• 한국분말재료학회지
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• 제26권3호
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• pp.195-200
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• 2019

Whisker-type magnesium hydroxide sulfate hydrate ($5Mg(OH)_2{\cdot}MgSO_4{\cdot}3H_2O$, abbreviated 513 MHSH), is used in filler and flame-retardant composites based on its hydrate phase and its ability to undergo endothermic dehydration in fire conditions, respectively. In general, the length of whiskers is determined according to various synthetic conditions in a hydrothermal reaction with high temperature (${\sim}180^{\circ}C$). In this work, high-quality 513 MHSH whiskers are synthesized by controlling the concentration of the raw material in ambient conditions without high pressure. Particularly, the concentration of the starting material is closely related to the length, width, and purity of MHSH. In addition, a ceramic-coating system is adopted to enhance the mechanical properties and thermal stability of the MHSH whiskers. The physical properties of the silica-coated MHSH are characterized by an abrasion test, thermogravimetric analysis, and transmission electron microscopy.

• 한국응용과학기술학회지
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• 제38권6호
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• pp.1678-1686
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• 2021

본 연구에서는 가교제인 붕산과 아크릴 수지 바인더에 삼인산(3 인산), 피트산(6 인산) 또는 폴리인산암모늄(10 인산)을 혼합하여 인계 난연 코팅액을 제조하였다. 제조된 인계 난연 코팅액을 부직포에 각각 코팅하여 높은 난연 효과를 얻었다. 이렇게 제조된 난연성 부직포를 연기밀도기준시험(ASTM E662), 산소한계지수기준시험(ISO E622), 수직연소기준시험(UL 94)을 이용하여 평가하였다. 그들의 난연 효과는 phosphate 그룹의 수에 의해 영향을 받았으며, 천연 또는 합성 바인더 수지에 관계없이 그 효과는 ammonium polyphosphate > phytic acid > triphosphate의 순서로 나타났다. 천연 탄화수소 화합물도 바인더 수지의 난연성을 결정하기 위해 조사되었다. 그 결과 천연 탄화수소 바인더 수지가 난연성 부직포 제조에 사용될 수 있음을 보여주었다.

• 공업화학
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• 제17권4호
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• pp.357-360
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• 2006

본 연구에서는 단열재로서의 페놀수지(PF) 발포폼의 물성과 응용가능성을 검토하였다. 실험결과 페놀수지 발포폼의 밀도는 $0.030g/cm^3$를 나타내었고, 열전도율은 $0.026kcal/m.h.^{\circ}C$를 나타내었다. 또한 페놀수지 발포폼은 $500^{\circ}C$로 1 h 동안 열을 가했을 경우 약 71.7 wt%가 휘발되었다. 그리고 페놀수지 발포폼의 화학구조는 단열재로서의 중요 물성인 closed cell 구조형태를 갖는 것으로 분석되었다. 따라서 제조된 페놀수지 발포폼은 단열소재로서의 우수한 물성을 갖는 것으로 확인되었다.

• 한국화재소방학회논문지
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• 제31권2호
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• pp.1-8
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• 2017

샌드위치패널은 건축물의 내 외벽 및 지붕구조에 사용되며 양면의 불연성재료와 단열용 심재로 구성된 복합자재이다. 뛰어난 단열성능과 경량 및 시공의 우수한 특성 대비 화재 시 패널간 결합부위를 통해 화염이 내부로 유입되어 심재가 쉽게 용융되며 급격한 화염확산으로 인명 및 재산피해를 발생시킨다. 현행 건축법은 건축물 마감재료에 대하여 소규모 시험편에 대한 화재시험방법으로 연소성능을 파악하며 규정한 성능기준에 합격한 제품을 사용하도록 한다. 외벽 마감재료의 경우 불연 준불연 성능확보 재료를 사용하거나 화재확산방지구조를 설치하도록 규정한다. 본 연구는 외벽 마감재료에 국한되어 적용하고 있는 화재확산방지 구조를 샌드위치패널 건축물에 적용하여 수평 수직 화재확산의 위험성의 차이를 확인하고자 하였다. 이에 샌드위치패널에 대하여 ISO 13784-1 시험방법을 통한 실물화재실험과 금속구조물을 이용하여 패널간 화염확산을 차단하는 시공을 통해 화염확산방지 적용 여부에 대한 연소거동과 그 효과를 측정하였다. 실험 결과 패널 조인트 부위의 화염확산방지구조 시공은 패널 내부의 화염확산을 지연하며 이에 따른 플래시오버 시간이 지연되어 복합자재 건축물의 화재안전확보에 중요한 요인으로 작용될 수 있음을 확인하였다.

• 한국가구학회지
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• 제27권1호
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• pp.8-14
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• 2016

Increasing concerns of environment need to make change furniture field to more environmentally friendly approach, such as reuse of by-products from wooden products. As it is, the methods of recycling wood for industrial purposes have the advantage of productivity and adaptability. However, the industrial way is required a certain production facility of processing wooden by-products and has possible hygienic problems due to contaminated sources. Many designers have developed their own methods for reuse of wood in unique and artistic ways. Even so, because of confined sources, it could be not enough supply. Therefore, I developed the design methodology utilizing wooden by-products from S Design Company to relieve former ways' problems. The design suggestion took materials from a safe and abundant source. The wooden leftover pieces were connected together with epoxy clay, so previous process traces of furniture are remained as a decorative factor. Moreover, the synthesized material was able to be processed by ordinary woodworking facilities without additional installations. In doing so, console table focused on a commercial purpose and dining table for an artistic objective were successfully fabricated as final suggestions. In consideration of the proposal using wooden furniture leftovers, diverse recycling designs should be investigated for future reference.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 추계 학술논문 발표대회
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• pp.87-88
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• 2019

Research has been conducted in many fields for the zero energy of domestic buildings. Among them, the development of insulation has become an essential element. Accordingly, researches are being made to improve the performance of organic insulating materials, and PF boards having the lowest thermal conductivity among organic insulating materials have been in the spotlight. However, problems have arisen due to the problems of durability of insulation materials such as PF boards and past acidification, and the durability of insulation materials is deteriorated when moisture or water enters due to crack gaps during the insulation of the basement layer or the external insulation method. In regard to the durability of the insulation, when the organic insulators of different kinds were placed in water, the pH was weakly basic in all organic insulation materials except PF, and the PF was about 4 pH. As a result, the PF should be continuously reviewed, and further analysis should be carried out to determine what causes acidification.

• 한국화재소방학회논문지
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• 제31권6호
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• pp.74-82
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• 2017

유기단열재를 사용한 샌드위치패널(복합자재) 건축물 화재는 소화가 어려우며, 가연성 심재를 통한 빠른 화재 확산으로 화재 시 피해가 크다. 샌드위치패널은 양면이 불연재로 되어있고, 불연재 사이에 심재인 단열재로 이루어져 있다. 단열재는 유기단열재와 무기단열재가 사용되고 있으며, 유기단열재가 무기단열재에 비하여 약 80% 이상 사용되고 있다. 유기단열재는 무기단열재에 비하여 경제적인 장점이 있지만 화재에 취약하다는 단점을 가지고 있기 때문에 샌드위치패널 화재 시 일반화재에 비하여 피해가 크다. 가스유해성시험의 경우 복합자재의 심재 위험성을 측정하기 위해 패널에 지름 25 mm 크기 3개의 원형 천공을 하여 시험하지만 콘칼로리미터 시험은 샌드위치패널 형태 그대로 시험을 진행한다. 본 연구에서는 KS F ISO 5660-1 콘칼로리미터 시험에서 복합자재의 경우 불연재인 표면에 가열한 경우와 천공을 통한 심재 노출 시험 및 심재에 직접가열 시 발생하는 화재의 위험성을 측정하였다. 시험에 사용된 유기단열재는 일반 EPS와 난연 EPS를 사용하였으며, 시험체 구성은 샌드위치패널, 천공된 샌드위치 패널, 심재의 3가지 형태로 시험을 진행하였다. 본 연구의 목적은 콘칼로리미터 시험 시 복합자재 심재의 화재 위험성을 평가하는 방안을 제시하고자 하였다.

• 한국안전학회지
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• 제38권5호
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• pp.8-14
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• 2023

Lithium ions can induce the thermal runaway phenomenon and lead to reignition due to electrical, mechanical, and environmental factors such as high temperature, smoke generation, explosions, or flames, which is extremely likely to create safety concerns. Therefore, one of the ways to improve the flame retardancy of the electrolyte is to use a flame-retardant additive. Comparing the associated characteristic value of existing substances with the required experimental value, it was found that these values were either considerably different or were not documented. It is vital to know a substance's combustion characteristic values, flash point, explosion limit, and autoignition temperature (AIT) as well as its combustion characteristics before using it. In this research, the flash point and AIT of materials were measured by mixing a highly volatile and flammable substance, diethyl carbonate (DEC), with flame-retardant dimethyl methylphosphonate (DMMP). The flash point of DEC, which is a pure substance, was 29℃, and that for DMMP was 65℃. Further, the lower explosion limit calculated using the measured flash point of DEC was 1.79 Vol.%, while that for DMMP was 0.79 Vol.%. The AIT was 410℃ and 390℃ for DEC and DMMP, respectively. In particular, since the AIT of DMMP has not been discussed in any previous study, it is necessary to ensure safety through experimental values. In this study, the experimental and regression analysis revealed that the average absolute deviation (ADD) for the flash point of the DEC+DMMP DEC+DMMP system is 0.58 sec and that the flash point tends to increase according to changes in the composition employed. It also revealed that the AAD for the AIT of the mixture was 3.17 sec and that the AIT tended to decrease and then increase based on changes in the composition.

• 한국염색가공학회지
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• 제34권4호
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• pp.250-260
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• 2022

In this research, a high-elasticity acrylic emulsion binder with core-shell polymerization and self-crosslinking system is mixed with a flame-retardant water-dispersed polyurethane (PUD) binder. In addition, finite element analysis was conducted through virtual engineering software ANSYS by applying three representative nonlinear material models. The most suitable nonlinear material model was selected after the relative comparison between the actual experimental values and the predicted values of the properties derived from simulations. The selected nonlinear material model is intended to be used as a nonlinear material model for computational simulation analysis that simulates the experimental environment of the vibration test (ASTM E1399) and the actual fire safety test (ASTM E1966). When the mass fraction of thermally expandable graphite was 0.7%, the thermal and physical properties were the best. Among the nonlinear material models, the simulation result of the Ogden model showed the closest value to the actual result.

• 한국응용과학기술학회지
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• 제27권4호
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• pp.399-406
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• 2010

This study was performed to test the flame retardancy of zelkova sarrata-based materials by the treatment of ammonium salts. Zelkova sarrata plate was soaked by the treatment with three 20 wt% ammonium salt solutions consisting ammonium chloride (AMSL), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After the drying specimen treated with chemicals, combustion properties were examined by the cone calorimeter (ISO 5660-1). When the ammonium salts were used as the retardant for zelkova sarrata, the flame retardancy improved due to the treated ammonium salts in the virgin zelkova sarrata. However the specimen shows increasing CO over virgin zelkova sarrata and It is supposed that toxicities depend on extents. Also, the specimen with ammonium salts showed the higher total smoke release (TSR) than that of virgin plate. Of specimens treated with ammonium salts the ammonium chloride handled the test side was considered a improved inhibitory effect of combustion.