• 제목/요약/키워드: fluorescence index

검색결과 142건 처리시간 0.028초

기원별 용존 유기물의 분광특성 및 COD 산화율 비교 (Comparison of Spectroscopic Characteristics and Chemical Oxygen Demand Efficiencies for Dissolved Organic Matters from Diverse Sources)

  • 정가영;박민혜;허진;이승윤;신재기
    • 한국물환경학회지
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    • 제25권4호
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    • pp.589-596
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    • 2009
  • The spectroscopic characteristics and chemical oxygen demand (COD) oxidation efficiencies were investigated for dissolved organic matters (DOM) from diverse sources, which may indirectly affect the concentrations and the quality of DOM found in watersheds. The DOM investigated for this study showed a wide range of the percent distributions of refractory organic matter (R-OM) from 8 to 100%. Relatively high R-OM distributions were observed for the DOM with the source of head water, sediments, paddy soils, field soils, and treated sewage whereas the DOM from livestock waste, reed, weeds, algae, and attached algae exhibited lower R-OM percent distributions. The percent distribution of R-OM had positive correlations with specific UV absorbance (SUVA) and humidification indices (HIX) of DOM. The investigated DOM was classified into four different source groups (i.e., biota, vegetables, soils, sediments) by comparing the synchronous fluorescence spectra. The DOM group from biota source was characterized by a prominent presence of protein-like fluorescence (PLF) whereas fulvic-like fluorescence (FLF) was additionally observed for vegetable-source DOM. FLF became significant for the DOM from both soils and sediments although no PLF was found for soil-derived DOM. A range of COD oxidation efficiency was observed for the various DOM, ranging from 36 to 94% and from 65 to 125% for $COD_{Mn}$ and $COD_{Cr}$, respectively. The results indicate that $COD_{Cr}$ reflects the higher OM concentration than $COD_{Mn}$. However, 95% confidence intervals of the COD oxidation efficiencies were similar for the two types of COD, suggesting that $COD_{Cr}$ may not be the superior OM index to $COD_{Mn}$ in terms of the variability of the oxidation efficiency. No significant correlations were obtained between COD oxidation efficiencies and the spectroscopic characteristics of DOM for this study.

유치의 치아우식증 확인을 위한 정량형광분석(QLF) 검사법의 우식탐지능력 평가 (Assessment of the Caries Detection Ability of Quantitative Light-induced Fluorescence (QLF) in Primary Teeth in vitro)

  • 조경현;강정민;정회인;이태양;송제선
    • 대한소아치과학회지
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    • 제49권1호
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    • pp.65-75
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    • 2022
  • 본 연구의 목적은 유치의 치아우식증 검사를 위한 정량형광분석(quantitative light-induced fluorescence, QLF) 기술의 유효성을 평가하고, 우식병소의 부피와 QLF 분석결과 사이의 상관관계를 확인하는 것이다. 치아우식증 검사를 위해 53개의 교합면 및 72개의 인접면을 포함한 총 125개의 유구치 치면을 휴대용 QLF 장비를 이용해 조사하여 유구치의 치아우식증을 확인하였다. 또한 치아우식증을 분류하고 우식병소의 부피를 계산하기 위해 micro-CT 방사선 검사를 시행하였다. 상대적으로 낮은 수치를 보였던 인접면 우식에 대한 𝚫R average 결과를 제외하면, QLF 분석결과는 유치의 치아우식증 진단에 대해 충분한 수준의 정확성과 신뢰도를 보였다(민감도 0.75 - 0.94, 특이도 0.82 - 0.95, AUROC 0.88 - 0.98). Spearman 상관분석 결과에서는 𝚫F average 및 QS-Index와 우식병소 부피 사이에 통계적으로 유의한 높은 상관성을 확인할 수 있었다(r = 0.805 - 0.832, p < 0.001). QLF 기술을 이용한 치아우식증 검사는 어린이의 치아우식증 진단에 있어 방사선 노출에 대한 걱정 없이 안전하게 사용 가능하고, 신뢰할 만한 방법이 될 수 있을 것이다.

표면처리용 형광증백제의 정량분석법에 대한 연구 (Development of Quantitative Analysis of the Fluorescent Whitening Agents Used for Surface Treatments)

  • 이지영;김철환;박종혜;김은혜;위상욱;성용주;허영준;김연오;황인영
    • 펄프종이기술
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    • 제47권3호
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    • pp.34-39
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    • 2015
  • Fluorescent whitening agents (FWAs) are widely applied in the papermaking process to improve the CIE whiteness and the ISO brightness of papers. Large amounts of FWAs are used in the paper and paperboard industry, but no standard method exists for quantitative FWA analysis. Therefore, a new method is needed to analyze the presence of FWAs in paper and paperboard to control their additions and applications. In particular, FWA analysis must concentrate on those used for surface treatment of paper because their use in surface applications has increased recently. The purposes of this study were to measure the optical properties of papers surface-treated with oxidized starch containing FWAs and to deduce the regression equations for the quantitative analysis of FWAs used for surface treatments. Surface sizing was carried out to treat the surface of a base paper with T-FWA and H-FWA, and the pickup weight of the surface sized paper was measured to determine the real weight of FWAs transferred onto the paper surface. After surface sizing and preconditioning, the paper was evaluated for CIE whiteness, ISO brightness, fluorescence index, and reflectance at 440 nm using an Elrepho spectrophotometer. The CIE whiteness and the ISO brightness increased linearly as FWA content increased. The fluorescence index and the reflectance showed linear relationships with T-FWA and H-FWA. Linear regression equations were determined for the quantitative analysis of FWAs used for surface treatments.

Qraycam을 이용한 치면세균막 검사의 타당도와 신뢰도 (Validity and Reliability of the Plaque Score Using Qraycam)

  • 김미;이수영;조영식
    • 치위생과학회지
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    • 제15권3호
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    • pp.377-382
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    • 2015
  • 본 연구는 노인 64명을 대상으로 Qraycam을 이용한 이미지로 치면세균막 지수를 측정하여 착색 검사와의 신뢰도를 평가하고자 하였으며, 수집된 자료를 분석하여 다음과 같은 결과를 얻었다. 측정 방법, 측정 부위, 지수유형별에 따른 치면세균막 지수의 각 측정값 사이에 높은 일치도가 나타났다. 측정 방법에 따른 전치부 순면의 Quigley-Hein index와 PCR의 평균은 유의한 차이가 없었으며, 측정 부위에 따른 Quigley-Hein index와 PCR의 평균은 통계적으로 유의한 차이가 있었다(p<0.001). Qraycam 검사와 착색 검사의 지수유형별 kappa계수를 확인한 결과 kappa값의 평균은 Quigley-Hein index 0.90, PCR 0.84로 전체적으로 높은 일치도를 보였다. Qraycam과 착색 검사의 전치부 순면 및 전체 치아를 Quigley-Hein index와 PCR로 측정하였을 때, 변수 간 ICC는 1에 가까운 결과를 보였다. 본 연구 결과 측정방법, 측정 부위, 지수유형별에 따른 치면세균막 지수의 일치도 평가에서 모든 측정값의 일치도가 높게 나타났다. 따라서 Qraycam은 치면세균막 검사 시 screening 도구로서 충분한 신뢰도가 있음을 확인하였다.

상동산 SCHEELITE의 특성연구 <특히 Powellite 진부 구명을 위하여>

  • 황재운
    • 기술사
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    • 제3권10호
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    • pp.3-6
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    • 1970
  • The scheelite occurred in Sang Dong mine are disseminated with a fine grain, and shelved pale blue or white color under the fluorescence. But among them, We can often observe the yellow fluorescent color mineral grains, which were called the powellite from the past time without any detail mineral study. I studied the characteristics of Sang-Dong scheelite and the so called powellite. In the result, the so called powellite is proved to be the molybdenum bearing scheelite in the view of specific gravity, index of refraction, chemical composition, other microscopic properties, and dressing. Such a scheelite is contained usually Zor 3% Mo, and oftenly 4 or 6% Mo, and fluorescent colors are pale yellow, leman yellow and chrome yellow.

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Photochemical Response Analysis on Drought Stress for Red Pepper (Capsiumannuum L.)

  • Yoo, Sung-Yung;Lee, Yong-Ho;Park, So-Hyun;Choi, Kyong-Mi;Park, June-Young;Kim, A-Ram;Hwang, Su-Min;Lee, Min-Ju;Ko, Tae-Seok;Kim, Tae-Wan
    • 한국토양비료학회지
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    • 제46권6호
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    • pp.659-664
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    • 2013
  • The aim of this study is to determine the drought stress index through photochemical analysis in red pepper (Capsiumannuum L.). The photochemical interpretation was performed in the basis of the relation between Kautsky effect and Photosystem II (PSII) following the measurement of chlorophyll, pheophytin contents, and $CO_2$ assimilation in drought stressed 5-week-old red pepper plants. The $CO_2$ assimilation rate was severely lowered with almost 77% reduction of chlorophyll and pheophytin contents at four days after non-irrigation. It was clearly observed that the chlorophyll fluorescence intensity rose from a minimum level (the O level), in less than one second, to a maximum level (the P-level) via two intermediate steps labeled J and I (OJIP process). Drought factor index (DFI) was also calculated using measured OJIP parameters. The DFI was -0.22, meaning not only the initial inhibition of PSII but also sequential inhibition of PSI. In real, most of all photochemical parameters such as quantum yield of the electron transport flux from Quinone A ($Q_A$) to Quinone B ($Q_B$), quantum yield of the electron transport flux until the PSI electron acceptors, quantum yield of the electron transport flux until the PSI electron acceptors, average absorbed photon flux per PSII reaction center, and electron transport flux until PSI acceptors per cross section were profoundly reduced except number of QA reducing reaction centers (RCs) per PSII antenna chlorophyll (RC/ABS). It was illuminated that at least 6 parameters related with quantum yield/efficiency and specific energy fluxes (per active PSII RC) could be applied to be used as the drought stress index. Furthermore, in the combination of parameters, driving forces (DF) for photochemical activity could be deduced from the performance index (PI) for energy conservation from photons absorbed by PSII antenna until the reduction of PSI acceptors. In conclusion, photochemical responses and their related parameters can be used as physiological DFI.

펜-타입 QLF 장비의 임상적 유구치 인접면 우식 탐지 성능 (Detecting of Proximal Caries in Primary Molars using Pen-type QLF Device)

  • 조혜진;김현태;송지수;신터전;김정욱;장기택;김영재
    • 대한소아치과학회지
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    • 제48권4호
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    • pp.405-413
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    • 2021
  • 이 연구의 목적은 펜-타입 quantitative light-induced fluorescence(QLF) 장비의 임상적 유구치 인접면 우식 탐지 성능을 평가하는 것이다. 이를 위해 형광 소실, 적색 자기형광 그리고 인접면 우식을 위해 간편화된 QLF 평가 기준(QS-proximal)이 사용되었으며 교익 방사선 영상과 비교, 평가되었다. 총 344개의 유구치 인접면이 분석되었으며 인접면 우식 병소는 시진과 방사선학적 검사 그리고 QLF 검진을 통하여 평가되었다. QLF 영상들을 이용하여 분석된 QLF 매개변수들과 QS-proximal을 방사선학적 평가와 비교하여 장비의 법랑질과 상아질 우식 탐지 능력에 대한 민감도, 특이도 그리고 area under receiver operating curve(AUROC)가 계산되었다. 두 QLF 매개변수 모두 준수한 상아질 우식 탐지 능력을 보였으며 AUROC은 △F = 0.794, △R = 0.750였다. QS-proximal(0.757 - 0.769)은 시진(0.653)보다 더 높은 AUROC을 나타내었다. 결론적으로 펜-타입 QLF 장비는 방사선학적 평가와 비교하여 임상적으로 적용 가능한 성능을 보였다.

불소바니쉬 도포주기에 따른 재광화 평가: QLF-D의 활용 (Remineralization effect according to application cycle of fluoride varnish: QLF-D analysis)

  • 전은영;이수영
    • 한국치위생학회지
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    • 제16권4호
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    • pp.525-530
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    • 2016
  • Objectives: The purpose of the study is to investigate remineralization effect according to application cycle of fluoride varnish in preschool children. Methods: The study subjects were fifty six children (92 teeth) having one or more early dental caries lesion. Fluoride varnish was applied to the primary area of maxillary and anterior mandibular teeth with the interval of one month, three months, and six months. Results: Dft index was 3.54 in male and 3.44 in female. The fluorescence loss(${\Delta}F$) value due to early caries lesions showed a significant difference in experiment groups I and II after the application of fluoride varnish, but there was no significant difference in experiment group III. After fluoride varnish application, there was a significant change in experimental group I and III. The maximum fluorescence loss(${\Delta}Fmax$) from early caries lesions showed a significant difference after application of the fluoride varnish in all three experiment groups of I, II, and III(p<0.001). Conclusions: Fluoride varnish should be recommended and applied to the children of high risk caries group in every three months.

Microbial and Physicochemical Monitoring of Granular Sludge During Start-up of Thermophilic UASB Reactor

  • Ahn, Yeong-Hee;Park, Sung-Hoon
    • Journal of Microbiology and Biotechnology
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    • 제13권3호
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    • pp.378-384
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    • 2003
  • Mesophilically-grown granular sludge seeded in thermophilic UASB reactor was monitored to better understand the start-up process of the reactor. The reactor was fed with a synthetic wastewater containing glucose. As COD loading rate increased stepwise, methane production rate increased. Maximum values of COD removal efficiency (95%) and methane production rate (5.3 l/day) were achieved by approximately day-80 and remained constant afterward. However, physicochemical and microbial properties of granules kept changing even after day-80. Specific methanogenic activity (SMA) was initially negligible, and increased continuously until day-153 and remained constant afterward, showing the maximum value of $1.51{\pm}0.13\;g\;CH_4-COD/g$ VSS/day. Deteriorated settling ability of granules recovered the initial value by day-98 and was maintained afterward, as determined by sludge volume index. Initially reduced granule size increased until day-126, reaching a plateau of 1.1 mm. Combined use of fluorescence in situ hybridization and confocal laser scanning microscopy (CLSM) allowed to localize families of Methanosaetaceae and Merhanosarcinaceae in granules with time Quantitative analyses of CLSM images of granule sections showed abundance patterns of the methanogens and numerical dominance of Methanosaeta spp. throughout the start-up period. The trend of SMA agreed well with abundance patterns of the methanogens.

화강 풍화암의 지반특성 및 풍화도 평가에 대한 사례 연구 (A Case Study on Geotechnical Properties and Weathering Degree of Weathered Granite Rock)

  • 이승환;유병수;정충기
    • 한국지반공학회논문집
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    • 제33권12호
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    • pp.127-139
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    • 2017
  • 고양 지역의 화강 풍화암 지층을 대상으로 시추조사 및 다양한 현장 시추공 시험(프레셔미터시험, 공내전단시험, Downhole test, Suspension PS 검층, 밀도검층)을 수행하였고, 채취한 풍화암 코어시료에 대한 X선 형광분석을 실시하여 풍화도를 평가하였다. 현장 시추공 시험 결과로부터 변형계수, 전단강도 정수, 전단파 속도 등을 평가하였고, 심도에 따라 각 지반특성 값이 증가하는 경향을 확인하였다. X선 형광분석을 통해 산정한 화학적 풍화지수는 심도에 따라 풍화도가 감소하는 일반적인 경향을 나타냈으며, 대표적 풍화지수인 VR과 풍화암의 지반특성과의 관계를 분석하였다.