• Korean Journal of Hazardous Materials
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• v.2 no.1
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• pp.18-26
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• 2014

We analyzed the demand of competent authorities requiring adequate technical information for initial investigation of chemical accidents. Reflecting technical reports on chemical accident response by environmental agencies in the U.S. and Canada, we presented information on environmental diffusion and toxic effects available for the first chemical accident response. Hydrogen fluoride may have the risk potential to corrode metals and cause serious burns and eye damages. In case of inhalation or intake, it could have severe health effects. The substance itself is inflammable, but once heated, it decomposes producing corrosive and toxic fume. In case of contact with water, it can produce toxic, corrosive, flammable or explosive gases and its solution, a strong acid, may react fiercely with a base. In case of hydrogen fluoride leak, the preventive measures are to decrease steam generation in exposed sites, prevent the transfer of vapor cloud and promptly respond using inflammable substances including calcium carbonate, sodium bicarbonate, ground limestone, dried soil, dry sand, vermiculite, fly ash and powder cement. The method for fire fighting is to suppress fire with manless hose stanchions or monitor nozzles by wearing the whole body protective clothing equipped with over-pressure self-contained breathing apparatus from distance. In case of transport accident accompanied with fire, evacuation distance is 1,600m radius. In cae of fire, fire suppression needs to be performed using dry chemicals, CO₂, water spray, water fog, and alcohol-resistance foam, etc. The major symptoms by exposure route are dyspnoea, bronchitis, chemical pneumonia and pulmonary edema for respiration, skin laceration, dermatitis, burn, frostbite and erythema for eyes, and nausea, diarrhea, stomachache, and tissue destruction for digestive organs. In atmosphere, its persistency is low, and its bioaccumulation in aquatic organism is also low.

• Fire Science and Engineering
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• v.34 no.2
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• pp.14-21
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• 2020

This paper presents the study of a fire risk to the backside of two miniatures of ISO 9705 2/5 using a lightweight partition for indoor space division and reproduction of the ISO 9705 test. An SGP partition, stud partition, glass wool panel, urethane foam panel, sandwich panel, and glass partition were selected as the test specimens, which are frequently used in construction. According to the ISO 9705 test standard, stabilization was achieved using a measuring device that recorded data before the ignition of a burner and continued recording for 120 s thereafter. After ignition was achieved, the power was increased to 300 kW for 600 s and then reduced to 100 kW for 600 s. The specimens were subsequently observed for 180 s, and the fire risk to the backside and the fire pattern of the wall unit were analyzed. Owing to the amount of heat generated by the ignition source, the maximum temperature of the backside was observed to be 67.7 ℃ for the SGP partition, 55.1 ℃ for the stud partition, 52.4 ℃ for the glass wool panel, 727.4 ℃ for the sandwich panel, 561 ℃ for the urethane foam panel, and 630.5 ℃ for the glass partition. In the cases of the sandwich and urethane foam panels, the explosion of flammable gas occurred by virtue of fusion of the interior materials. The reinforced glass was fractured owing to the temperature difference between the heat- and nonheat-responsive parts. Ultimately, the fire risk to the nearby section room was deemed to be high.

• Journal of the Society of Disaster Information
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• v.14 no.1
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• pp.89-100
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• 2018

when the explosive wastes to be treated as designated wastes are brought into the wastes treatment plant by mistake and lead to an explosion in the wastes disposal process, many people and property damage are involved. Waste should be treated properly. As mentioned in this paper, ignition reac- tion tests of ignitable re-burning of explosives packing material waste (solid butadiene) confirmed that ignition was easily occurred, and that even small ignition sources were easily ignited and burned quickly and explosively. In particular, when explosives are loaded into incineration wastes in large quantities and mixed with organic compound wastes, such as fire and explosion accidents caused by explosives packing materials at waste disposal sites, flammable and oxidative gases are generated due to mutual oxidation and pyrolysis It is confirmed that there is a possibility that ignition sources such as spark ignite and instantaneously lead to explosion. It is hoped that this study will be a small reference for on - site detection in the field of fire, and it is expected that the fire - fighting agency will be recognized as a fire investigation agency and will contribute to the improvement of the credibility.

• Fire Science and Engineering
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• v.31 no.3
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• pp.97-105
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• 2017

Because asphalt is a solid at normal temperature and is not a hazardous material as stipulated in the Safety Management Act on Hazardous Materials, it is often recognized as having no risk of fire or explosion. On the other hand, it is as dangerous as flammable liquid because it is heated to $170-180^{\circ}C$ and stored in a storage tank. This study analyzed the risk of fire and explosion during the storage and handling of asphalt and the actual conditions of asphalt regulations by fire service organizations. Moreover, this study analyzed the domestic case of explosions in the production process of asphalt concrete (ASCON) and domestic and foreign cases of asphalt storage tank explosions. The analysis suggested that unlike Japan, Korea has no asphalt regulations in fire service organizations. Explosions can occur when ignition is delayed after fuel is sprayed on the dryer drum burner of the aggregates during the production of ASCON. A physical explosion can occur in the storage tank when environmental purification facilities suddenly work strongly to remove air pollutants or bad smells during the heating of asphalt in an asphalt storage tank. In addition, explosions can occur when fires such as welding is performed in the asphalt storage tank.

• Fire Science and Engineering
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• v.31 no.3
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• pp.25-30
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• 2017

Because of the vertical combustion characteristics of combustible substances, accurate substance safety information for their safe use, handling and transportation is essential. The flash point, fire point, explosion limits and autoignition temperature (AIT) are important safety parameters which need special attention in chemical plants and laboratories that handle dangerous materials. In this study, tert-butylbenzene which is widely used as an intermediate material in the chemical industry was selected. For the reliability of the flammable properties of tert-butylbenzene, this study was investigated the explosion limits of tert-butylbenzene in the reference data. The flash points, fire points and AITs by the ignition delay time for tert-butylbenzene were experimented. The lower flash points of tert-butylbenzene by using the Setaflash and Pensky-Martens closed-cup testers measured $39^{\circ}C$ and $44^{\circ}C$, respectively. The flash points of tert-butylbenzene by using the Tag and Cleveland open cup testers are measured $51^{\circ}C$ and $54^{\circ}C$. And the fire points of tert-butylbenzene by the Tag and Cleveland open cup testers were $54^{\circ}C$ and $58^{\circ}C$ respectively. The AIT of tert-butylbenzene measured by the ASTM 659E tester was measured as $450^{\circ}C$. The lower explosion limit of $39^{\circ}C$ which measured by the Setaflash flash point tester was calculated to be 0.68 vol%.

• Fire Science and Engineering
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• v.28 no.4
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• pp.1-7
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• 2014

Several complex devices and equipments are installed in the car's engine room, including various kind of oils or other flammable materials. So re-ignition is very likely to take place in it. In addition, it is restrictive for the driver or the occupant to open the bonnet and to spray the fire extinguisher in the engine room due to the high possibility of explosion. Therefore, a fire extinguishing system, which can detect a fire and inject the fire extinguishing agent to extinguish it, and fire extinguishing agents including HFC-227ea, which can stand the high temperature within the engine room and hold the viscosity sufficient to keep it in the kind of foam, were developed and tested. And the suffocation effect and the cooling effect come from the fire extinguishing principle of the foam fire extinguishing agent and the inhibiter catalyst effect come from the one of HFC-227ea was led simultaneously, and fire extinguishing agents without the secondary damage caused by residuals after the fire extinguishment like a case of the powder fire extinguishing agent, were developed. And experiments using a vehicle collision after the discharge is complete, foreign material can be removed without extinguishing the advantage that experimental results obtained.

• Journal of the Korean Institute of Gas
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• v.22 no.4
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• pp.27-31
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• 2018

Classification of explosion hazard areas is very important in terms of cost and safety in the workplace handling flammable materials. This is because the radius of the hazardous area determines whether or not the explosion-proof equipment is installed in the electrical machinery and apparatus. From November 6, 2017, KS C IEC-60079-10-1: 2015 will be issued and applied as a new standard. It is important to understand and apply the difference between the existing standard and the new standard. Leakage coefficients and compression factors were added to the leakage calculation formula, and the formula of evaporation pool leakage, application of leakage ball size, and shape of explosion hazard area were applied. The range of the safety factor K has also been changed. Also, in the radius of the hazardous area, the existing standard applies the number of ventilation to the virtual volume, but the revised standard is calculated by using the leakage characteristic value. In this study, we investigated the differences from existing standards in terms of ventilation and dilution and examined the effect on the radius of the hazard area. Comparisons and analyzes were carried out by applying revised standards to workplaces where existing explosion hazard locations were selected. The results showed that even if the ventilation and dilution were successful, the risk radius was not substantially affected.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.12
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• pp.804-815
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• 2019

Due to the depletion and environmental problems of fossil fuel, biomass has arisen as an alternative energy source. Biomass is a renewable and carbon-neutral source. However, it is moister and has lower energy density. Therefore, biomass needs thermal chemical conversion processes like gasification, and it does not only produce a flammable gas, called 'syngas', which consists of CO, H2, and CH4, but also some unwanted byproducts such as tars and some particulates. These contaminants are condensed and foul in pipelines, combustion chamber and turbine, causing a deterioration in efficiency. Thus this work attempted to find a method to remove tars and particles from syngas with a filter which adopts a pre-coating technology for preventing blockage of the filter medium. Hydrated limestone powder and activated carbon(wood char) powder were used as the pre-coat materials. The removal efficiency of the tars was 86 % and 80 % with activated carbon(wood char) coating and hydrated limestone coating, respectively.

• Fire Science and Engineering
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• v.32 no.4
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• pp.50-59
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• 2018

Recently, huge life losses occurred in the elderly long-term medical care fires due to lack of escape safety. As part of the measures to enhance the effectiveness of fire escape safety, while they prolong the available safe egress time (ASET) of non fire compartments, a measure to shorten fire-fighter's arrival time by fire alarm notifying device should be implemented in these facilities. The four categories from the aspects of fire prevention/protection engineering were provided with the necessary component technologies for carrying out these helper-guided evacuations. Fire prevention engineered technology was presented by two provisions; one for ensuring small compartment sections by installing the fire rated wall between bed rooms and another for ensuring the fire retardant or/and non-flammable performance of finishing materials. Also fire protection engineered technology was presented by two items; one for imposing cooling effects by sprinklers and another for providing automatic fire alarm notifying functions to fire stations. In order to improve the escape safety of these facilities in Korea, alternative revisions may presented by considering insufficient provisions in the architectural/fire law provisions by analyzing the provisions of Japanese and domestic laws in detail.

• Journal of the Korean GEO-environmental Society
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• v.21 no.5
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• pp.23-33
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• 2020

As the scale of the economy expands, the number of cases of damage in enclosed spaces such as tunnels is increasing due to the accident of transportation vehicles of dangerous substances such as explosive flammable materials that have increased rapidly. In the case of road tunnels in particular, in the aspect of protection against the long-winding trend and the environment in the downtown area, the number of cases of passing through the downtown area increases, and securing the safety of structures against unexpected extreme disasters such as explosions during tunnel passage is very urgent. For this reason, developed countries are already conducting a review of internal bombardment, but there are almost no evaluation and countermeasures for explosion risk in Korea. Therefore, in this study, in order to evaluate the explosion safety of road tunnels, a boiling liquid explosive explosion (BLEVE), which is considered to have the greatest explosion load among vehicles driving on the road, is set as a reference explosion source, and the equivalent TNT explosion load is used for simulation of the explosion. A method of conversion was presented. In addition, by applying the derived explosion load, dynamic behavior simulation was performed by assuming various variables for the tunnel, and the explosion safety of the tunnel was analyzed.