• Title/Summary/Keyword: flexible viscosity

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A new versatile Microemulsion Gel Technology with flexible Viscosity

  • Ulrich Kux;Jorg Schreiber;Diec, Khiet-Hien;Sabine Ripke;Wittern, Klaus-Peter
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.232-257
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    • 2003
  • It has been shown that transparent microemulsion gels of flexibly adjustable viscosity containing less than 10% w/w surfactants can be obtained just by cooling down through a new 1-step preparation procedure (via 4 different in-situ colloidal systems) using PIT-technology with a range of emulsifiers, co-emulsifiers and lipids. They can be used for a wide scope of applications. Specific examples have been given with antiperspirant formulas that proof the stability of these thickened microemulsions even with high content of electrolytes and low pH. We propose that the structure of these microemulsion gels can be described by cross-linking of nano-fine oil droplets via an ABA-triblock copolymer. A new generation of transparent antiperspirant roll-ons with significantly improved skin tolerance can now be formulated as an attractive alternative to alcohol-based products.

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A Theoretical Study on the Dynamic Characteristics of Damping Flexible Coupling(I) (유체감쇠 커플링의 동특성에 관한 이론적 연구(I))

  • 김종수;제양규;정재현;전효중
    • Journal of Advanced Marine Engineering and Technology
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    • v.18 no.1
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    • pp.11-22
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    • 1994
  • The present works are the theoretical results of the study to develope a damping flexible coupling which has a high performance of control for the torsional vibrations of power shafts in a large machinery. It is established the analysis scheme of the multiple-leaf spring, to obtain the static coefficient of stiffness of the coupling. Also, the dynamic coefficient of stiffness and the damping coefficient of the coupling are indentified through the flow analysis for a induced flow of working fluid by the deflection of multiple-leaf springs. This paper dealt with damping contributions by the friction between each plate of the multiple-leaf spring. In this paper, it is found that the dynamic characteristics of the damping flexible coupling are strongly dependent on the stiffness and the number of the multiple-leaf spring, and also vary with the viscosity of working fluid and the vibration speed of the inner star.

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Rheological Characterization of Dextran Solution (DEXTRAN 용액의 유동학적 특성)

  • Kim, Nam-Hie;Lee, Hyang-Aee
    • YAKHAK HOEJI
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    • v.32 no.1
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    • pp.86-94
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    • 1988
  • Some rheological properties of subfractions for dextran in the molecular weights range from $3{\times}10^4$ to $2{\times}10^6$ was investigated at room temperature. The dependence of the viscosity on concentration, shear rate, pH & ionic strength, temperature and solvent effect was observed. From the experimental data the Mark-Houwink viscosity equation in water at $25^{\circ}C$ was determined for samples having the molecular weight ranging from $3{\times}10^4$ to $2{\times}10^6$ as$[{\eta}]=3.1{\times}10^{-3}\;Mw^{0.39}(in\;dl/g)$. The intrinsic stiffness of the dextran backbone was estimated by evaluating the 'characteristic ratio' $C_{\infty}$, which is below the 0.082. In the concentrated region, the viscosity was decreased with increasing shear rate and was exponentially decreased with raising temperature, the viscosity showed the maximum value at neutral condition. From the experimental data, it was concluded that dextran chain, linked by the ${\alpha}-1$, 6-glucosidic linkage, behaves like a flexible random coil chain in aqueous solution, dextran solutions were pseudoplastic power law fluids among the empirical models of non-Newtonian behavior. Urea was an active reagent which increases the viscosity and swells dextran while pyrididine and glycerol were inactive reagents. Also, it could be estimated that the formation of gel structure is promote to the neutral state, the molecular weight larger than $2{\times}10^5$, when electrolytic concentration is IN and Ureas is use to solvent.

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A VIRTUAL BOUNDARY METHOD FOR SIMULATION OF FLOW OVER SWIMMING STRINGS

  • Huang, Wei-Xi;Sung, Hyung-Jin
    • 한국전산유체공학회:학술대회논문집
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    • 2006.10a
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    • pp.66-69
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    • 2006
  • In the present study, we propose a virtual boundary method for simulation of massive inextensible flexible strings immersed in viscous fluid flow. The fluid motion is governed by the Navier-Stokes equations and a momentum forcing is added in order to bring the fluid to move at the same velocity with the immersed surface. A massive inextensible flexible string model is described by another set of equations with an additional momentum forcing which is a result of the fluid viscosity and the pressure difference across the string. The momentum forcing is calculated by a feedback loop. Simulations of several numerical examples are carried out, inlcuding a hanging string which starts moving under gravity without ambient fluid, a string swimming within a uniform flow and a uniform flow over two side-by side strings. The numerical results agree well with the theoretical analysis and previous experimental observations. Preliminary results of a swimming elongated fishlike body will also be presented.

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Curing Kinetics and Chemorheological Behavior of No-flow Underfill for Sn/In/Bi Solder in Flexible Packaging Applications

  • Eom, Yong-Sung;Son, Ji-Hye;Bae, Hyun-Cheol;Choi, Kwang-Seong;Lee, Jin-Ho
    • ETRI Journal
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    • v.38 no.6
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    • pp.1179-1189
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    • 2016
  • A chemorheological analysis of a no-flow underfill was conducted using curing kinetics through isothermal and dynamic differential scanning calorimetry, viscosity measurement, and solder (Sn/27In/54Bi, melting temperature of $86^{\circ}C$) wetting observations. The analysis used an epoxy system with an anhydride curing agent and carboxyl fluxing capability to remove oxide on the surface of a metal filler. A curing kinetic of the no-flow underfill with a processing temperature of $130^{\circ}C$ was successfully completed using phenomenological models such as autocatalytic and nth-order models. Temperature-dependent kinetic parameters were identified within a temperature range of $125^{\circ}C$ to $135^{\circ}C$. The phenomenon of solder wetting was visually observed using an optical microscope, and the conversion and viscosity at the moment of solder wetting were quantitatively investigated. It is expected that the curing kinetics and rheological property of a no-flow underfill can be adopted in arbitrary processing applications.

Flexible Dye-sensitized Solar Cells by a Low-temperature Sintering Method (저온소결법에 의한 플렉시블 염료감응 태양전지)

  • Baek, Ji-Hye;Kim, Joo-yong;Kang, Wee-Kyung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.320-322
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    • 2007
  • A new binder-free $TiO_{2}$ paste was prepared by common ion applying effect, enabling low temperature fabrication required for flexible solar cells. The binder-free and high viscosity $TiO_{2}$ coating solution was produced by adding 7.5% aniline in $TiO_{2}$ colloid solution obtained from the high pressure water-heat response method. The resulting pastes had high level of viscosities proper for optimal coating and thus revealed excellent performances in terms of thickness uniformity and I-V characteristics.

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Blends of semi-rigid substituted poly(p-phenylene) with BPA-polycarbonate

  • Dijkstra Dirk J.;Karbach Alexander;Malkovich Nick
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.364-364
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    • 2006
  • The rheological properties of Parmax 1200, a new semi-flexible substituted polyphenylene, were investigated. The reported high stiffness of the material was confirmed. The rheological measurements proved that, despite the very high stiffness of the molecules, Parmax showed shear thinning and that, although the viscosity is very high and the melt is highly elastic, the polymer can be extruded in the melt. A worm-like morphology was detected in AFM and TEM. This morphology could explain the reported mechanical and rheological behaviour. The compatibility with flexible chain polymers (e.g. polycarbonate) could also be explained by the worm-like morphology.

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Performance of Squeeze Film Damper Using Magneto-Rheological Fluid (MR유체를 이용한 스퀴즈필름 댐퍼의 응답특성)

  • 안영공;양보석;신동춘;김동조
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.67-70
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    • 2002
  • This paper presents the property of the Squeeze Film Damper (SFD) using Magneto-Rheological fluid (MR fluid). The damping property of a SFD for a flexible rotor system varied according to vibration mode. MR fluid is known as a functional fluid with controllable apparent viscosity of the fluid by applied magnetic field strength. When the MR fluid is applied in the SFD, the SFD using MR fluid can effectively reduce vibrations of the flexible rotor in a wide range of rotating speed by control of the applied magnetic field strength. To investigate in detail the SFD using MR fluid, the SFD to support one mass was constructed and its performance was experimentally investigated in the present study. The damping property of the SFD using MR fluid has viscous damping by Newtonian fluid, but not Coulomb friction by Bingham fluid. Therefore, The system damped by the SFD can be considered as a linear system.

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Shear-induced structure and dynamics of hydrophobically modified hydroxy ethyl cellulose (hmHEC) in the presence of SDS

  • Tirtaatmadija, Viyada;Cooper-white, Justin J.;Gason, Samuel J.
    • Korea-Australia Rheology Journal
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    • v.14 no.4
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    • pp.189-201
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    • 2002
  • The interaction between hydrophobically modified hydroxyethyl cellulose (hmHEC), containing approximately 1 wt% side-alkyl chains of $C_{16}$, and an anionic sodium dodecyl sulphate (SDS) surfactant was investigated. For a semi-dilute solution of 0.5 wt% hmHEC, the previously observed behaviour of a maximum in solution viscosity at intermediate SDS concentrations, followed by a drop at higher SDS concentrations, until above the cmc of surfactant when the solution resembles that of the unsubstituted polymer, was confirmed. Additionally, a two-phase region containing a hydrogel phase and a water-like supernatant was found at low SDS concentrations up to 0.2 wt%, a concentration which is akin to the critical association concentration, cac, of SDS in the presence of hmHEC. Above this concentration, SDS molecules bind strongly to form mixed micellar aggregates with the polymer alkyl side-chains, thus strengthening the network junctions, resulting in the observed increase in viscosity and elastic modulus of the solution. The shear behaviour of this polymer-surfactant complex during steady and step stress experiments was examined In great detail. Between SDS concentrations of 0.2 and 0.25 wt%, the shear viscosity of the hmHEC-polymer complex network undergoes shear-induced thickening, followed by a two-stage shear-induced fracture or break-up of the network. The thickening is thought to be due to structural rearrangement, causing the network of flexible polymers to expand, enabling some polymer hydrophobic groups to be converted from intra- to inter-chain associations. At higher applied stress, a partial local break-up of the network occurs, while at even higher stress, above the critical or network yield stress, a complete fracture of the network into small microgel-like units, Is believed to occur. This second network rupture is progressive with time of shear and no steady state in viscosity was observed even after 300 s. The structure which was reformed after the cessation of shear is found to be significantly different from the original state.