• 대한안전경영과학회지
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• 제25권1호
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• pp.61-66
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• 2023

The purpose of this study is to compare and analyze the flame retardant performance of Japanese cypress(Chamaecyparis obtusa) plywood, commonly used in indoor decoration, furniture, and tableware, by treating it with three different fire retardants with different primary ingredients. The experiment was conducted in compliance with Article 31, Paragraph 2 of the Enforcement Decree of the Fire Facilities Installation and Management Act and Articles 4 and 7-2 of the Flame Retardant Performance Standards. After flame time, after glow time, char length, and char area were measured. As a result, first, after flame time was measured at 0 seconds regardless of whether the flame retardant treatment was applied. Second, after glow time was relatively long, measuring 22.7 seconds without treatment, which is likely due to the weak fire resistance and high concentration of carbon monoxide generated by the chemical characteristics of the Japanese cypress itself. Third, it was confirmed that the effects of the primary ingredient, phosphorus, in the flame retardant treatment varied depending on the technological development of the manufacturers of the same species of Japanese cypress plywood. In the future, it is expected that the results of this study will provide fundamental data to select flame retardant treatments that show high flame retardant performance according to the botanical characteristics of the wood.

• 한국화재소방학회논문지
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• 제30권2호
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• pp.35-42
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• 2016

막구조 건축물은 경량의 건축용 막재를 사용하므로 자유로운 곡면표현이 가능하고 시각적인 만족도가 높아 그 사용이 점차 확대되고 있다. 하지만 건축용 막재를 구성하는 직물이 화재에 취약하므로 용도에 적합하며 보다 높은 난연성능을 가지는 불연성 막재의 개발이 요구되고 있다. 따라서 본 연구에서는 단열성, 내열성, 불연성이 우수한 현무암섬유를 건축용 막재의 직포로 적용하고 PTFE 분산 수지를 함침 코팅하여 DSC/TGA 열분석, 강도특성, 방염 및 난연특성을 평가하였다. 또한, 일반적으로 사용되는 건축용 막재 중 성능이 가장 우수한 유리섬유 직포 막재와 난연특성을 비교하였으며 평가결과 현무암섬유 직포의 건축용 막재로서의 가능성을 확인할 수 있었다.

• 한국화재소방학회논문지
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• 제30권1호
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• pp.17-23
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• 2016

막구조물은 코팅된 직물을 주재료로 하는 구조로 연성을 가진 막을 사용하여 외부하중에 대해 안정된 형태를 유지하는 구조물을 말한다. 막에 의한 구조시스템은 대공간 시공이 가능하고 가벼우며 빛을 투과할 수 있는 등 자원 및 관리비용 절감 면에서 많은 이점을 가지고 있어 다양한 용도의 구조물에 적용되며 그 사용용도가 점차 확대되고 있는 실정이다. 하지만 막구조 건축물 및 막재가 다양해짐에도 불구하고 화재안전을 고려한 막재의 성능에 대한 기준은 미비한 실정이며 다양한 용도에 적합한 난연성능이 우수한 막재의 개발이 요구되고 있다. 따라서 본 연구에서는 시판되는 건축용 막재인 PTFE, PVDF와 PVF, ETFE 필름 막재의 방염 및 난연성능 시험 등을 통해 건축용 막재의 난연특성을 확인하였다.

• 한국염색가공학회지
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• 제11권6호
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• pp.7-17
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• 1999

Aminophosphazene derivatives were prepared from hexachlorocyclotriphosphazene and used for the curing agents of epoxy resins. The effect of the curing agent on the dynamic viscoelastic properties, flame proofing, and heat resistance of the cured epoxy resins were investigated and compared with those for the epoxy resins cured with aliphatic and aromatic amines. The epoxy resin cured by 1,1-diamino-3,3,5,5-tetrachlorocyclotriphosphazene showed the highest storage modulus and glass transition temperature when cured at 19$0^{\circ}C$ for 6 hours. The epoxy resins cured with phosphazene derivatives showed superior flame proofing to those with aliphatic amine and aromatic amine. Particularly it is an effective curing agent for epoxy resins to enhance the storage modulus, flame proofing and resistance to heat.

• 한국응용과학기술학회지
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• 제19권1호
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• pp.25-32
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• 2002

Two PU flame-retardant coatings, 2,3-DBPO/N-l00 (DBPON) and 2,3-DBPO/IL (DBPOI), were prepared by curing 2,3-dibromo modified polyester (2,3-DBPO) with isocyanate curing agent Desmodur N-l00 (or Desmodur IL) at room temperature. The physical properties and flame-retardancy of the two coatings were tested and compared. As a result, the pot-life, yellowness index, lightness index difference, $60^{\circ}$ specular gloss, cross-hatch adhesion, viscosity, and accelerated weathering resistance of DBPON were better than those of DBPOI; the fineness of grind of the two coatings were the same; and the drying time, hardness, and abrasion resistance of DBPOI were better than those of DBPON. The flame retardancy of the flame-retardant coatings increased with the content of the flame retarding component, 2,3-dibromopropanoic acid (2,3-DBP); and the LOI values of the two coatings were in a range of $27{\sim}29%$ when the content of 2,3-DBP was 30wt%.

• 접착 및 계면
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• 제11권4호
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• pp.168-173
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• 2010

할로겐 함유 난연 화합물은 인체에 무해하고 유해가스 발생이 없는 환경 친화적인 소재로 대체되어가고 있다. 반도체 소자의 밀봉용 소재로 사용되는 에폭시 수지 조성물도 친환경적인 소재로 만들기 위해서, 에폭시 수지의 자소화에 관해 많은 연구가 이루어지고 있다. 본 연구에서도 신규 에폭시 수지(E3)를 사용하여 할로겐계 화합물을 전혀 함유하지 않는 자소성 에폭시 수지 조성물을 제조하였다. 새로 만들어진 에폭시 수지 조성물(EMC-1)은 UL 난연 V0를 갖고 5 wt% 분해 온도가 $451.9^{\circ}C$로, 할로겐계 난연제나 삼산화안티몬 등을 첨가하지 않고도 난연성이 우수하고 열분해성, 내열성 등이 우수하게 나타나 친환경 소재로 적용할 수 있다.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2004년도 추계학술대회
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• pp.189-195
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• 2004

It compared quality characteristics for the stone surface treatment system and its products. With the result, the flame burner equipment was mainly used to the surface treatment of granite, but it occurred greatly the high temperature, the rock fragment, the noise and dust. For the other side, the whetstone polishing machine for the polishing was a maintenance for the specific physical properties of stone, and it did not occur the stone fragment and the dust. The durability of the stone products due to the flame burner was investigated with that it falls to $20\sim25\%$ more than the surface treatment by the whetstone polishing. Share's hardness of the polishing products in the durability test showed more greatly index than the flame burner and conventional product. The polishing products of Pochon stone in the case of the abrasion resistance showed great more $15\%$ than the general products, more $9\%$ than the products by the flame burner.

• 전기학회논문지
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• 제58권10호
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• pp.1895-1901
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• 2009

This paper describes the conductor temperature and tensile load analysis of invar by flame exposure on STACIR(Super Thermal-resistance Aluminium-alloy Conductors Reinforced) overhead transmission line based on real fault phenomena. Firstly, short-circuit fault by flame exposure is analysed by EMTP/ATP simulation, then the cutting causes of Al layer are also discussed. And then, the conductor temperature is calculated based on IEC 60949 according to 3 kinds of materials including invar, Al conductor and ACSR when same load current respectively flows in 3 kinds of material, they are compared each other. Finally, the tensile load tests are performed with various samples including new invar, used invar for a long time and invar exposed flame.

• 한국응용과학기술학회지
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• 제22권2호
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• pp.123-135
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• 2005

Reaction intermediates PCP/BZA (PBI) and tetramethylene bis(orthophosphate)(TBOP) were synthesized from polycaprolactone (PCP) and benzoic acid (BZA) and from pyrophosphoric acid and 1,4-butanediol, respectively. Benzoic acid modified polyesters containing phosphorus (APTB-S, -10, -15) were synthesized by polycondensation of the prepared PBI (containing 5, 10, 15wt% of benzoic acid), TBOP, adipic acid, and 1,4-butanediol. Network structured PU flame-retardant coatings (APHD) were prepared by curing the synthesized benzoic acid modified polyesters containing phosphorus (APT B - 5 , -10, -15) with hexamethylene diisocyanate (HDI)-timer. From the TGA analysis of APTBs, it was found that the afterglow decreased with the amount of BZA content at the high temperatures. With the introduction of BZA, the film viscosity and film hardness of APHD decreased. With the introduction of caprolactone group, the flexibility, impact resistance, accelerated weathering resistance of APTBs increased. Flame retardancy of the coatings was tested. In a vertical burning method, APHD shows 210$^{\sim}$313 seconds, which indicates that the coatings are good flame-retardant coatings. Moreover, the amount of afterglow and flame retardancy of the coatings are decreased with increasing BZA content.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1313-1314
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• 2006

For improvement of wear resistance property of atmospheric thermal plasma sprayed molybdenum (Mo) coating, diamond deposition on the atmospheric plasma sprayed molybdenum coating by the combustion flame chemical vapor deposition (CFCVD) has been operated. In this study, to diminish the thermal damage of the substrate during operation, a thermal insulator was equipped between substrate and water-cooled substrate holder. Consequently, diamond particles could be created on the Mo coating without fracture and peeling off. From these results, it was found that this process had a high potential in order to improve wear resistance of thermal sprayed coating.