• Title/Summary/Keyword: flotation

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Thickening of Bulking Sludge using DAF (Dissolved Air Flotation) (DAF(Dissolved Air Flotation)를 이용한 팽화 슬러지 농축)

  • Kim Dong-Seog;Park Young-Seek
    • Journal of Environmental Science International
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    • v.15 no.1
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    • pp.77-84
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    • 2006
  • An effective technique of sludge separation is required for excess sludge of sewage or wastewater plant. The separation of bulking sludge of paper manufacturing plant was studied using DAF(Dissolved Air Flotation) system. The effects of parameters such as nozzle type, A/S(air/solid) ratio. pressure, injection time of pressured water and saturation time were examined. The results showed that the best nozzle type was flat which had small orifice hole, The optimum A/S ratio and pressure were $7.070\times10^{-3}$(recycle ratio of pressured water $20\%$) and 5atm, respectively. Injection times of pressurized water around 20-25 sesc and flotation time of 30 min appeared to be optimal for the DAF operation. The order of performance of packing was 18 mm > 22 mm > 32 mm.

Comparison of Froth-flotation Efficiency between Fatty Acid and Non-ionic Surfactant Added to Recovered Paper with Increased Mixing Ratio of OMG (순환제지자원의 OMG비율 증가에 따른 지방산과 비이온성 계면활성제의 탈묵효율 비교)

  • Seo, Jin Ho;Lee, Kwang Seob;Lee, Tai Ju;Lee, Myoung Ku;Ryu, Jeong Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.88-95
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    • 2015
  • The main sources of recovered paper for newsprint are old newsprint (ONP) and old magazine (OMG). Recently, a lot of advertisement flyers are flowing into bales of ONP and portion of OMG is increasing in recovered paper because the consumption level of coated paper increases. In this study, nonionic surfactant and fatty acid were used as the de-inking agent for froth-flotation process of mixed recovered paper to investigate the effect of increased mixing ratio of OMG. De-inking efficiency of nonionic surfactant decreased as the mixing ratio of OMG increased; ink removal efficiency of froth-flotation is poor, however, the reject ratio increases due to ash from OMG. In comparison with nonionic surfactant, the ash from OMG had a little effect on reject ratio and optical properties of fatty acid applied flotation accept. If nonionic surfactant and fatty acid are added to pulper and flotation cell sequentially, excessive ash from OMG may not give an adverse effect on de-inking efficiency of mixed recovered paper.

Evaluation of Flotation Efficiency and Particle Separation Characteristics of Carbon Dioxide Bubbles using Collision Efficiency Model (단일포집자충돌(SCC) 모델을 이용한 이산화탄소기포의 입자분리특성과 부상효율 평가)

  • Lee, Jun-Young;Kim, Seong-Jin;Yoo, Young-Hoon;Chung, Paul-Gene;Kwon, Young-Ho;Park, Yang-Kyun;Kwak, Dong-Heui
    • Journal of Korean Society on Water Environment
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    • v.28 no.1
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    • pp.129-136
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    • 2012
  • In this century, scientists realized that carbon dioxide gas in the atmosphere cause a greenhouse effect which affects the planet's temperature. Therefore lots of attempts have carried out to decrease the discharge of carbon dioxide gas in the field. The dissolved carbon dioxide flotation (DCF) process was developed as an alternative of DAF process to decrease the discharge and reuse of carbon dioxide as well as to save energy consumption. To investigate the particle separation characteristics and the flotation efficiency of carbon dioxide, SCC model was employed in the DCF process which has been applied extensively for the evaluation and simulation in the DAF process. The simulation results by the SCC model revealed the predicted curve of flotation efficiency became decreased gradually over the optimal pressure range of saturator about 1.6 atm in accordance with the experiment results of the DCF pilot plant and the size distribution and the bubble volume concentration of $CO_{2}$ bubbles depending on the operation pressure of saturator. The findings through the simulation results led to the conclusion that there was no significant difference between $CO_{2}$ bubbles and air bubbles, affecting on the practical flotation efficiency, in terms of the initial collision and attachment efficiency.

Removal of Iron Bearing Minerals from Illite (일라이트에 함유된 Fe 불순물 제거)

  • Kim, Yun-Jong;Cho, Sung-Baek;Park, Hyun-Hae;Kim, Sang-Bae
    • Korean Journal of Materials Research
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    • v.16 no.8
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    • pp.497-502
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    • 2006
  • Recently, many attention have been focused on illite as a material for the well-being industry. Illite contains various kinds of iron bearing materials and they restrict their usage. In this study, Fe impurities in the illite produced in Yeongdong-gun, Chungcheongbuk-do were characterized and their removal experiments were performed. According to the characterization of illite raw ore, it contained 1.54 wt.%$Fe_2O_3$ due to the existence of iron oxide($Fe_2O_3$) and pyrite($FeS_2$). The raw ore was crushed into 3 mm or less using cone crusher and then ground by rod mill for the liberation of impurity mineral. For the removal of iron bearing minerals, an acid treatment, a flotation, a magnetic separation, and a flotation combined with magnetic separator were performed respectively. When the illite raw ore was treated with magnetic separation and various kinds of acid, 1.54wt.%. $Fe_2O_3$ content was reduced to 0.78 and 1.0 wt.%, respectively. On the other hand $Fe_2O_3$ content was reduced to be 0.52 wt.% after flotation. These results indicate that iron bearing minerals cannot be reduced below 0.3wt.%$Fe_2O_3$. However, combination of magnetic separation and flotation enable us to get 0.24wt.% of illite concentrate. It is concluded that, for the refinement of illite from Yeongdong-gun, the flotation combined with magnetic separation is good for high purity illite.

Colour Removal from Dyestuff Wastewater by Micro Bubbles Flotation Process (마이크로 버블 부상 공정에 의한 염료폐수의 색도 제거)

  • Kim, Myeng-Joo;Han, Sien-Ho
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.606-612
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    • 2022
  • The purpose of this study is to convert hydrophobic dyestuff to hydrophilic dyestuff by reacting cationic collector with anionic dyestuff and reaction anionic collector with cationic dyestuff. The removal of colors from aqueous solutions and/or dispersions has been studied by dispersed-air flotation in a batch column. In this studies used generated micro bubble by ceramic gas diffuser having micro pore size for air flotation process. In this study, a ceramic gas diffuser with micro pore size was used to generate micro bubbles for the air flotation process. Two colours were used for the experiments: Basic Yellow 1 (cationic dyestuff) and Direct Orange 10 (anionic dyestuff). All two were effectively removed by flotation within 8 mins. Sodium dodecyl sulfate, sodium oleate (an anionic collector), and amines (a cationic collector) were found to be effective as collectors in the removal of color, which was found to be related to the pH of the solution and the amount of collector added to it, with high collector dosages causing the process to become pH-independent.

Diagnostic metallurgy of porphyry copper-gold deposits in the Pan-Pacific

  • Kim Joe Y.;Kim Sun S.;Shin Hyung J.;Kong Bong S.;Lee Keon K.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.581-589
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    • 2003
  • The variable flotation response ores from different deposits results basically from mineralogical association and their differences. Development of new techniques for analyzing the metallurgical performance of flotation and other concentration processes is demanded even in the treatment of rather simple ores such as porphyry ores. Diagnostic metallurgical analysis can be used to quantify the most possible recovery processes. Several porphyry copper/gold ores around the world were used to examine the responses in flotation, gravity separation and cyanidation in order to define the linkage between the recovery processes for both copper and old values. Laboratory batch flotation, gravity separation and cyanidation tests were carried out on these samples. All results were used to correlate the relative recovery of copper and gold, and to predict the highest possible metal recovery in the system. The metallurgical predictions were made according to the flotation conditions used and gravity separation. The results of various concentration processes on each porphyry ore samples are presented and discussed. All seven samples have shown significantly different gold/copper metallurgy. The grade/recovery relationships of gold and copper in the laboratory batch tests for the best results and the plants are given in the Figures below. The results of laboratory tests show that the copper recoveries converged to about $90\%$, but the gold recoveries were spread over $55-80\%$, except the K S ore. Series of standard cyanidation tests on the flotation concentrate samples and gravity separation using Knelson Separator on heads ores were carried out to cross-link the metallurgy and mineralogy of gold in the porphyry ores.

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Mineralogical Characteristics and Fundamental Study of Flotation for Molybdenum Ore (몰리브덴광의 광물학적 특성 및 부선 기초연구)

  • Oyunbileg Purev;Hyun Soo Kim;Chul-Hyun Park
    • Resources Recycling
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    • v.31 no.6
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    • pp.73-80
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    • 2022
  • This study investigated the mineralogical characteristics and basic flotation properties of domestic molybdenum ores. The source mineral of molybdenum was identified as molybdenite, and the main gangue minerals in the raw ore were silicate minerals. Copper, lead, and zinc were also found in trace amounts. Based on the results of basic flotation properties, molybdenite's zeta potential showed negative charges in all pH ranges. The contact angle of molybdenite increased with pH, reaching a maximum of 74° at pH 9. In optimal conditions, the grade and recovery of the concentrate by unit flotation were MoS2 82.4% and 92.04%, respectively. Further investigation of the impurities in the concentrate revealed a sulfide mineral with surface characteristics similar to molybdenite and silicate minerals combined with molybdenite, which may degrade the quality of the concentrate. To improve the concentrate quality, we intend to control silicate minerals through regrinding and liberation and use column flotation to improve fine particle separation efficiency.

Development of Microbubble Flotation Technique for the Production of High Grade Coal (Microbubble Flotation에 의한 고품위(高品位) 석탄생산(石炭生産) 기술(技術) 개발(開發))

  • Han, Oh-Hyung;Park, Sin-Woong;Kim, Byoung-Gon
    • Resources Recycling
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    • v.21 no.4
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    • pp.44-52
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    • 2012
  • The purpose of this study is to confirm the possibility of obtaining high grade coal from fixed carbon 20.68% coal. Also, the mineralogical, physical/chemical and liberation characteristics was found with the aim of decrease in ash amount, during the pre-processing of clean coal technology. In this study, batch flotation and microbubble column flotation that was appropriate for the processing of fine particles was used with the variation in kinds and quantity of frother, collector and depressant. Also grinding time, air flow rate and feeding rates were examined. As a result of batch flotation, using pulp density 20%, collector DMU-101+dodecyl amine(100 mL/ton), frother pine oil (200 mL/ton), depressant sodium silicate(1 kg/ton), obtained the result of ash rejection 81.55% and combustible recovery 70.23%. In result of microbubble column flotation, the result was ash rejection 83.85% and combustible recovery 70.42% under the condition of pulp density 5%, grinding time 5 min. collector DMU-101+DDA(100 mL/ton), frother AF65(5.4 L/ton), depressant SMP(3.5 kg/ton), wash water(360 mL/min.) and air flow rate(1,197 mL/min.).

Comparative Study on Removal Characteristics of Disinfection By-products by Air Stripping and Flotation Processes (탈기와 부상 공정에 의한 소독부산물의 제거특성에 관한 비교 연구)

  • Cha, Hwa-Jeong;Won, Chan-Hee;Lee, Kang-Hag;Oh, Won-Kyu;Kwak, Dong-Heui
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.9
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    • pp.513-520
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    • 2016
  • It is well known that volatile compounds including disinfection by-products as well as emissive dissolved gas in water can be removed effectively by air stripping. The micro-bubbles of flotation unit are so tiny as microns while the diameter of fine bubbles applied to air stripping is ranged from hundreds to thousands of micrometer. Therefore, the micro-bubbles in flotation can supply very wide specific surface area to transfer volatile matters through gas-liquid boundary. In addition, long emission time also can be gained to emit the volatile compound owing to the slow rise velocity of micro-bubbles in the flotation tank. There was a significant difference of the THMs species removal efficiency between air stripping and flotation experiments in this study. Moreover, the results of comparative experiments on the removal characteristics of THMs between air stripping and flotation revealed that the mass transfer coefficient, $K_La$ showed obvious differences. To overcome the limit of low removal efficiency of dissolved volatile compounds such as THMs in flotation process, the operation range of bubble volume concentration is required to higher than the operation condition of conventional particle separation.

Comparative Evaluation on Collision and Particle Separation Efficiency between CO2 Bubbles and Air Bubbles Using Contact Zone Model of Flotation Process (부상분리 공정의 접촉영역 모델을 이용한 이산화탄소와 공기 기포의 충돌 및 입자 분리효율 비교 평가)

  • Yang, Jong-Won;Choi, Yong-Ho;Chae, In-Seok;Kim, Mi-Sug;Jeong, Yong-Hoon;Kim, Tae-Geum;Kwak, Dong-Heui
    • Journal of Korean Society on Water Environment
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    • v.35 no.1
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    • pp.64-71
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    • 2019
  • In recent years, carbon dioxide ($CO_2$) bubbles emerged as the most widely applied material with the recycling of sequestrated storage to decrease global warming. Flotation using $CO_2$ as an alternative to air could be effective in overcoming the high power consumption in the dissolved air flotation (DAF) process. The comparison of DAF and DCF system indicated that, the carbon dioxide flotation (DCF) system with pressurized $CO_2$ only requires 1.5 ~ 2.0 atm, while the DAF system requires 3.0 ~ 6.0 atm. In a bid to understand the characteristics of particle separation, the single collector collision (SCC) model was used and a series of simulations were conducted to compare the differences of collision and flotation between $CO_2$ bubbles and air bubbles. In addition, laboratory experiments were sequentially done to verify the simulation results of the SCC model. Based on the simulation results, surfactant injection, which is known to decrease bubble size, cloud improved the collision efficiency of $CO_2$ bubbles similar to that of air bubbles. Furthermore, the results of the flotation experiments showed similar results with the simulation of the SCC model under anionic surfactant injection. The findings led us to conclude that $CO_2$ bubbles can be an alternative to air bubbles and a promising material as a collector to separate particles in the water and wastewater.