• Journal of the Korean Chemical Society
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• v.67 no.6
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• pp.420-428
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• 2023

Crosslinking was introduced into vinylized-mesoporous silica and recycled polyethylene. By introducing a vinyl group into the mesoporous silica, it becomes a material capable of inducing cross-linking with non-polar polyethylene. By synthesizing vinylized-mesoporous silica and inducing crosslinking with recycled polyethylene, a recycled polyethylene composite with improved physical properties than existing recycled polyethylene was synthesized. In addition, even when a small amount is added according to the grade of recycled polyethylene using vinylized-mesoporous silica, the crosslinking reaction proceeds and all physical properties are improved. Four types of vinylized-mesoporous silica were synthesized, and the shape, microstructure, and functional groups were analyzed by TEM, BET, FT-IR, and XRD. Using vinylized-mesoporous silica, three types of compounds were blended by crosslinking reaction with recycled polyethylene. In order to confirm the presence or absence of crosslinking, analysis was performed using XPS and FT-IR, and physical properties such as tensile strength, elongation, flexural strength, and flexural modulus were confirmed using a universal testing machine. As a result, by applying vinylized-mesoporous silica to recycled polyethylene in various grades, the weak physical properties of existing recycled polyethylene were overcome. By applying the vinylized-mesoporous silica, recycled polyethylene composite material that overcomes the weak physical properties to the normal polyethylene, it shows the optimal physical property index that can be used commercially. Therefore, it is expected that it can potentially increase the use of recycled polyethylene and recycle resources.

• Structural Engineering and Mechanics
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• v.90 no.6
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• pp.611-633
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• 2024

This study intends to investigate the response of multi-cell (MC) beams to flexural loads in which the primary reinforcement is composed of both metallic and non-metallic materials. "Multi-cell" describes beam sections with multiple longitudinal voids separated by thin webs. Seven reinforced concrete MC beams measuring 300×200×1800 mm were tested under flexural loadings until failure. Two series of beams are formed, depending on the type of main reinforcement that is being used. A control RC beam with no openings and six MC beams are found in these two series. Series one and two are reinforced with metallic and non-metallic main reinforcement, respectively, in order to maintain a constant reinforcement ratio. The first crack, ultimate load, deflection, ductility index, energy absorption, strain characteristics, crack pattern, and failure mode were among the structural parameters of the beams under investigation that were documented. The primary variables that vary are the kind of reinforcing materials that are utilized, as well as the kind and quantity of mesh layers. The outcomes of this study that looked at the experimental and numerical performance of ferrocement reinforced concrete MC beams are presented in this article. Nonlinear finite element analysis (NLFEA) was performed with ANSYS-16.0 software to demonstrate the behavior of composite MC beams with holes. A parametric study is also carried out to investigate the factors, such as opening size, that can most strongly affect the mechanical behavior of the suggested model. The experimental and numerical results obtained demonstrate that the FE simulations generated an acceptable degree of experimental value estimation. It's also important to demonstrate that, when compared to the control beam, the MC beam reinforced with geogrid mesh (MCGB) decreases its strength capacity by a maximum of 73.33%. In contrast, the minimum strength reduction value of 16.71% is observed in the MC beams reinforced with carbon reinforcing bars (MCCR). The findings of the experiments on MC beams with openings demonstrate that the presence of openings has a significant impact on the behavior of the beams, as there is a decrease in both the ultimate load and maximum deflection.

• Journal of the Korea Concrete Institute
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• v.25 no.4
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• pp.381-388
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• 2013

This study presents that effect of anchor plate on concrete breakout strength was evaluated. The addition of the anchor plate is to improve the concrete breakout capacity for a single anchor system in a thin-walled concrete panel (Insulated concrete sandwich wall panel). In this study, an elasticity-based simplified model was developed and used to predict effect on the anchor plate. Flexural stresses of the plate with respect to the concrete breakout strength obtained from CCD (Capacity Concrete Design) approach were compared with the test results. Through the test results, while the concrete breakout strength was improved due to increment of the width and thickness of the anchor plate, improvement of the strength was steadily declined. In addition, the It was observed that the analytical and experimental flexure of the anchor plate was comparatively in good agreement using the simplified elastic analysis model.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.15 no.1
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• pp.117-126
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• 2002

In this paper, 3-D fame design using second-orders plastic-hinge analysis accounting for lateral torsional buckling is developed. This analysis accounts for material and geometric nonlinearities of the structural system and its component members. Moreover, the problem associated with conventional second-order plastic-hinge analyses, which do not consider the degradation of the flexural strength caused by lateral torsional buckling, is overcome. Efficient ways of assessing steel frame behavior including gradual yielding associated with residual stresses and flexure, second-order effect, and geometric imperfections are presented. In this study, a model consisting of the unbraced length and cross-section shape is used to account for lateral torsional buckling. The proposed analysis is verified by the comparison of the LRFD results. A case studs shows that lateral torsional buckling is a very crucial element to be considered in second-order plastic-hinge analysis. The proposed analysis is shown to be an efficient reliable tool ready to be implemented into design practice.

• Steel and Composite Structures
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• v.31 no.4
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• pp.373-385
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• 2019

This paper presents a useful in-plane structural analysis of low-rise blind-bolted composite frames with semi-rigid joints. Analytical models were used to predict the moment-rotation relationship of the composite beam-to-column flush endplate joints that produced accurate and reliable results. The comparisons of the analytical model with test results in terms of the moment-rotation response verified the robustness and reliability of the model. Abaqus software was adopted to conduct frame analysis considering the material and geometrical non-linearities. The flexural behaviour of the composite frames was studied by applying the lateral loads incorporating wind and earthquake actions according to the Australian standards. A wide variety of frames with a varied number of bays and storeys was analysed to determine the bending moment envelopes under different load combinations. The design models were finalized that met the strength and serviceability limit state criteria. The results from the frame analysis suggest that among lateral loads, wind loads are more critical in Australia as compared to the earthquake loads. However, gravity loads alone govern the design as maximum sagging and hogging moments in the frames are produced as a result of the load combination with dead and live loads alone. This study provides a preliminary analysis and general understanding of the behaviour of low rise, semi-continuous frames subjected to lateral load characteristics of wind and earthquake conditions in Australia that can be applied in engineering practice.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.1
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• pp.49-56
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• 2020

Epoxy/carbon composite was used to prepare a bipolar plate for polymer electrolyte membrane fuel cell (PEMFC). Phenol novolac-type epoxy and diglycidyl ether of bisphenol A (DGEBA)-type epoxy mixture was used as a matrix and graphite powder, carbon fiber (CF) and graphite fiber (GF) were used as carbon materials. In order to improve the mechanical properties of the bipolar plate, surface-modified CF was incorporated into the epoxy/carbon composite. To determine the cure temperature of the epoxy mixture, differential scanning calorimetry (DSC) analysis was performed and the data were introduced to Kissinger equation in order to get reaction activation energy and pre-exponential factor. Tensile and flexural strength was obtained by using universal testing machine (UTM). The surface morphology of the fractured specimen and the interfacial morphology between epoxy matrix and CF or GF were observed by a scanning electron microscopy (SEM).

• Proceedings of the Korea Concrete Institute Conference
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• 1992.10a
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• pp.82-87
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• 1992

In this thesis, the fatigue tests were performed on a series of SFRC (steel fiber reinforced concrete)to investigate the flexural tensile behavior of SFRC varying with the steel fiber contents and the steel fiber aspect ratios. Beam specimens of 10$\times$10$\times$60cm are used. the specimen series are classified according to the steel fiber contents varying 0.5. 1.0, 1.5%, and to the steel fiber aspect ratios varying 60, 80, 100. The three point loading system was used in the fatigue tests. The minimum value of repeated loading was fixed at 10.0kgf and maximum value was 75% to static ultimate strength for periodically using concrete strain gages located at the lower end of the mid-span, and the stress-strain curves were drawn for each specimens, respectively. From the tests result, it was found that the larger steel fiber content and the smaller the steel fiber aspect ratio is , the tensile strain of SFRC under fatigue load proportionally increases. By the regression analysis on these results, the empirical formulae to predict the tensile strain of SFRC were suggested. In comparison of the tensile elastic modulus under fatigue load, it was also found that the larger steel fiber content and the smaller steel fiber aspect ratio is , the smaller decreasing rate of the stiffness of SFRC under fatigue load decreased.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.04a
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• pp.67-70
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• 2000

Mechanical properties of (10%$AI_20_3{\cdot}SiO_2$+5%Ni)/Al hybrid composites fabricated by the reaction squeeze casting were compared with those of (15%$AI_20_3{\cdot}SiO_2$)/Al composites. Intermetallic compound formed by reaction between molten aluminum and reinforcing powder was uniformly distributed in the Al matrix. These intermetallic compounds were identified as $Al_3$NI using EDS and X-ray diffraction analysis. Microhardness and flexural strength of hybrid composites were higher than that of (15%$AI_20_3{\cdot}SiO_2$)/Al Composite. In-Situ fracture tests were Conducted on (15%$AI_20_3{\cdot}SiO_2$)/Al Composites and (10%$AI_20_3{\cdot}SiO_2$+5%Ni)/Al hybrid composites to identify the microfracture process. It was identified from the in-situ fracture test of (10%$AI_20_3{\cdot}SiO_2$+5%Ni)/Al composites, microcracks were initiated mainly at the short fiber / matrix interfaces. As the loading was continued, the crack propagated mainly along the separated interfacial regions and the well developed shear bands. It was identified from the in-situ fracture test of (10%$AI_20_3{\cdot}SiO_2$+5%Ni)/Al hybrid composites, microcracks were initiated mainly by the short fiber/matrix interfacial debonding. The crack proceeded mainly through the intermetallic compound clusters

• Journal of the Korean Ceramic Society
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• v.39 no.1
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• pp.51-56
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• 2002

The effect of kind of starting materials used for a sintering additive. magnesium acetate and magnesium nitrate, on the mechanical properties of alumina sintered body made by adding 1000 ppm of the additives, respectively, was investigated. As for the alumina sintered bodies prepared from magnesium acetate and magnesium nitrate, we observed that their relative densities decreased rapidly with increasing sintering temperature 1$600^{\circ}C$. Outer layer of alumina bodies had a duplex microstructure consisting of pores and grain growth. Also the inner layer had a second phase between alumina grain boundaries. By EPMA analysis, we confirmed that the grain boundary phase was a compound containing Mg.

• Proceedings of the KIEE Conference
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• 2011.07a
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• pp.1449-1450
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• 2011

The SiC-$ZrB_2$ composites were produced by subjecting a 40:60 (vol.%) mixture of zirconium diboride($ZrB_2$) powder and ${\beta}$-silicon carbide (SiC) matrix to spark plasma sintering(SPS) under argon atmosphere at 50MPa(P50) and 60MPa(P60) pressure. The relative density, 94.13% of P60 sample was lower than that, 94.75% of P50 sample. Reactions between ${\beta}$-SiC and $ZrB_2$ were not observed via x-ray diffraction (hereafter, XRD) analysis. The trend of flexural strength of SiC-$ZrB_2$ composites were in accordance with the relative density. The properties of a SiC-$ZrB_2$ composites through SPS under argon atmosphere were positive temperature coefficient resistance in the temperature range from $25^{\circ}C$ to $500^{\circ}C$, and electrical resistivity of P50 and P60 sample were $6.75{\times}10^{-4}$ and $7.22{\times}10^{-4}{\Omega}{\cdot}cm$ at room temperature, respectively.