrane pressure $({\triangle}P_T)$, and stirring speed. Optimum separation conditions were decided when maximal flux was obtained. Under the optimum separation conditions, the effect of membrane material and fouling on flux as time passed as well as lysozyme concentration, protein concentration, specific activity (SA) in the permeate were measured. Best separation conditions of HEWL with PM30 membrane were sample concentration 0.25%, temperature $35^{\circ}C$, ${\Delta}P_T\;30\;psi$, and stirring speed 300 rpm. During the first 12 min, the flux of YM30 was higher, but at the steady-state it was lower than that of PM30. The SA of the PM30 permeate was over 2 times higher in spite of the lysozyme and protein concentration being lower than that of YM30 permeate. The flux of 5 times used PM30 decreased 30% compared to a new PM30, but both had the same tendency in flux decrease when time passed. Both of them reached a steady-state after 35 min and remained at 70% of the initial flux. In the PM30 permeate, the lysozyme concentration and SA were 110 units/mL and 2,821 units/mg protein, respectively. Therefore, PM30 membrane separation was very effective for separation of antimicrobial lysozyme.

  • PDF